On the Structure of Chiral Dirhodium(II) Carboxylate Catalysts: Stereoselectivity Relevance and Insights

Stabilization of a Chiral Dirhodium Carbene by Encapsulation and a Discussion of the Stereochemical Implications

(2016) Christophe Werlé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design and Synthesis of Novel Chiral Dirhodium(II) Carboxylate Complexes for Asymmetric Cyclopropanation Reactions

(2016) Frady G. Adly et al.   CHEMISTRY-A EUROPEAN JOURNAL

Site-selective and stereoselective functionalization of unactivated C–H bonds

(2016) Kuangbiao Liao et al.   NATURE

Enantioselective Intermolecular C–H Functionalization of Allylic and Benzylic sp3 C–H Bonds Using N-Sulfonyl-1,2,3-triazoles

(2016) Robert W. Kubiak et al.   ORGANIC LETTERS

Polymer monolith-supported dirhodium(II)-catalyzed continuous flow cyclopropanation in capillary format †

(2016) Frady G. Adly et al.   TETRAHEDRON LETTERS

Chiral Dirhodium(II) Catalysts for Selective Metal Carbene Reactions

(2015) Yongming Deng et al.   CURRENT ORGANIC CHEMISTRY

Enantioselective cis-β-lactam synthesis by intramolecular C–H functionalization from enoldiazoacetamides and derivative donor–acceptor cyclopropenes

(2015) Xinfang Xu et al.   Chemical Science

Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles

(2014) Frady G. Adly et al.   CHIRALITY

Rh2(S-1,2-NTTL)4: A Novel Rh2(S-PTTL)4Analog With Lower Ligand Symmetry for Asymmetric Synthesis of Chiral Cyclopropylphosphonates

(2014) Frady G. Adly et al.   CHIRALITY

Rh2(R-TPCP)4-Catalyzed Enantioselective [3+2]-Cycloaddition between Nitrones and Vinyldiazoacetates

(2013) Changming Qin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Conversion of Furans to Highly Functionalized Pyrroles

(2013) Brendan T. Parr et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of 2-Arylbicyclo[1.1.0]butane Carboxylates

(2013) Changming Qin et al.   ORGANIC LETTERS

Guide to enantioselective dirhodium(II)-catalyzed cyclopropanation with aryldiazoacetates

(2013) Kathryn M. Chepiga et al.   TETRAHEDRON

Enantio- and diastereoselective hetero-Diels–Alder reactions between 4-methyl-substituted Rawal’s diene and aldehydes catalyzed by chiral dirhodium(II) carboxamidates: catalytic asymmetric synthesis of (−)-cis-aerangis lactone

(2013) Yudai Watanabe et al.   TETRAHEDRON-ASYMMETRY

Rhodium-catalyzed enantioselective cyclopropanation of electron-deficient alkenes

(2013) Hengbin Wang et al.   Chemical Science

Chiral Dirhodium Catalysts: A New Era for Asymmetric Catalysis

(2012) Moteaa El-Deftar et al.   CURRENT ORGANIC CHEMISTRY

Rh2(S-PTTL)3TPA—a mixed-ligand dirhodium(ii) catalyst for enantioselective reactions of α-alkyl-α-diazoesters

(2012) David T. Boruta et al.   Chemical Science

Fine Tuning of Dirhodium(II) Complexes: Exploring the Axial Modification

(2012) Alexandre F. Trindade et al.   ACS Catalysis

Design and Synthesis of Chiral Heteroleptic Rhodium(II) Carboxylate Catalysts: Experimental Investigation of Halogen Bond Rigidification Effects in Asymmetric Cyclopropanation

(2012) Vincent N. G. Lindsay et al.   ACS Catalysis

Rhodium(II)-Catalyzed Cross-Coupling of Diazo Compounds

(2011) Jørn H. Hansen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Cyclopropenation Reaction of 1-Alkynes with α-Alkyl-α-Diazoesters Catalyzed by Dirhodium(II) Carboxylates

(2011) Takayuki Goto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H Functionalization in organic synthesis

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

D2-Symmetric Dirhodium Catalyst Derived from a 1,2,2-Triarylcyclopropanecarboxylate Ligand: Design, Synthesis and Application

(2011) Changming Qin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Rh(II)-Catalyzed Cyclopropanation of Alkenes with Diacceptor Diazo Compounds:p-Methoxyphenyl Ketone as a General Stereoselectivity Controlling Group

(2011) Vincent N. G. Lindsay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined C–H Functionalization/Cope Rearrangement with Vinyl Ethers as a Surrogate for the Vinylogous Mukaiyama Aldol Reaction

(2011) Yajing Lian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Mechanism and Selectivity of the Combined C−H Activation/Cope Rearrangement

(2011) Jørn H. Hansen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Optimizing dirhodium(ii) tetrakiscarboxylates as chiral NMR auxiliaries

(2011) Jens T. Mattiza et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rh2(S-PTAD)4-catalyzed asymmetric cyclopropenation of aryl alkynes

(2011) John F. Briones et al.   TETRAHEDRON

Enantio- and diastereoselective cyclopropanation with tert-butyl α-diazopropionate catalyzed by dirhodium(II) tetrakis[N-tetrabromophthaloyl-(S)-tert-leucinate]

(2011) Takayuki Goto et al.   TETRAHEDRON LETTERS

The chiral crown conformation in paddlewheel complexes

(2010) Andrew DeAngelis et al.   CHEMICAL COMMUNICATIONS

First X-ray Structure of aN-Naphthaloyl-Tethered Chiral Dirhodium(II) Complex: Structural Basis for Tether Substitution Improving Asymmetric Control in Olefin Cyclopropanation

(2010) Ashraf Ghanem et al.   CHEMISTRY-A EUROPEAN JOURNAL

Studies in catalytic C–H amination involving nitrene C–H insertion

(2010) Florence Collet et al.   DALTON TRANSACTIONS

Controlling Factors for C−H Functionalization versus Cyclopropanation of Dihydronaphthalenes

(2010) Etienne Nadeau et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Enantioselective Rh2(S-DOSP)4-Catalyzed Cyclopropenation of Alkynes with Styryldiazoacetates

(2010) John F. Briones et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vinylogous reactivity of silver(i) vinylcarbenoids

(2010) Jørn H. Hansen et al.   Chemical Science

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Application of donor/acceptor-carbenoids to the synthesis of natural products

(2009) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Chiral Crown Conformation of Rh2(S-PTTL)4: Enantioselective Cyclopropanation with α-Alkyl-α-diazoesters

(2009) Andrew DeAngelis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Evidence for the All-Up Reactive Conformation of Chiral Rhodium(II) Carboxylate Catalysts: Enantioselective Synthesis ofcis-Cyclopropane α-Amino Acids

(2009) Vincent N. G. Lindsay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed [3 + 2] Annulation of Indoles

(2009) Yajing Lian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C−C Bond Formation by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement between Donor/Acceptor Carbenoids and Allylic Alcohols

(2009) Zhanjie Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Reactions of Donor/Acceptor Carbenoids Derived from α-Aryl-α-Diazoketones

(2009) Justin R. Denton et al.   ORGANIC LETTERS

Cationic Chiral Dirhodium Carboxamidates Are Activated for Lewis Acid Catalysis

(2008) Yuanhua Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective construction of nitrile-substituted cyclopropanes

(2008) Justin R. Denton et al.   CHEMICAL COMMUNICATIONS

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Catalyzed addition of diazoacetoacetates to imines: synthesis of highly functionalized aziridines

(2008) Xue-jing Zhang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

High symmetry dirhodium(II) paddlewheel complexes as chiral catalysts

(2007) Jørn Hansen et al.   COORDINATION CHEMISTRY REVIEWS