Carbene-Catalyzed Alkylation of Carboxylic Esters via Direct Photoexcitation of Acyl Azolium Intermediates

Photocatalytic decarboxylative alkylations of C(sp3)-H and C(sp2)-H bonds enabled by ammonium iodide in amide solvent

(2021) Guang-Zu Wang et al.   Science China-Chemistry

Combined Photoredox and Carbene Catalysis for the Synthesis of Ketones from Carboxylic Acids

(2020) Karl Scheidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic Methods Driven by the Photoactivity of Electron-Donor Acceptor Complexes

(2020) Giacomo E. M. Crisenza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NHC-Catalyzed Radical Trifluoromethylation Enabled by Togni Reagent

(2020) Bei Zhang et al.   ORGANIC LETTERS

Photo/N-Heterocyclic Carbene Co-catalyzed Ring Opening and γ-Alkylation of Cyclopropane Enal

(2020) Lei Dai et al.   ORGANIC LETTERS

Generation of Alkyl Radical through Direct Excitation of Boracene-Based Alkylborate

(2020) Yukiya Sato et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Synthesis of δ-Ketocarbonyls

(2020) Kenji Ota et al.   ORGANIC LETTERS

Cooperative NHC and Photoredox Catalysis for the Synthesis of β‐Trifluoromethylated Alkyl Aryl Ketones

(2020) Qing-Yuan Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bio- and Medicinally Compatible α-Amino-Acid Modification via Merging Photoredox and N-Heterocyclic Carbene Catalysis

(2020) Ding Du et al.   ORGANIC LETTERS

Direct Synthesis of Dialkyl Ketones from Aliphatic Aldehydes through Radical N-Heterocyclic Carbene Catalysis

(2020) Yuki Kakeno et al.   ACS Catalysis

Triphenylphosphine-Catalyzed Alkylative Iododecarboxylation with Lithium Iodide under Visible Light

(2020) Ming-Chen Fu et al.   ORGANIC LETTERS

Design and Implementation of a Catalytic Electron Donor–Acceptor Complex Platform for Radical Trifluoromethylation and Alkylation

(2020) Edward J. McClain et al.   ACS Catalysis

Catalytic, Metal-Free Amide Synthesis from Aldehydes and Imines Enabled by a Dual-Catalyzed Umpolung Strategy under Redox-Neutral Conditions

(2020) Ming-Shang Liu et al.   ACS Catalysis

Photocatalytic decarboxylative alkylations mediated by triphenylphosphine and sodium iodide

(2019) Ming-Chen Fu et al.   SCIENCE

N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes

(2019) Takuya Ishii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Redox-Active Nickel Complex that Acts as an Electron Mediator in Photochemical Giese Reactions

(2019) Thomas van Leeuwen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-Free Deaminative Functionalizations of Primary Amines by Photoinduced Single-Electron Transfer

(2019) Jingjing Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible‐Light‐Mediated Charge Transfer Enables C−C Bond Formation with Traceless Acceptor Groups

(2019) Michael J. James et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-Light-Driven Organic Photochemical Reactions in the Absence of External Photocatalysts

(2019) Yi Wei et al.   SYNTHESIS-STUTTGART

Anion‐π interactions in light‐induced reactions. Their role in the amidation of (hetero)aromatic systems with activated N‐aryloxyamides

(2019) Miquel A. Pericàs et al.   CHEMISTRY-A EUROPEAN JOURNAL

N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes

(2019) Takuya Ishii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemical Asymmetric Nickel-Catalyzed Acyl Cross-Coupling

(2019) Eugenio Gandolfo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploiting Imine Photochemistry for Masked N-Centered Radical Reactivity

(2019) Daryl Staveness et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Driven N-Heterocyclic Carbene Catalyzed γ- and ϵ -Alkylation with Alkyl Radicals

(2019) Lei Dai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical Acylfluoroalkylation of Olefins through N-Heterocyclic Carbene Organocatalysis

(2019) Jun-Long Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A continuing challenge: N-heterocyclic carbene-catalyzed syntheses of γ-butyrolactones

(2018) Kathleen J. R. Murauski et al.   CHEMICAL SOCIETY REVIEWS

Direct Stereoselective Installation of Alkyl Fragments at the β-Carbon of Enals via Excited Iminium Ion Catalysis

(2018) Charlie Verrier et al.   ACS Catalysis

Photoinduced Deaminative Borylation of Alkylamines

(2018) Jingjing Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex

(2018) Zhong-Yan Cao et al.   Nature Communications

Stereocontrolled Synthesis of 1,4-Dicarbonyl Compounds by Photochemical Organocatalytic Acyl Radical Addition to Enals

(2018) Giulio Goti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bioinspired Radical Stetter Reaction: Radical Umpolung Enabled by Ion-Pair Photocatalysis

(2018) Tobias Morack et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deaminative Borylation of Aliphatic Amines Enabled by Visible Light Excitation of an Electron Donor-Acceptor Complex

(2018) Frederik Sandfort et al.   CHEMISTRY-A EUROPEAN JOURNAL

What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis?

(2018) Vianney Regnier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-light excitation of iminium ions enables the enantioselective catalytic β-alkylation of enals

(2017) Mattia Silvi et al.   Nature Chemistry

Photoinduced decarboxylative borylation of carboxylic acids

(2017) Alexander Fawcett et al.   SCIENCE

N-Heterocyclic carbene-catalyzed oxidative [3 + 2] annulation of dioxindoles and enals: cross coupling of homoenolate and enolate

(2017) Xiang-Yu Chen et al.   Chemical Science

N-Heterocyclic Carbene Catalysis via the α,β-Unsaturated Acyl Azolium

(2017) Changhe Zhang et al.   ACS Catalysis

N-Heterocyclic Carbene Catalyzed γ-Dihalomethylenation of Enals by Single-Electron Transfer

(2016) Wen Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photochemical Approaches to Complex Chemotypes: Applications in Natural Product Synthesis

(2016) Markus D. Kärkäs et al.   CHEMICAL REVIEWS

Mechanism of the Stereoselective α-Alkylation of Aldehydes Driven by the Photochemical Activity of Enamines

(2016) Ana Bahamonde et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

(2015) Darrin M. Flanigan et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbene-Catalyzed Radical Reactions for Highly Enantioselective β-Hydroxylation of Enals

(2015) Yuexia Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photo-organocatalytic Enantioselective Perfluoroalkylation of β-Ketoesters

(2015) Łukasz Woźniak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals

(2015) Nicholas A. White et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Organocatalytic Alkylation of Aldehydes and Enals Driven by the Direct Photoexcitation of Enamines

(2015) Mattia Silvi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

X-Ray Characterization of an Electron Donor-Acceptor Complex that Drives the Photochemical Alkylation of Indoles

(2014) Sandeep R. Kandukuri et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective N-Heterocyclic Carbene-Catalyzed β-Hydroxylation of Enals Using Nitroarenes: An Atom Transfer Reaction That Proceeds via Single Electron Transfer

(2014) Nicholas A. White et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Enantioselective direct α-alkylation of cyclic ketones by means of photo-organocatalysis

(2014) Elena Arceo et al.   Chemical Science

Visible Light-mediated Direct Arylation of Arenes and Heteroarenes Using Diaryliodonium Salts in the Presence and Absence of a Photocatalyst

(2013) Mamoru Tobisu et al.   CHEMISTRY LETTERS

β-Carbon activation of saturated carboxylic esters through N-heterocyclic carbene organocatalysis

(2013) Zhenqian Fu et al.   Nature Chemistry

Photochemical activity of a key donor–acceptor complex can drive stereoselective catalytic α-alkylation of aldehydes

(2013) Elena Arceo et al.   Nature Chemistry

Enantioselective Activation of Stable Carboxylate Esters as Enolate Equivalents via N-Heterocyclic Carbene Catalysts

(2012) Lin Hao et al.   ORGANIC LETTERS

NHC Catalyzed Oxidations of Aldehydes to Esters: Chemoselective Acylation of Alcohols in Presence of Amines

(2010) Suman De Sarkar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biomimetic Carbene-Catalyzed Oxidations of Aldehydes Using TEMPO

(2008) Joyram Guin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed C-Allylation of Benzoins and an NHC-Catalyzed Three Component Coupling Derived Thereof: Compatibility of NHC- and Pd-Catalysts

(2008) Raphaël Lebeuf et al.   ORGANIC LETTERS

N-Heterocyclic Carbene-Catalyzed Oxidation of Unactivated Aldehydes to Esters

(2008) Brooks E. Maki et al.   ORGANIC LETTERS