期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 48, 页码 13188-13191出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201406853
关键词
asymmetric catalysis; diazo compounds; iron; small ring systems; spiro compounds
资金
- National Natural Science Foundation of China
- National Basic Research Program of China [2011CB808600]
- 111 project of the Ministry of Education of China [B06005]
- National Program for Support of Top-notch Young Professionals
An iron-catalyzed asymmetric intramolecular cyclopropanation was realized in high yields and excellent enantio-selectivity (up to 97% ee) by using the iron complexes of chiral spiro-bisoxazoline ligands as catalysts. The superiority of iron catalysts exhibited in this reaction demonstrated the potential abilities of this sustainable metal in asymmetric carbenoid transformation reactions.
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