Enantioselective Metal-Catalyzed Reductive Coupling of Alkynes with Carbonyl Compounds and Imines: Convergent Construction of Allylic Alcohols and Amines

Stereo- and Site-Selective Conversion of Primary Alcohols to Allylic Alcohols via Ruthenium-Catalyzed Hydrogen Auto-Transfer Mediated by 2-Butyne

(2022) Eliezer Ortiz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Enantioselective α-Alkenylation of N-Sulfonyl Amines: Modular Access to Chiral α-Branched Amines

(2021) Lun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio- and Enantioselective Reductive Coupling of Alkynes and Aldehydes via Photoredox Cobalt Dual Catalysis

(2021) Yan-Lin Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Hydrogenation to Transfer Hydrogenation to Hydrogen Auto-Transfer in Enantioselective Metal-Catalyzed Carbonyl Reductive Coupling: Past, Present, and Future

(2021) Catherine Gazolla Santana et al.   ACS Catalysis

Dual Functionalization of Alkynes Utilizing the Redox Characteristics of Transition Metal Catalysts

(2021) Sudipta Ghosh et al.   ChemCatChem

Life cycle assessment of acetylene production from calcium carbide and methane in China

(2021) Suisui Zhang et al.   Journal of Cleaner Production

Understanding Halide Counterion Effects in Enantioselective Ruthenium-Catalyzed Carbonyl (α-Aryl)allylation: Alkynes as Latent Allenes and Trifluoroethanol-Enhanced Turnover in The Conversion of Ethanol to Higher Alcohols via Hydrogen Auto-transfer

(2021) Eliezer Ortiz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines

(2021) Xiao-Biao Yan et al.   Nature Communications

A Synthesis Strategy for the Production of a Macrolactone of Gulmirecin A via a Ni(0)-Mediated Reductive Cyclization Reaction

(2020) Shun Kitahata et al.   ORGANIC LETTERS

Enantio- and Diastereoselective Synthesis of Functionalized Carbocycles by Cu-Catalyzed Borylative Cyclization of Alkynes with Ketones

(2019) Joseph M. Zanghi et al.   ORGANIC LETTERS

Transition metal-catalyzed carboxylation reactions with carbon dioxide

(2018) Ruben Martin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines

(2018) Michael Holmes et al.   CHEMICAL REVIEWS

Versatile Cobalt-Catalyzed Enantioselective Entry to Boryl-Functionalized All-Carbon Quaternary Stereogenic Centers

(2018) Chao Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed asymmetric silylative cyclization of cyclohexadienone-containing 1,6-enynes

(2018) Cheng-Yu He et al.   TETRAHEDRON

Nickel/N-Heterocyclic Carbene Complex-Catalyzed Enantioselective Redox-Neutral Coupling of Benzyl Alcohols and Alkynes to Allylic Alcohols

(2018) Yuan Cai et al.   ACS Catalysis

NHC Ligands Tailored for Simultaneous Regio- and Enantiocontrol in Nickel-Catalyzed Reductive Couplings

(2017) Hengbin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of a Modular Synthetic Route to (+)-Pleuromutilin, (+)-12-epi-Mutilins, and Related Structures

(2017) Mingshuo Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Big Data from Pharmaceutical Patents: A Computational Analysis of Medicinal Chemists’ Bread and Butter

(2016) Nadine Schneider et al.   JOURNAL OF MEDICINAL CHEMISTRY

Evaluation of Chromane-Based Bryostatin Analogues Prepared via Hydrogen-Mediated C–C Bond Formation: Potency Does Not Confer Bryostatin-like Biology

(2016) John M. Ketcham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Nickel-Catalyzed anti-Carbometallative Cyclizations of Alkynyl Electrophiles Enabled by Reversible Alkenylnickel E/Z Isomerization

(2016) Christopher Clarke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-catalyzed reductive coupling of olefin-derived nucleophiles: Reinventing carbonyl addition

(2016) Khoa D. Nguyen et al.   SCIENCE

Recent Advances in the Asymmetric Nozaki–Hiyama–Kishi Reaction

(2016) Guozhu Zhang et al.   SYNTHESIS-STUTTGART

Ruthenium-Catalyzed Transfer Hydrogenation for C–C Bond Formation: Hydrohydroxyalkylation and Hydroaminoalkylation via Reactant Redox Pairs

(2016) Felix Perez et al.   Topics in Current Chemistry

Mechanistic Basis for Regioselection and Regiodivergence in Nickel-Catalyzed Reductive Couplings

(2015) Evan P. Jackson et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nickel Catalysis: Synergy between Method Development and Total Synthesis

(2015) Eric A. Standley et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly Enantioselective Nickel-Catalyzed Intramolecular Reductive Cyclization of Alkynones

(2015) Wenzhen Fu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ferrocene-Based Planar Chiral Imidazopyridinium Salts for Catalysis

(2015) Christopher T. Check et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereocontrolled Formation of Several Carbon–Carbon Bonds in Acyclic Systems

(2015) Guillaume Eppe et al.   CHEMICAL REVIEWS

Ruthenium(II) and Osmium(II) Vinyl Complexes as Highly Sensitive and Selective Chromogenic and Fluorogenic Probes for the Sensing of Carbon Monoxide in Air

(2015) Anita Toscani et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective dialkylzinc-mediated alkynylation, arylation and alkenylation of carbonyl groups

(2015) Tomasz Bauer   COORDINATION CHEMISTRY REVIEWS

Catalytic Enantioselective CH Functionalization of Alcohols by Redox-Triggered Carbonyl Addition: Borrowing Hydrogen, Returning Carbon

(2014) John M. Ketcham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Reductive Coupling Reactions of Organic Halides with Carbonyl-Type Compounds

(2014) Toni Moragas et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of seco-B-Ring Bryostatin Analogue WN-1 via C–C Bond-Forming Hydrogenation: Critical Contribution of the B-Ring in Determining Bryostatin-like and Phorbol 12-Myristate 13-Acetate-like Properties

(2014) Ian P. Andrews et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric Tandem Cyclization for Efficient and Rapid Access to Underexplored Heterocyclic Tertiary Allylic Alcohols Containing a Tetrasubstituted Olefin

(2014) Yi Li et al.   ORGANIC LETTERS

Catalytic Asymmetric Synthesis of Allylic Alcohols and Derivatives and their Applications in Organic Synthesis

(2013) Alexandre Lumbroso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of (+)-Trienomycins A and F via C–C Bond-Forming Hydrogenation and Transfer Hydrogenation

(2013) David J. Del Valle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic carbene (NHC)–copper-catalysed transformations of carbon dioxide

(2013) Liang Zhang et al.   Chemical Science

Carbon dioxide as a carbon source in organic transformation: carbon–carbon bond forming reactions by transition-metal catalysts

(2012) Yasushi Tsuji et al.   CHEMICAL COMMUNICATIONS

Asymmetric homogeneous hydrogenations at scale

(2012) David J. Ager et al.   CHEMICAL SOCIETY REVIEWS

Rhodium-catalysed asymmetric hydrogenation as a valuable synthetic tool for the preparation of chiral drugs

(2012) Pablo Etayo et al.   CHEMICAL SOCIETY REVIEWS

Transition-Metal-Catalyzed Cyclization of Alkynals via Oxametallacycle Intermediates

(2012) Ken Tanaka et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Activation of Vinyl Iodides for the Highly Enantioselective Addition to Aldehydes

(2011) Albert M. DeBerardinis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism and Origins of Regio- and Enantioselectivities in RhI-Catalyzed Hydrogenative Couplings of 1,3-Diynes and Activated Carbonyl Partners: Intervention of a Cumulene Intermediate

(2011) Peng Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Synthesis of Bryostatin 7viaC–C Bond-Forming Hydrogenation

(2011) Yu Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Characterization, and Properties of Anthracene-Bridged Bimetallic Ruthenium Vinyl Complexes [RuCl(CO)(PMe3)3]2(μ-CH═CH-anthracene-CH═CH)

(2011) Ya-Ping Ou et al.   ORGANOMETALLICS

Theoretical studies of regioselectivity of Ni- and Rh-catalyzed C–C bond forming reactions with unsymmetrical alkynes

(2010) Peng Liu et al.   INORGANICA CHIMICA ACTA

Rhodium-Catalyzed Asymmetric Reductive Cyclization of Heteroatom-Linked 5-Alkynals with Heteroatom-Substituted Acetaldehydes

(2010) Rie Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Vinylation of Alcohols or Aldehydes Employing Alkynes as Vinyl Donors: A Ruthenium Catalyzed C−C Bond-Forming Transfer Hydrogenation

(2009) Ryan L. Patman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

ESI-MS, DFT, and Synthetic Studies on the H2-Mediated Coupling of Acetylene: Insertion of C═X Bonds into Rhodacyclopentadienes and Brønsted Acid Cocatalyzed Hydrogenolysis of Organorhodium Intermediates

(2009) Vanessa M. Williams et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Characterization, and Substituent Effects of Binuclear Ruthenium Vinyl Complexes [RuCl(CO)(PMe3)3]2(μ-CHCH−Ar−CHCH)

(2009) Xiang Hua Wu et al.   ORGANOMETALLICS

Catalyst-Directed Diastereoselectivity in Hydrogenative Couplings of Acetylene to α-Chiral Aldehydes: Formal Synthesis of All Eightl-Hexoses

(2008) Soo Bong Han et al.   ORGANIC LETTERS

Ruthenium Complexes with Vinyl, Styryl, and Vinylpyrenyl Ligands:  A Case of Non-innocence in Organometallic Chemistry

(2007) Jörg Maurer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY