期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 7, 页码 2468-2471出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja5131676
关键词
-
资金
- 973 program [2011CB808700]
- NSFC [21225210, 21202185, 21421091, 21472219]
A novel Pd-catalyzed intermolecular regio- and diastereoselective fluorosulfonylation of styrenes has been developed under mild conditions. This reaction exhibits a wide range of functional-group tolerance in styrenes and arylsulfinic acids to afford various beta-fluoro sulfones. Preliminary mechanistic study reveals an unusual mechanism, in which a high-valent (L2PdF)-F-III species side-selectively reacts with a benzylic carbon radical to deliver a C-F bond. This pathway is distinct from a previously reported radical fluorination reaction.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据