Stereo- and Site-Selective Conversion of Primary Alcohols to Allylic Alcohols via Ruthenium-Catalyzed Hydrogen Auto-Transfer Mediated by 2-Butyne

Diastereo- and Enantioselective Ruthenium-Catalyzed C-C Coupling of 1-Arylpropynes and Alcohols: Alkynes as Chiral Allylmetal Precursors in Carbonyl anti-(α-Aryl)allylation

(2021) Ming Xiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio- and Enantioselective Reductive Coupling of Alkynes and Aldehydes via Photoredox Cobalt Dual Catalysis

(2021) Yan-Lin Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Use of Lithium Diisopropylamide in Flow: Operability and Safety Challenges Encountered on a Multigram Scale

(2021) Marta Alonso et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

From Hydrogenation to Transfer Hydrogenation to Hydrogen Auto-Transfer in Enantioselective Metal-Catalyzed Carbonyl Reductive Coupling: Past, Present, and Future

(2021) Catherine Gazolla Santana et al.   ACS Catalysis

Enantioconvergent Arylation of Racemic Secondary Alcohols to Chiral Tertiary Alcohols Enabled by Nickel/N-Heterocyclic Carbene Catalysis

(2021) Yuan Cai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding Halide Counterion Effects in Enantioselective Ruthenium-Catalyzed Carbonyl (α-Aryl)allylation: Alkynes as Latent Allenes and Trifluoroethanol-Enhanced Turnover in The Conversion of Ethanol to Higher Alcohols via Hydrogen Auto-transfer

(2021) Eliezer Ortiz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

What’s Hot, What’s Not: The Trends of the Past 20 Years in the Chemistry of Odorants

(2020) Nicolas Armanino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expedient Synthesis of Ketones via NHC/Nickel-Catalyzed Redox-Economical Coupling of Alcohols and Alkynes

(2020) Yu-Qing Li et al.   CHINESE JOURNAL OF CHEMISTRY

Chemical syntheses and chemical genetics of carboxyl polyether ionophores: Recent highlights

(2019) Han Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Feedstock Reagents in Metal-Catalyzed Carbonyl Reductive Coupling: Minimizing Preactivation for Efficiency in Target-Oriented Synthesis

(2019) Rosalie S. Doerksen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A review and critique of academic lab safety research

(2019) A. Dana Ménard et al.   Nature Chemistry

Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines

(2018) Michael Holmes et al.   CHEMICAL REVIEWS

Improved Safety during Transfer of Pyrophoric tert-Butyllithium from Flasks with Protective Seals

(2018) Martin B. Johansen et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Site-Selective Functionalization of Hydroxyl Groups in Carbohydrate Derivatives

(2018) Victoria Dimakos et al.   CHEMICAL REVIEWS

Nickel/N-Heterocyclic Carbene Complex-Catalyzed Enantioselective Redox-Neutral Coupling of Benzyl Alcohols and Alkynes to Allylic Alcohols

(2018) Yuan Cai et al.   ACS Catalysis

Hydrogen-Mediated C−C Bond Formation: Stereo- and Site-Selective Chemical Synthesis Beyond Stoichiometric Organometallic Reagents

(2017) Leyah A. Schwartz et al.   ISRAEL JOURNAL OF CHEMISTRY

NHC Ligands Tailored for Simultaneous Regio- and Enantiocontrol in Nickel-Catalyzed Reductive Couplings

(2017) Hengbin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Deuteration of Aldehydes with D2O

(2017) Stephen Newman et al.   SYNLETT

Big Data from Pharmaceutical Patents: A Computational Analysis of Medicinal Chemists’ Bread and Butter

(2016) Nadine Schneider et al.   JOURNAL OF MEDICINAL CHEMISTRY

Enantioselective Alcohol C–H Functionalization for Polyketide Construction: Unlocking Redox-Economy and Site-Selectivity for Ideal Chemical Synthesis

(2016) Jiajie Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-catalyzed reductive coupling of olefin-derived nucleophiles: Reinventing carbonyl addition

(2016) Khoa D. Nguyen et al.   SCIENCE

Recent Advances in the Asymmetric Nozaki–Hiyama–Kishi Reaction

(2016) Guozhu Zhang et al.   SYNTHESIS-STUTTGART

Ferrocene-Based Planar Chiral Imidazopyridinium Salts for Catalysis

(2015) Christopher T. Check et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed CC Coupling of Fluorinated Alcohols with Allenes: Dehydrogenation at the Energetic Limit of β-Hydride Elimination

(2015) Brannon Sam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II) and Osmium(II) Vinyl Complexes as Highly Sensitive and Selective Chromogenic and Fluorogenic Probes for the Sensing of Carbon Monoxide in Air

(2015) Anita Toscani et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Ruthenium-Catalyzed Carbonyl Allylation via Alkyne–Alcohol C–C Bond-Forming Transfer Hydrogenation: Allene Hydrometalation vs Oxidative Coupling

(2015) Tao Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic Studies on Aculeximycin: Synthesis of C24–C40 Segment by Kobayashi Aldolization and Epoxide Rearrangements

(2015) Takuya Kato et al.   ORGANIC LETTERS

Catalyst-Directed Diastereo- and Site-Selectivity in Successive Nucleophilic and Electrophilic Allylations of Chiral 1,3-Diols: Protecting-Group-Free Synthesis of Substituted Pyrans

(2014) Inji Shin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Catalyzed Reductive Coupling Reactions of Organic Halides with Carbonyl-Type Compounds

(2014) Toni Moragas et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Redox-Economical Coupling of Alcohols and Alkynes to Form Allylic Alcohols

(2014) Kenichiro Nakai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkynes as Allylmetal Equivalents in Redox-Triggered C–C Couplings to Primary Alcohols: (Z)-Homoallylic Alcohols via Ruthenium-Catalyzed Propargyl C–H Oxidative Addition

(2014) Boyoung Y. Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Polyketide construction via hydrohydroxyalkylation and related alcohol C–H functionalizations: reinventing the chemistry of carbonyl addition

(2014) Anne-Marie R. Dechert-Schmitt et al.   NATURAL PRODUCT REPORTS

Preparation, Properties, and Safe Handling of Commercial Organolithiums: Alkyllithiums, Lithium sec-Organoamides, and Lithium Alkoxides

(2014) Terry ‘Li’ Rathman et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Protecting-Group-Free Diastereoselective CC Coupling of 1,3-Glycols and Allyl Acetate through Site-Selective Primary Alcohol Dehydrogenation

(2013) Anne-Marie R. Dechert-Schmitt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Concise Synthesis of Reduced Propionates by Stereoselective Reductions Combined with the Kobayashi Reaction

(2013) Tatsuya Nakamura et al.   ORGANIC LETTERS

Direct, Redox-Neutral Prenylation and Geranylation of Secondary Carbinol C–H Bonds: C4-Regioselectivity in Ruthenium-Catalyzed C–C Couplings of Dienes to α-Hydroxy Esters

(2012) Joyce C. Leung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

June Sutor and the C–H ··· O hydrogen bonding controversy

(2012) Carl H. Schwalbe   Crystallography Reviews

Activation of Vinyl Iodides for the Highly Enantioselective Addition to Aldehydes

(2011) Albert M. DeBerardinis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Characterization, and Properties of Anthracene-Bridged Bimetallic Ruthenium Vinyl Complexes [RuCl(CO)(PMe3)3]2(μ-CH═CH-anthracene-CH═CH)

(2011) Ya-Ping Ou et al.   ORGANOMETALLICS

Hydrogen/Deuterium Exchange Reactions of Olefins with Deuterium Oxide Mediated by the Carbonylchlorohydrido- tris(triphenylphosphine)ruthenium(II) Complex

(2010) Sunny Kai San Tse et al.   ADVANCED SYNTHESIS & CATALYSIS

LEARNING FROM UCLA

(2010) JYLLIAN KEMSLEY   CHEMICAL & ENGINEERING NEWS

A General Strategy for Regiocontrol in Nickel-Catalyzed Reductive Couplings of Aldehydes and Alkynes

(2010) Hasnain A. Malik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Enantioselective Addition of Alkyne Nucleophiles to Carbonyl Groups

(2009) Barry M. Trost et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct Vinylation of Alcohols or Aldehydes Employing Alkynes as Vinyl Donors: A Ruthenium Catalyzed C−C Bond-Forming Transfer Hydrogenation

(2009) Ryan L. Patman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Characterization, and Substituent Effects of Binuclear Ruthenium Vinyl Complexes [RuCl(CO)(PMe3)3]2(μ-CHCH−Ar−CHCH)

(2009) Xiang Hua Wu et al.   ORGANOMETALLICS

Cobalt- and Nickel-Catalyzed Regio- and Stereoselective Reductive Coupling of Alkynes, Allenes, and Alkenes with Alkenes

(2008) Masilamani Jeganmohan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium Complexes with Vinyl, Styryl, and Vinylpyrenyl Ligands:  A Case of Non-innocence in Organometallic Chemistry

(2007) Jörg Maurer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY