Radical N-heterocyclic carbene catalysis for β-ketocarbonyl synthesis

Enantioselective Iridium-Catalyzed Allylic Alkylation of Racemic Branched Alkyl-Substituted Allylic Acetates with Malonates

(2021) Tian-Yuan Zhang et al.   ORGANIC LETTERS

C–C Bond Acylation of Oxime Ethers via NHC Catalysis

(2021) Hai-Bin Yang et al.   ORGANIC LETTERS

Carbene-Catalyzed Alkylation of Carboxylic Esters via Direct Photoexcitation of Acyl Azolium Intermediates

(2021) Shi-Chao Ren et al.   ACS Catalysis

Direct α-Acylation of Alkenes via N-Heterocyclic Carbene, Sulfinate, and Photoredox Cooperative Triple Catalysis

(2021) Kun Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Benzylic C−H acylation by cooperative NHC and photoredox catalysis

(2021) Qing-Yuan Meng et al.   Nature Communications

Combined Photoredox and Carbene Catalysis for the Synthesis of Ketones from Carboxylic Acids

(2020) Karl Scheidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organophotoredox-Catalyzed Decarboxylative C(sp3)–O Bond Formation

(2020) Shotaro Shibutani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NHC-Catalyzed Radical Trifluoromethylation Enabled by Togni Reagent

(2020) Bei Zhang et al.   ORGANIC LETTERS

N ‐Heterocyclic carbene organocatalysis: activation modes and typical reactive intermediates

(2020) Xingkuan Chen et al.   CHINESE JOURNAL OF CHEMISTRY

N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Synthesis of δ-Ketocarbonyls

(2020) Kenji Ota et al.   ORGANIC LETTERS

Cooperative NHC and Photoredox Catalysis for the Synthesis of β‐Trifluoromethylated Alkyl Aryl Ketones

(2020) Qing-Yuan Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bio- and Medicinally Compatible α-Amino-Acid Modification via Merging Photoredox and N-Heterocyclic Carbene Catalysis

(2020) Ding Du et al.   ORGANIC LETTERS

N-Heterocyclic Carbene-Based Catalysis Enabling Cross-Coupling Reactions

(2020) Hirohisa Ohmiya   ACS Catalysis

Direct Synthesis of Dialkyl Ketones from Aliphatic Aldehydes through Radical N-Heterocyclic Carbene Catalysis

(2020) Yuki Kakeno et al.   ACS Catalysis

Catalytic, Metal-Free Amide Synthesis from Aldehydes and Imines Enabled by a Dual-Catalyzed Umpolung Strategy under Redox-Neutral Conditions

(2020) Ming-Shang Liu et al.   ACS Catalysis

A General Organocatalytic System for Enantioselective Radical Conjugate Additions to Enals

(2020) Emilien Le Saux et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Three-Component 1,2-Cyanoalkylacylation of Alkenes via Radical Relay

(2020) Yu Gao et al.   ORGANIC LETTERS

N-Heterocyclic Carbene/Magnesium Cocatalyzed Radical Relay Assembly of Aliphatic Keto Nitriles

(2020) Lei Chen et al.   ORGANIC LETTERS

N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes

(2019) Takuya Ishii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes

(2019) Takuya Ishii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical Acylfluoroalkylation of Olefins through N-Heterocyclic Carbene Organocatalysis

(2019) Jun-Long Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed Photoenolization/Diels-Alder Reaction of Acid Fluorides

(2019) Andreas Mavroskoufis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalysis via Azolium Dienolates: An Efficient Strategy for Remote Enantioselective Functionalizations

(2018) Xiang-Yu Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A continuing challenge: N-heterocyclic carbene-catalyzed syntheses of γ-butyrolactones

(2018) Kathleen J. R. Murauski et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Synthesis of Chiral α-Azido and α-Aryloxy Quaternary Stereogenic Centers via the Phase-Transfer-Catalyzed α-Alkylation of α-Bromomalonates, Followed by SN2 Substitution

(2017) Doyoung Kim et al.   JOURNAL OF ORGANIC CHEMISTRY

N-Heterocyclic Carbene Catalysis via the α,β-Unsaturated Acyl Azolium

(2017) Changhe Zhang et al.   ACS Catalysis

Recent advances in N-heterocyclic carbene (NHC)-catalysed benzoin reactions

(2016) Rajeev S Menon et al.   Beilstein Journal of Organic Chemistry

Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

(2015) Darrin M. Flanigan et al.   CHEMICAL REVIEWS

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

A Continuum of Progress: Applications of N-Hetereocyclic Carbene Catalysis in Total Synthesis

(2012) Javier Izquierdo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multicomponent and sequential organocatalytic reactions: diversity with atom-economy and enantiocontrol

(2012) Charles M. Marson   CHEMICAL SOCIETY REVIEWS

Low-loading asymmetric organocatalysis

(2011) Francesco Giacalone et al.   CHEMICAL SOCIETY REVIEWS

A Family of Thiazolium Salt Derived N-Heterocyclic Carbenes (NHCs) for Organocatalysis: Synthesis, Investigation and Application in Cross-Benzoin Condensation

(2011) Isabel Piel et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

α-Aroyloxyaldehydes: scope and limitations as alternatives to α-haloaldehydes for NHC-catalysed redox transformations

(2010) Kenneth B. Ling et al.   CHEMICAL COMMUNICATIONS

Organocatalytic cascade reactions as a new tool in total synthesis

(2010) Christoph Grondal et al.   Nature Chemistry

Thiamin Diphosphate Catalysis: Enzymic and Nonenzymic Covalent Intermediates

(2008) Ronald Kluger et al.   CHEMICAL REVIEWS

The advent and development of organocatalysis

(2008) David W. C. MacMillan   NATURE