Arylation of Axially Chiral Phosphorothioate Salts by Dinuclear PdI Catalysis

Electrochemically Promoted Nickel-Catalyzed Carbon–Sulfur Bond Formation

(2019) Yang Wang et al.   ACS Catalysis

Nickel-Catalyzed Thiolation of Aryl Halides and Heteroaryl Halides through Electrochemistry

(2019) Dong Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective C-S Bond Formation at C-Br over C-OTf and C-Cl Enabled by an Air-Stable, Easy-to-Recover & Recyclable Pd(I) Catalyst

(2018) Thomas Scattolin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-controlled Fe(Pc)-catalyzed aerobic oxidation of thiols for the synthesis of S–S and S–P(O) bonds

(2018) Hai Huang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Practical Reagents and Methods for Nucleophilic and Electrophilic Phosphorothiolations

(2018) Szabolcs Kovács et al.   ADVANCED SYNTHESIS & CATALYSIS

Modular Functionalization of Arenes in a Triply Selective Sequence: Rapid C(sp2 ) and C(sp3 ) Coupling of C−Br, C−OTf, and C−Cl Bonds Enabled by a Single Palladium(I) Dimer

(2018) Sinead T. Keaveney et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unlocking P(V): Reagents for chiral phosphorothioate synthesis

(2018) Kyle W. Knouse et al.   SCIENCE

Synthesis and application of phosphonothioates, phosphonodithioates, phosphorothioates, phosphinothioates and related compounds

(2018) David J. Jones et al.   TETRAHEDRON LETTERS

Metal- and oxidant-free S–P(O) bond construction via direct coupling of P(O)H with sulfinic acids

(2017) Youngtaek Moon et al.   GREEN CHEMISTRY

Visible-Light-Promoted C–S Cross-Coupling via Intermolecular Charge Transfer

(2017) Bin Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Control of phosphorothioate stereochemistry substantially increases the efficacy of antisense oligonucleotides

(2017) Naoki Iwamoto et al.   NATURE BIOTECHNOLOGY

Room-Temperature Arylation of Thiols: Breakthrough with Aryl Chlorides

(2016) Min Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rapid Room-Temperature, Chemoselective Csp2 −Csp2 Coupling of Poly(pseudo)halogenated Arenes Enabled by Palladium(I) Catalysis in Air

(2016) Indrek Kalvet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of S-Aryl Phosphorothioates by Copper-Catalyzed Phosphorothiolation of Diaryliodonium and Arenediazonium Salts

(2016) Liangliang Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient Pd-Catalyzed Dehydrogenative Coupling of P(O)H with RSH: A Precise Construction of P(O)–S Bonds

(2016) Yueyue Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphorothiolation of Aryl Boronic Acids Using P(O)H Compounds and Elemental Sulfur

(2016) Jian Xu et al.   ORGANIC LETTERS

Highly Efficient CSeCF3Coupling of Aryl Iodides Enabled by an Air-Stable Dinuclear PdICatalyst

(2015) Marialuisa Aufiero et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethylthiolation of Aryl Iodides and Bromides Enabled by a Bench-Stable and Easy-To-Recover Dinuclear Palladium(I) Catalyst

(2015) Guoyin Yin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Computational Studies of Synthetically Relevant Homogeneous Organometallic Catalysis Involving Ni, Pd, Ir, and Rh: An Overview of Commonly Employed DFT Methods and Mechanistic Insights

(2015) Theresa Sperger et al.   CHEMICAL REVIEWS

Peroxide promoted metal-free thiolation of phosphites by thiophenols/disulfides

(2015) Jichao Wang et al.   TETRAHEDRON

Copper(I)-Induced Sulfenylation of H-Phosphonates, H-Phosphonites and Phosphine Oxides with Aryl/alkylsulfonylhydrazides as a Thiol Surrogate

(2014) Gullapalli Kumaraswamy et al.   ADVANCED SYNTHESIS & CATALYSIS

Environmentally benign synthesis and antimicrobial study of novel chalcogenophosphates

(2014) Shubhanjan Mitra et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Copper-catalyzed reductive coupling of aryl sulfonyl chlorides with H-phosphonates leading to S-aryl phosphorothioates

(2014) Jie Bai et al.   CHEMICAL COMMUNICATIONS

Tuning Thiophene with Phosphorus: Synthesis and Electronic Properties of Benzobisthiaphospholes

(2014) Yunyan Qiu et al.   CHEMISTRY-A EUROPEAN JOURNAL

[(IPent)PdCl2(morpholine)]: A Readily Activated Precatalyst for Room-Temperature, Additive-Free Carbon-Sulfur Coupling

(2014) Jennifer L. Farmer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Kinetic and Computational Studies on Pd(I) Dimer-Mediated Halogen Exchange of Aryl Iodides

(2014) Indrek Kalvet et al.   JOURNAL OF ORGANIC CHEMISTRY

New benzotriazole-based reagents for the phosphonylation of various N-, O-, and S-nucleophiles

(2014) Deepak S. Panmand et al.   TETRAHEDRON LETTERS

Room-temperature carbon-sulfur bond formation from Ni(II) σ-aryl complex via cleavage of the S-S bond of disulfide moieties

(2013) Ken Okamoto et al.   APPLIED ORGANOMETALLIC CHEMISTRY

A simple and convenient method for the synthesis of S-aryl phosphorothioates catalyzed by cesium hydroxide

(2013) Yue-Jun Ouyang et al.   CHINESE CHEMICAL LETTERS

N-Chlorosuccinimide-promoted synthesis of thiophosphates from thiols and phosphonates under mild conditions

(2013) Yi-Chen Liu et al.   GREEN CHEMISTRY

A New Family of Nucleophiles for Photoinduced, Copper-Catalyzed Cross-Couplings via Single-Electron Transfer: Reactions of Thiols with Aryl Halides Under Mild Conditions (O °C)

(2013) Christopher Uyeda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon–Heteroatom Coupling Using Pd-PEPPSI Complexes

(2013) Cory Valente et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Copper(I) Iodide Catalyzed Synthesis of Thiophosphates by Coupling of H-Phosphonates with Benzenethiols

(2013) Babak Kaboudin et al.   SYNTHESIS-STUTTGART

Dinuclear Pd(i) complexes—solely precatalysts? Demonstration of direct reactivity of a Pd(i) dimer with an aryl iodide

(2013) Karl J. Bonney et al.   Chemical Science

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereocontrolled Solid-Phase Synthesis of Phosphorothioate Oligoribonucleotides Using 2′-O-(2-Cyanoethoxymethyl)-nucleoside 3′-O-Oxazaphospholidine Monomers

(2012) Yohei Nukaga et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions

(2011) Georgiy Teverovskiy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbon-Sulfur Bond Formation of Challenging Substrates at Low Temperature by Using Pd-PEPPSI-IPent

(2011) Mahmoud Sayah et al.   CHEMISTRY-A EUROPEAN JOURNAL

Resting State and Elementary Steps of the Coupling of Aryl Halides with Thiols Catalyzed by Alkylbisphosphine Complexes of Palladium

(2009) Elsa Alvaro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereocontrolled Synthesis of Oligoribonucleoside Phosphorothioates by an Oxazaphospholidine Approach

(2009) Natsuhisa Oka et al.   ORGANIC LETTERS

Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides

(2008) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Solid-Phase Synthesis of Stereoregular Oligodeoxyribonucleoside Phosphorothioates Using Bicyclic Oxazaphospholidine Derivatives as Monomer Units

(2008) Natsuhisa Oka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY