期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 2, 页码 1240-1246出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b02605
关键词
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资金
- Deutsche Forschungsge-meinschaft (DFG, German Research Foundation) [408033718]
- Chinese Scholarship Council
Si-H insertion reactions represent an important method for the efficient construction of new C-Si bonds, and typically, they are conducted in the presence of metal catalysts. In this report, we describe a photochemical approach that now allows the insertion of carbenes into the Si-H bond of silanes under metal-free reaction conditions (23 examples, up to 83% yield).
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