Insertion of sulfur dioxide via a radical process: an efficient route to sulfonyl compounds

Stereoselective synthesis of sulfonated 1-indenones via radical-triggered multi-component cyclization of β-alkynyl propenones

(2018) Zheng-Jia Shen et al.   CHEMICAL COMMUNICATIONS

A copper-catalyzed sulfonylative C–H bond functionalization from sulfur dioxide and aryldiazonium tetrafluoroborates

(2018) Hongguang Xia et al.   Organic Chemistry Frontiers

Synthesis of sulfonated naphthols via C–H bond functionalization with the insertion of sulfur dioxide

(2018) Kaida Zhou et al.   Organic Chemistry Frontiers

Generation of sulfonated isobenzofuran-1(3H)-ones under photocatalysis through the insertion of sulfur dioxide

(2018) Jun Zhang et al.   Organic Chemistry Frontiers

Remote site-selective C–H activation directed by a catalytic bifunctional template

(2017) Zhipeng Zhang et al.   NATURE

Synthesis of Tetrahydropyridine Derivatives through a Reaction of 1,6-Enynes, Sulfur Dioxide, and Aryldiazonium Tetrafluoroborates

(2017) Yuanyuan An et al.   ORGANIC LETTERS

Construction of Functionalized Annulated Sulfone via SO2/I Exchange of Cyclic Diaryliodonium Salts

(2017) Ming Wang et al.   ORGANIC LETTERS

Copper-Catalyzed Arylsulfonylation and Cyclizative Carbonation of N-(Arylsulfonyl)acrylamides Involving Desulfonative Arrangement toward Sulfonated Oxindoles

(2017) Hepan Wang et al.   ORGANIC LETTERS

N-Radical Initiated Aminosulfonylation of Unactivated C(sp3)–H Bond through Insertion of Sulfur Dioxide

(2017) Yuewen Li et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct C–H Functionalization of Indoles with the Insertion of Sulfur Dioxide: Synthesis of 2-Sulfonated Indoles

(2017) Tong Liu et al.   ORGANIC LETTERS

Formation of α-chiral centers by asymmetric β-C(sp 3 )–H arylation, alkenylation, and alkynylation

(2017) Qing-Feng Wu et al.   SCIENCE

Ruthenium-promoted reductive transformation of CO2

(2017) Xuedong Li et al.   Science China-Chemistry

Cobalt(ii)-catalyzed remote C5-selective C–H sulfonylation of quinolines via insertion of sulfur dioxide

(2017) Kai Wang et al.   RSC Advances

Synthesis of thiophosphates through a three-component reaction by using sulfur dioxide as the sulfur source

(2017) Xinxing Gong et al.   Organic Chemistry Frontiers

A photoinduced reaction of perfluoroalkyl halides with 1,3-diarylprop-2-yn-1-ones catalyzed by DABSO

(2017) Yuewen Li et al.   Organic Chemistry Frontiers

Synthesis of 3-(((2,3-dihydrobenzofuran-3-yl)methyl)sulfonyl) coumarins through the reaction of 2-(allyloxy)anilines, sulfur dioxide, and aryl propiolates

(2017) Xuefeng Wang et al.   Organic Chemistry Frontiers

Radical cyclization of benzene-tethered 1,7-enynes with aryldiazonium tetrafluoroborates: a facile route to benzo[j]phenanthridines

(2017) Yuanyuan An et al.   Organic Chemistry Frontiers

Synthesis of 3-((arylsulfonyl)methyl)indolin-2-ones via insertion of sulfur dioxide using anilines as the aryl source

(2017) Tong Liu et al.   Organic Chemistry Frontiers

Generation of benzosultams via a radical process with the insertion of sulfur dioxide

(2017) Kaida Zhou et al.   Organic Chemistry Frontiers

Reductive insertion of sulfur dioxide for the synthesis of trifluoromethyl thiolsulphonates through a one-pot reaction of aniline and trifluoromethanesulfanylamide

(2017) Jie Sheng et al.   Organic Chemistry Frontiers

Transition-metal-free oxidative reaction of hydrazines and potassium metabisulfite for preparation of sulfonohydrazides

(2017) Yang Wang et al.   Organic Chemistry Frontiers

Synthesis of β-keto sulfones via a multicomponent reaction through sulfonylation and decarboxylation

(2017) Jiyao Yu et al.   Organic Chemistry Frontiers

Generation of Sulfonyl Radicals from Aryldiazonium Tetrafluoroborates and Sulfur Dioxide: The Synthesis of 3-Sulfonated Coumarins

(2016) Danqing Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-catalyzed synthesis of arylsulfinates through radical coupling reaction

(2016) Weixi Zhang et al.   CHEMICAL COMMUNICATIONS

New amination strategies based on nitrogen-centered radical chemistry

(2016) Tao Xiong et al.   CHEMICAL SOCIETY REVIEWS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Visible light photoredox-controlled reactions of N-radicals and radical ions

(2016) Jia-Rong Chen et al.   CHEMICAL SOCIETY REVIEWS

Vicinal Difluoroalkylation and Aminosulfonylation of Alkynes under Photoinduced Conditions

(2016) Yuanchao Xiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Advances in Hydrogenation of Carboxylic Acid Derivatives and CO2 Using Triphos as the Coordination Ligand

(2016) Linli Zhang et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Contra-thermodynamic Hydrogen Atom Abstraction in the Selective C–H Functionalization of Trialkylamine N-CH3 Groups

(2016) Joshua P. Barham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Charge-transfer-directed radical substitution enables para-selective C–H functionalization

(2016) Gregory B. Boursalian et al.   Nature Chemistry

Enantioselective amine α-functionalization via palladium-catalysed C–H arylation of thioamides

(2016) Pankaj Jain et al.   Nature Chemistry

A palladium-catalyzed coupling reaction of aryl nonaflates, sulfur dioxide, and hydrazines

(2016) Yuanyuan An et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Functionalization of C(sp3)-H bonds using a transient directing group

(2016) F.-L. Zhang et al.   SCIENCE

Ligand-accelerated enantioselective methylene C(sp3)–H bond activation

(2016) Gang Chen et al.   SCIENCE

Copper-Catalyzed Selective Aerobic Oxidative Cascade Reaction of Hydrazines, DABSO, and Amines for the Direct Synthesis of Sulfonamides

(2016) Bingnan Du et al.   Asian Journal of Organic Chemistry

A general route to sulfones via insertion of sulfur dioxide promoted by cobalt oxide

(2016) Danqing Zheng et al.   Organic Chemistry Frontiers

Copper(i)-catalyzed sulfonylation of (2-alkynylaryl)boronic acids with DABSO

(2016) Runyu Mao et al.   Organic Chemistry Frontiers

Generation of N-aminosulfonamides via a photo-induced fixation of sulfur dioxide into aryl/alkyl halides

(2016) Yuewen Li et al.   Organic Chemistry Frontiers

A copper(i)-catalyzed three-component reaction of triethoxysilanes, sulfur dioxide, and alkyl halides

(2016) Danqing Zheng et al.   Organic Chemistry Frontiers

Generation of (2-oxoindolin-3-yl)methanesulfonohydrazides via a photo-induced reaction of N-(2-iodoaryl)acrylamide, DABSO, and hydrazine

(2016) Kaida Zhou et al.   Organic Chemistry Frontiers

A copper(ii)-catalyzed three-component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, with alkenes

(2016) Runyu Mao et al.   Organic Chemistry Frontiers

Direct vicinal difunctionalization of alkynes through trifluoromethylation and aminosulfonylation via insertion of sulfur dioxide under catalyst-free conditions

(2016) Yuewen Li et al.   Organic Chemistry Frontiers

An unexpected reaction of 2-alkynylaryldiazonium tetrafluoroborate with sulfur dioxide

(2015) Yong Luo et al.   CHEMICAL COMMUNICATIONS

Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations

(2015) Chao Liu et al.   CHEMICAL REVIEWS

Photo-induced Metal-Catalyst-Free Aromatic Finkelstein Reaction

(2015) Lu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst

(2015) Anton A. Toutov et al.   NATURE

A four-component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, 1,2-dibromoethane, and hydrazines

(2015) Danqing Zheng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Fixation of sulfur dioxide into small molecules

(2015) Gang Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Arylsulfonyl Radical Triggered 1,7-Enyne Bicyclizations

(2015) Yi-Long Zhu et al.   ORGANIC LETTERS

An efficient one-pot, three-component synthesis of vinyl sulfones via iodide-catalyzed radical alkenylation

(2015) Weizheng Fan et al.   TETRAHEDRON

Synthesis of sulfones via a reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, and aryliodoniums

(2015) Xia Liu et al.   TETRAHEDRON

Empowering a transition-metal-free coupling between alkyne and alkyl iodide with light in water

(2015) Wenbo Liu et al.   Nature Communications

The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry

(2015) Edward J. Emmett et al.   Asian Journal of Organic Chemistry

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Aminosulfonylation of Arenes, Sulfur Dioxide, and Hydrazines Cocatalyzed by Gold(III) Chloride and Palladium Acetate

(2014) Shengqing Ye et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal-Free Aminosulfonylation of Aryldiazonium Tetrafluoroborates with DABCO⋅(SO2)2and Hydrazines

(2014) Danqing Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of Fundamental Organometallic Chemistry to the Development of a Gold-Catalyzed Synthesis of Sulfinate Derivatives

(2014) Miles W. Johnson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 1-(2,3-dihydrobenzofuran-3-yl)-methanesulfonohydrazides through insertion of sulfur dioxide

(2014) Yuanyuan An et al.   CHEMICAL COMMUNICATIONS

Aminosulfonylation of aromatic amines, sulfur dioxide and hydrazines

(2014) Danqing Zheng et al.   CHEMICAL COMMUNICATIONS

Catalytic conversion of aryl triazenes into aryl sulfonamides using sulfur dioxide as the sulfonyl source

(2014) Wanfang Li et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Aminosulfonylation of Aryl Iodides by using Na2SO3as the SO2Source

(2014) Wanfang Li et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Discovery of Vinyl Sulfones as a Novel Class of Neuroprotective Agents toward Parkinson’s Disease Therapy

(2014) Seo Yeon Woo et al.   JOURNAL OF MEDICINAL CHEMISTRY

A Copper-Catalyzed Three-Component Reaction of Triethoxysilanes, Sulfur Dioxide, and Hydrazines

(2014) Xianbo Wang et al.   ORGANIC LETTERS

Palladium-Catalyzed Three-Component Diaryl Sulfone Synthesis Exploiting the Sulfur Dioxide Surrogate DABSO

(2013) Edward J. Emmett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Taming sulfur dioxide: a breakthrough for its wide utilization in chemistry and biology

(2013) Philippe Bisseret et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

DABSO-Based, Three-Component, One-Pot Sulfone Synthesis

(2013) Alex S. Deeming et al.   ORGANIC LETTERS

Synthesis of Sulfones from Organozinc Reagents, DABSO, and Alkyl Halides

(2013) Benjamin N. Rocke et al.   ORGANIC LETTERS

One-pot three-component sulfone synthesis exploiting palladium-catalysed aryl halide aminosulfonylation

(2013) Charlotte S. Richards-Taylor et al.   Chemical Science

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A palladium-catalyzed reaction of aryl halides, potassium metabisulfite, and hydrazines

(2012) Shengqing Ye et al.   CHEMICAL COMMUNICATIONS

A palladium-catalyzed three-component coupling of arylboronic acids, sulfur dioxide and hydrazines

(2012) Shengqing Ye et al.   CHEMICAL COMMUNICATIONS

Catalytic Hydrocarboxylation of Alkenes and Alkynes with CO2

(2011) Yugen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Aminosulfonylation of Aryl Halides

(2010) Bao Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of arylsulfonyl chlorides by chlorosulfonylation of in situ generated diazonium salts using a continuous flow reactor

(2010) Laia Malet-Sanz et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

(2009) Ramesh Giri et al.   CHEMICAL SOCIETY REVIEWS

Aqueous Process Chemistry: The Preparation of Aryl Sulfonyl Chlorides

(2009) Philip J. Hogan et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Recent progress in the generation and use of nitrogen-centred radicals

(2008) Samir Z. Zard   CHEMICAL SOCIETY REVIEWS