期刊
TETRAHEDRON
卷 76, 期 51, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2020.131316
关键词
Photochemistry; Visible light; Carbenes; N-H insertion; Amides
资金
- CNPq
- Fapesp [2017/24017-0]
A photochemical protocol using blue light allows the N-H insertion of amides, isatins, sulfonamides and imides into aryldiazoacetates to afford the corresponding alpha-amino esters. This method is experimentally simple, inexpensive and tolerates numerous functional groups, thus allowing the straightforward preparation of a variety of alpha-aryl amino acid derivatives in good yields. (C) 2020 Published by Elsevier Ltd.
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