期刊
CHEMICAL SCIENCE
卷 4, 期 12, 页码 4434-4439出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc52054d
关键词
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资金
- Swiss National Science Foundation
- ETH Zurich
- RWTH Aachen University
- NRW Returning Scholars Program
This report provides experimental, computational and spectroscopic data in support of the direct reactivity of a Pd(I) dimer with an aryl iodide, resulting in Br/I halogen exchange between the complex and the aryl iodide. The reactivity could not be achieved through analogous Pd(0) conditions, demonstrating the distinct reactivities at such multiple Pd-sites. Computational studies support that the direct oxidative addition to ArI by the dinuclear metal complex is energetically feasible.
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