Role of Lewis-Base-Coordinated Halogen(I) Intermediates in Organic Synthesis: The Journey from Unstable Intermediates to Versatile Reagents

Cyclization of Malonate Derivatives with Iodine(III) Reagents

(2017) Florence Malmedy et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Charge-Transfer-Induced para-Selective sp2 C–H Bond Activation of Arenes by Use of a Hypervalent Iodine Compound: A Theoretical Study

(2017) Jiyang Zhao et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Aryl(2,4,6-trimethoxyphenyl)iodonium Trifluoroacetate Salts

(2017) Virginie Carreras et al.   JOURNAL OF ORGANIC CHEMISTRY

Dehydrogenative Aromatic Ring Fusion for Carbazole Synthesis via C–C/C–N Bond Formation and Alkyl Migration

(2017) Saikat Maiti et al.   ORGANIC LETTERS

CBr4 as a Halogen Bond Donor Catalyst for the Selective Activation of Benzaldehydes to Synthesize α,β-Unsaturated Ketones

(2017) Imran Kazi et al.   ORGANIC LETTERS

Radical Alkynyltrifluoromethylation of Alkenes Initiated by an Electron Donor–Acceptor Complex

(2017) Heng Jiang et al.   ORGANIC LETTERS

Organo-Iodine(III)-Catalyzed Oxidative Phenol-Arene and Phenol-Phenol Cross-Coupling Reaction

(2016) Koji Morimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free Synthesis of Aryl Amines: Beyond Nucleophilic Aromatic Substitution

(2016) Alexander H. Sandtorv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient photolytic C–H bond functionalization of alkylbenzene with hypervalent iodine(iii) reagent

(2016) Ryu Sakamoto et al.   CHEMICAL COMMUNICATIONS

The Halogen Bond

(2016) Gabriella Cavallo et al.   CHEMICAL REVIEWS

Advances in Synthetic Applications of Hypervalent Iodine Compounds

(2016) Akira Yoshimura et al.   CHEMICAL REVIEWS

Dioxoiodane Compounds as Versatile Sources for Iodine(I) Chemistry

(2016) Kilian Muñiz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents

(2016) Michael Brown et al.   CHEMISTRY-A EUROPEAN JOURNAL

Advances in Iodine(III)-Mediated Halogenations: A Versatile Tool to Explore New Reactivities and Selectivities

(2016) Andreas M. Arnold et al.   CHEMISTRY-A EUROPEAN JOURNAL

Halogen Bonding in Organic Synthesis and Organocatalysis

(2016) David Bulfield et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-Light-Mediated Synthesis of Amides from Aldehydes and Amines via in Situ Acid Chloride Formation

(2016) Naeem Iqbal et al.   JOURNAL OF ORGANIC CHEMISTRY

Hypervalent Iodine(III) Mediated Synthesis of 3-Substituted 5-Amino-1,2,4-thiadiazoles through Intramolecular Oxidative S–N Bond Formation

(2016) Arumugam Mariappan et al.   JOURNAL OF ORGANIC CHEMISTRY

Conversion of Simple Cyclohexanones into Catechols

(2016) Yu-Feng Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stabilized pyrrolyl iodonium salts and metal-free oxidative cross-coupling

(2016) Koji Morimoto et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iodocyclization of N-Arylpropynamides Mediated by Hypervalent Iodine Reagent: Divergent Synthesis of Iodinated Quinolin-2-ones and Spiro[4,5]trienones

(2016) Ying Zhou et al.   ORGANIC LETTERS

Regioselective Oxo-Amination of Alkenes and Enol Ethers with N-Bromosuccinimide–Dimethyl Sulfoxide Combination: A Facile Synthesis of α-Amino-Ketones and Esters

(2016) Pragati K. Prasad et al.   ORGANIC LETTERS

N-Iodosuccinimide-Promoted Hofmann–Löffler Reactions of Sulfonimides under Visible Light

(2016) Calvin Q. O’Broin et al.   ORGANIC LETTERS

Organic Synthesis Enabled by Light-Irradiation of EDA Complexes: Theoretical Background and Synthetic Applications

(2016) Carolina G. S. Lima et al.   ACS Catalysis

Origin of the Catalytic Effects of Molecular Iodine: A Computational Analysis

(2016) Martin Breugst et al.   ACS Catalysis

Oxidative Amidation of Nitroalkanes with Amine Nucleophiles using Molecular Oxygen and Iodine

(2015) Jing Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization Reactions

(2015) Jacob Davies et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Iodine-Catalyzed Hofmann-Löffler Reaction

(2015) Claudio Martínez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic amounts of CBr4 mediated dehydrogenative coupling of isochromans with aromatic ketones

(2015) Congde Huo et al.   CHEMICAL COMMUNICATIONS

Tris(trimethylsilyl)silane and visible-light irradiation: a new metal- and additive-free photochemical process for the synthesis of indoles and oxindoles

(2015) Gustavo Piva da Silva et al.   CHEMICAL COMMUNICATIONS

Cocrystal or Salt: Solid State-Controlled Iodine Shift in Crystalline Halogen-Bonded Systems

(2015) Olena Makhotkina et al.   CRYSTAL GROWTH & DESIGN

From simple organobromides or olefins to highly value-added bromohydrins: a versatile performance of dimethyl sulfoxide

(2015) Song Song et al.   GREEN CHEMISTRY

Efficient bromination of olefins, alkynes, and ketones with dimethyl sulfoxide and hydrobromic acid

(2015) Song Song et al.   GREEN CHEMISTRY

Metal-Free Synthesis of Indole via NIS-Mediated Cascade C–N Bond Formation/Aromatization

(2015) Yin-Long Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Nitro-Assisted Brønsted Acid Catalysis: Application to a Challenging Catalytic Azidation

(2015) Marian Dryzhakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cationic Multidentate Halogen-Bond Donors in Halide Abstraction Organocatalysis: Catalyst Optimization by Preorganization

(2015) Stefan H. Jungbauer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Organocatalytic Alkylation of Aldehydes and Enals Driven by the Direct Photoexcitation of Enamines

(2015) Mattia Silvi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of (2Z)-2,4-Dienamides via NBS-Mediated Allyloxyl Addition–Claisen Rearrangement–Dehydrobromination Cascade Reaction of Ynsulfonamides

(2015) Runbo Ding et al.   ORGANIC LETTERS

Efficient and Practical Oxidative Bromination and Iodination of Arenes and Heteroarenes with DMSO and Hydrogen Halide: A Mild Protocol for Late-Stage Functionalization

(2015) Song Song et al.   ORGANIC LETTERS

A Versatile and One-Pot Strategy to Synthesize α-Amino Ketones from Benzylic Secondary Alcohols Using N-Bromosuccinimide

(2015) Somraj Guha et al.   ORGANIC LETTERS

Direct Dehydroxylative Coupling Reaction of Alcohols with Organosilanes through Si–X Bond Activation by Halogen Bonding

(2015) Masato Saito et al.   ORGANIC LETTERS

I2- or NBS-Catalyzed Highly Efficient α-Hydroxylation of Ketones with Dimethyl Sulfoxide

(2015) Yu-Feng Liang et al.   ORGANIC LETTERS

N-Bromosuccinimide as a Brominating Agent for the Transformation of N-H (or N-Benzyl) Ketoaziridines into Oxazoles

(2015) Heshmat Samimi et al.   SYNTHESIS-STUTTGART

Iodonium Metathesis Reactions

(2014) Takahito Kasahara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Auto-Oxidative Coupling of Glycine Derivatives

(2014) Congde Huo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Indole Synthesis Based On A Modified Koser Reagent

(2014) Laura Fra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of a carbonyl compound by halogen bonding

(2014) Stefan H. Jungbauer et al.   CHEMICAL COMMUNICATIONS

Reactivity of Hydroxy- and Aquo(hydroxy)-λ3-iodane-Crown Ether Complexes

(2014) Kazunori Miyamoto et al.   CHEMISTRY-A EUROPEAN JOURNAL

Anion−π Catalysis

(2014) Yingjie Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Synthesis of Vinyl Halides, Vinyl Sulfones, and Alkynes: A Tandem Intermolecular Nucleophilic and Electrophilic Vinylation of Tosylhydrazones

(2014) Devi Prasan Ojha et al.   ORGANIC LETTERS

2-Halogenoimidazolium Salt Catalyzed Aza-Diels–Alder Reaction through Halogen-Bond Formation

(2014) Youhei Takeda et al.   ORGANIC LETTERS

High-turnover hypoiodite catalysis for asymmetric synthesis of tocopherols

(2014) M. Uyanik et al.   SCIENCE

A solvent-resistant halogen bond

(2014) Craig C. Robertson et al.   Chemical Science

Iodine-Catalyzed Selective Synthesis of 2-SulfanylphenolsviaOxidative Aromatization of Cyclohexanones and Disulfides

(2013) Wenlei Ge et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Enantioselective Iodoetherification of Oximes

(2013) Chandra Bhushan Tripathi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Developments in Asymmetric Phase-Transfer Reactions

(2013) Seiji Shirakawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis with Anion-π Interactions

(2013) Yingjie Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Highly Selective ortho-Halogenation (I, Br, Cl) of Arylnitriles via sp2 C–H Bond Activation Using Cyano as Directing Group

(2013) Bingnan Du et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Conversion of N-Alkoxyamides to Carboxylic Esters through Tandem NBS-Mediated Oxidative Homocoupling and Thermal Denitrogenation

(2013) Ningning Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Halogen and Chalcogen Cation Pools Stabilized by DMSO. Versatile Reagents for Alkene Difunctionalization

(2013) Yosuke Ashikari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemical activity of a key donor–acceptor complex can drive stereoselective catalytic α-alkylation of aldehydes

(2013) Elena Arceo et al.   Nature Chemistry

N-Bromosuccinimide/1,8-Diazabicyclo[5.4.1]undec-7-ene Combination: β-Amination of Chalcones via a Tandem Bromoamination/Debromination Sequence

(2013) Ying Wei et al.   ORGANIC LETTERS

Mild Metal-Free Sequential Dual Oxidative Amination of C(sp3)–H bonds: Efficient Synthesis of Imidazo[1,5-a]pyridines

(2013) Yizhe Yan et al.   ORGANIC LETTERS

N-Bromoimide/DBU Combination as a New Strategy for Intermolecular Allylic Amination

(2013) Ying Wei et al.   ORGANIC LETTERS

Evidence for a Symmetrical Fluoronium Ion in Solution

(2013) M. D. Struble et al.   SCIENCE

Metal-free synthesis of 2-aminobenzoxazoles using hypervalent iodine reagent

(2013) Yogesh S. Wagh et al.   TETRAHEDRON LETTERS

Defined Hypervalent Iodine(III) Reagents Incorporating Transferable Nitrogen Groups: Nucleophilic Amination through Electrophilic Activation

(2012) José A. Souto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Ion-Pairing Catalysis

(2012) Katrien Brak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications

(2012) Manuel Mahlau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free α-CH amination of ethers with hypervalent sulfonylimino-λ3-bromane that acts as an active nitrenoid

(2012) Masahito Ochiai et al.   CHEMICAL COMMUNICATIONS

NIS-Catalyzed Reactions: Amidation of Acetophenones and Oxidative Amination of Propiophenones

(2012) Manjunath Lamani et al.   CHEMISTRY-A EUROPEAN JOURNAL

Lewis Base Catalysis by Thiourea: N-Bromosuccinimide-Mediated Oxidation of Alcohols

(2012) Chandra Bhushan Tripathi et al.   JOURNAL OF ORGANIC CHEMISTRY

Symmetric Halogen Bonding Is Preferred in Solution

(2012) Anna-Carin C. Carlsson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Halocyclization Using Reagents Tailored for Chiral Anion Phase-Transfer Catalysis

(2012) Yi-Ming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

One-Pot Cascade Leading to Direct α-Imidation of Ketones by a Combination of N-Bromosuccinimide and 1,8-Diazabicyclo[5.4.1]undec-7-ene

(2012) Ying Wei et al.   ORGANIC LETTERS

Breathing molecular crystals: halogen- and hydrogen-bonded porous molecular crystals with solvent induced adaptation of the nanosized channels

(2012) Kari Raatikainen et al.   Chemical Science

Ditopic Ion Transport Systems: Anion-π Interactions and Halogen Bonds at Work

(2011) Andreas Vargas Jentzsch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Intramolecular Bromo-Amination ofN-Alkenyl Sulfonamides via Umpolung of Alkali Metal Bromides

(2011) Katsuhiko Moriyama et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Bromoaminocyclization Using Amino–Thiocarbamate Catalysts

(2011) Ling Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aminothiocarbamate-Catalyzed Asymmetric Bromolactonization of 1,2-Disubstituted Olefinic Acids

(2011) Chong Kiat Tan et al.   ORGANIC LETTERS

Silver-Catalyzed Intramolecular Chloroamination of Allenes: Easy Access to Functionalized 3-Pyrroline and Pyrrole Derivatives

(2011) Masahiro Sai et al.   ORGANIC LETTERS

A Divergent and Selective Synthesis of Isomeric Benzoxazoles from a Single N–Cl Imine

(2011) Cheng-yi Chen et al.   ORGANIC LETTERS

Highly practical amino acid and alkaloid synthesis using designer chiral phase transfer catalysts as high-performance organocatalysts

(2010) Keiji Maruoka   CHEMICAL RECORD

Experimental and Theoretical Study of Halogen-Bonded Complexes of DMAP with Di- and Triiodofluorobenzenes. A Complex with a Very Short N···I Halogen Bond

(2010) Laila C. Roper et al.   CRYSTAL GROWTH & DESIGN

Dialkyl Chloronium Ions

(2010) Evgenii S. Stoyanov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhancement of Anion Recognition Exhibited by a Halogen-Bonding Rotaxane Host System

(2010) Nathan L. Kilah et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Thiourea-Catalyzed Cationic Polycyclizations

(2010) Robert R. Knowles et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Bromolactonization Using Amino-thiocarbamate Catalyst

(2010) Ling Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis base catalysis of bromo- and iodolactonization, and cycloetherification

(2010) S. E. Denmark et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Quaternary Ammonium (Hypo)iodite Catalysis for Enantioselective Oxidative Cycloetherification

(2010) M. Uyanik et al.   SCIENCE

Carbon Tetrabromide/Sodium Triphenylphosphine-m-sulfonate (TPPMS) as an Efficient and Easily Recoverable Catalyst for Acetalization and Tetrahydropyranylation Reactions

(2009) Congde Huo et al.   ADVANCED SYNTHESIS & CATALYSIS

IBX−I2Redox Couple for Facile Generation of IOH and I+: Expedient Protocol for Iodohydroxylation of Olefins and Iodination of Aromatics

(2009) Jarugu Narasimha Moorthy et al.   JOURNAL OF ORGANIC CHEMISTRY

Halogen Bonding: A Study based on the Electronic Charge Density

(2009) Nancy J. Martinez Amezaga et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Recent advances in the application of bromodimethylsulfonium bromide (BDMS) in organic synthesis

(2009) Lokman H. Choudhury et al.   TETRAHEDRON

Lewis Base Catalysis in Organic Synthesis

(2008) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective α-Oxysulfonylation of Ketones Mediated by Iodoarenes

(2008) Sabine M. Altermann et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Asymmetric Iodination of Aldehydes Using an Axially Chiral Bifunctional Amino Alcohol Catalyst

(2008) Taichi Kano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iodocyclization of Ethoxyethyl Ethers to Alkynes: A Broadly Applicable Synthesis of 3-Iodobenzo[b]furans

(2008) Takashi Okitsu et al.   ORGANIC LETTERS