Article
Materials Science, Paper & Wood
Maria Fredriksson, Markus Rueggeberg, Thomas Nord-Larsen, Greeley Beck, Emil Engelund Thybring
Summary: The moisture content of wood cell walls is determined by both environmental conditions and material characteristics of the wood. This study used data exploration to identify the important wood characteristics determining the cell wall moisture content. Chemical composition was found to be the most important predictor of the cell wall moisture content, while in the low moisture range, cellulose crystallinity and hydroxyl accessibility were important predictors, and at high moisture contents, microfibril orientation in the cell walls was important. Overall, no single wood characteristic had a major effect on the cell wall moisture content.
Article
Engineering, Chemical
Nadine M. S. Moubayed, Hadeel Jawad Al-Houri
Summary: Biosorption using marine algae, particularly Spirulina platensis, has been identified as an effective method for removing heavy metals pollution from aqueous solutions. This study highlights the changes that occur on the algal surface during copper adsorption, as well as the functional groups available for copper binding. The Freundlich isotherm model showed a linear plot, indicating spontaneous, endothermic, and entropy favorable sorption behavior. The maximum biosorption rate was found to be 90.6% under specific conditions.
DESALINATION AND WATER TREATMENT
(2022)
Article
Engineering, Chemical
Mukaddes Karatas, Nurhan Arslan
Summary: This study investigated the sorption process of cowpea stored in a chamber with controlled relative humidity. The results showed that cowpea exhibited type III behavior in sorption isotherms and hysteresis effect was observed. Among various models, the Peleg equation provided the best fit for predicting the sorption behavior. The sorption isotherms data were also used to estimate the thermodynamic functions, revealing that the sorption process for cowpea was enthalpy-controlled and nonspontaneous.
JOURNAL OF FOOD PROCESS ENGINEERING
(2022)
Article
Engineering, Chemical
Salah Knani, Nabil Mabrouk, Saleh Toumah Alanazi, Nabil Kechaou
Summary: The modeling of food moisture content is important for predicting product shelf life during storage and packaging. By using a statistical physics formalism, an advanced model was applied to interpret and discuss the sorption isotherm of water into banana. The desorption isotherms, pore size distribution, and energy interpretation provide insights into the microscopic and macroscopic aspects of moisture adsorption and desorption processes.
Article
Engineering, Chemical
Tatiana G. Matuda, Larissa M. Hoshino, Eliana P. Ribeiro, Carmen C. Tadini
Summary: Unripe acerola powders obtained from freeze-drying were analyzed using DSC and vapor sorption isotherms. The presence of polydextrose affected the glass transition and increased stability of the powder. The sorption isotherms showed higher monolayer water content for powders with polydextrose.
JOURNAL OF FOOD ENGINEERING
(2023)
Article
Chemistry, Analytical
Sabiha Hashmi, Arijit Sengupta, Rohit Singh Chauhan
Summary: Dried coconut leaf, exhausted tea leaf, and coffee powder were used for cost effective sorption of UO(2)(2+ )ion from aqueous solution, with coconut leaf showing the highest sorption efficiency. The sorption process was found to be spontaneous, energetically favorable, endothermic, and entropically driven.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
(2021)
Article
Engineering, Environmental
Umesh Fegade, Sachin Kolate, Rajesh Dhake, Inamuddin, Tariq Altalhi, Suvardhan Kanchi
Summary: Size-controlled Pb0.06Fe0.7O3 nanoparticles (Pb-FeONPs) were fabricated by the thermal co-precipitation method and characterized using various techniques. The adsorption of Congo Red (CR) onto Pb-FeONPs was found to follow a pseudo-second-order reaction, with the Langmuir plot showing good fitting and a high Q(max) value. The nanoparticles were successfully regenerated for up to 5 cycles, making them economically viable for wastewater treatment applications.
WATER SCIENCE AND TECHNOLOGY
(2021)
Article
Chemistry, Applied
Yoshiharu Nishiyama
Summary: Polysaccharides, even non-ionic ones, can swell in water and generate significant pressure, which can be utilized for actuation purposes or result in structural damage. The investigation of swelling pressure dates back to the 19th century, with thermodynamic considerations developed in the early 20th century. Recent data suggests that the swelling process is mainly driven by enthalpy. The molecular origin of the heat involved in swelling is discussed, taking into account the specific characteristics of polysaccharides or biopolymers with rigid chain conformations that contradict the compact packing necessary for enthalpy stabilization. The elastic energy stored in the rigid structure is proposed to contribute to the heat of swelling and potential work associated with it, which can be explored in the design of actuation or control of swelling.
CARBOHYDRATE POLYMERS
(2023)
Article
Energy & Fuels
Janakan S. Saral, Dekketi G. C. Vikram Reddy, Panneerselvam Ranganathan
Summary: This study investigated the hydrothermal liquefaction of Spirulina platensis. By developing a kinetic model and calculating the activation energy, it was found that the hydrothermal liquefaction process is feasible for biofuel generation from algal biomass.
BIOMASS CONVERSION AND BIOREFINERY
(2022)
Review
Chemistry, Multidisciplinary
Otheman Amrhar, Lahoucine El Gana, Mohamed Mobarak
Summary: Adsorption is a crucial phenomenon in various scientific disciplines, with adsorption isotherm models based on statistical physics being used to analyze adsorption performance. The discussion typically revolves around steric, energetic, and thermodynamic parameters.
ENVIRONMENTAL CHEMISTRY LETTERS
(2021)
Article
Construction & Building Technology
Brahim Mazhoud, Florence Collet, Sylvie Pretot, Christophe Lanos
Summary: This study experimentally investigates the effects of clay stabilization and hemp content on hygric and thermal performances of composites. It reveals that the designed composites exhibit excellent moisture buffering properties and thermal conductivity suitable for distributed insulation. The linear relationships between hemp content, binder types, density, and water content are identified in this study.
CONSTRUCTION AND BUILDING MATERIALS
(2021)
Article
Forestry
Mojgan Vaziri, Christopher Dreimol, Lars Abrahamsson, Peter Niemz, Dick Sandberg
Summary: This study investigated the wood-water interactions of welded bond-lines of European beech and Scots pine using dynamic vapour sorption equipment. The aim was to understand the water sorption properties of the welded bond-line and how they differ from the unwelded wood. The results showed that the welded wood had lower equilibrium moisture contents and greater hysteresis than the unwelded wood. The diffusion coefficients of adsorption and desorption varied between beech and pine, as well as between welded and unwelded wood.
Article
Environmental Sciences
Lujian Lin, Shuai Tang, Xuesong Wang, Xuan Sun, Ying Liu
Summary: The addition of HBCD increased the sorption ability of PS MPs for TC, with sorption mechanism mainly controlled by film diffusion and intra-particle diffusion. Multiple mechanisms including π-π and hydrophobic interactions jointly regulated the sorption of TC onto both the MPs.
ENVIRONMENTAL POLLUTION
(2021)
Article
Environmental Sciences
Shymaa M. Shalaby, Fedekar F. Madkour, Hala Y. El-Kassas, Adel A. Mohamed, Ahmed M. Elgarahy
Summary: Organic dyes are major pollutants in wastewater effluents globally, impacting public health. Greenly synthesized iron oxide nanoparticles (SP-IONPs) effectively removed dyes from aqueous solutions, showing great potential for wastewater remediation.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Energy & Fuels
Lokesh Kumar, Shefali Tripathi, Kirtiraj K. K. Gaikwad
Summary: A cactus mucilage-gelatin bio-composite film was made using a solution casting method. The effects of citric acid as a crosslinking agent at different concentrations on the film's moisture sorption characteristics and mechanical properties were studied. Results showed that incorporating citric acid reduced the film's moisture content, swelling ratio, water vapor permeability, and moisture sorption tendency. The film with 0.5% citric acid exhibited the best crystallinity and highest tensile strength, making it suitable for food packaging applications.
BIOMASS CONVERSION AND BIOREFINERY
(2023)
Article
Chemistry, Physical
Nadia Bouaziz, Fatma Aouaini, Yosra Ben Torkia, Abeer S. Altowyan, Abdelmottaleb Ben Lamine
Summary: The study investigates the hydrogen absorption properties of LaMgNi3.6M0.4 (M = Al, Mn, Ni, Co, Cu) alloys for hydrogen storage, providing insights into the absorption mechanism and potential for increasing hydrogen absorption capacity. The analysis of absorption energies reveals the significance of the chemical interaction between hydrogen and metals in the hydrogen absorption process.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Engineering, Chemical
Gabriela Saldanha Soares, Scarlet Neves Tuchtenhagen, Luiz Antonio de Almeida Pinto, Carlos Alberto Severo Felipe
Summary: This study aimed to monitor temperature and pressure drop behaviors during the drying of Persian clover and arrowleaf clover seeds in a fluidized bed. The changes observed in temperature and pressure drop profiles were significant and related to the transition between drying periods. Analysis in the frequency domain showed distinct power spectra characteristics, indicating the potential for this technique as an alternative for monitoring drying operations.
Article
Environmental Sciences
Andrei Vallerao Igansi, Patrick Peres da Silva, Jenifer Ines Engelmann, Luiz Antonio de Almeida Pinto, Rafael Lipinski Paes, Tito Roberto Sant'Anna Cadaval Junior
Summary: The study evaluated the production of oil rich in omega-3 from catfish processing wastes, showing positive economic feasibility and profitability, with the quickest return on investment achievable in 1.56 years.
WASTE AND BIOMASS VALORIZATION
(2022)
Article
Engineering, Environmental
Hanjing Xue, Xuemei Wang, Qi Xu, Fatma Dhaouadi, Lotfi Sellaoui, Moaaz K. Seliem, Abdelmottaleb Ben Lamine, Hafedh Belmabrouk, Abdullah Bajahzar, Adrian Bonilla-Petriciolet, Zichao Li, Qun Li
Summary: Activated carbons and MOF-based composites were prepared from ashitaba biomass for the adsorption of methylene blue, and results showed that the surfactant-functionalized activated carbon outperformed other adsorbents with an adsorption capacity exceeding 400 mg/g. This adsorbent shows promising application potential for treating wastewater polluted by dye molecules.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Environmental Sciences
Lotfi Sellaoui, Fatma Dhaouadi, Sonia Taamalli, Hanan Yahya Saeed AlZahrani, Florent Louis, Abderrahman El Bakali, Alessandro Erto, Abdelmottaleb Ben Lamine, Diana Ramos Lima, Eder Claudio Lima, Zhuqi Chen
Summary: The study investigates the adsorption of nicotinamide and propranolol on magnetic-activated carbon, finding that adsorption capacity increases with temperature and propranolol has a higher tendency to form multiple layers. The modeling results suggest that both pharmaceutical compounds adsorb onto the MAC adsorbent via the formation of one or two layers, with propranolol showing a higher tendency for multiple layers. Adsorption energy is estimated to be endothermic, with physical interactions responsible for the adsorption process.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Fatma Aouaini, Nadia Bouaziz, Wafa Alfwzan, Noura Khemiri, Zainab Elqahtani, Abdelmottaleb Ben Lamine
Summary: In this paper, the adsorption phenomenon of carbon dioxide on a synthesized zeolite (ZSM-5) is analyzed using statistical physics treatment and a multilayer model. The results show that CO2 adsorption occurs via a non-parallel orientation on the ZSM-5 surface, and the highest adsorption amount is observed for Zn-ZSM-5. The analysis of the adsorption energies confirms that CO2 adsorption on ZSM-5 zeolite is a physical adsorption phenomenon.
APPLIED SCIENCES-BASEL
(2022)
Article
Engineering, Environmental
Lotfi Sellaoui, Samia Yahyaoui, Sonia Taamalli, Zainab Srour, Dison Franco, Matias Schadeck Netto, Jordana Georgin, Adrian Bonilla-Petriciolet, Florent Louis, Abderrahman El Bakali, Valerie Fevre-Nollet, Guilherme Luiz Dotto, Alessandro Erto, Abdemottaleb Ben Lamine, Zhuqi Chen
Summary: This study investigates the quaternary adsorption of Cu2+, Co2+, Ni2+, and Ag+ ions on an adsorbent derived from alkaline fusion of wastewater treatment sludge. The study reveals that the adsorption of Cu2+, Co2+, and Ni2+ ions is endothermic, while the adsorption of Ag+ ions is exothermic. In the quaternary system, the adsorption of Ag+ ions is significantly reduced due to the competitive effect of other divalent ions, whereas the adsorption capacities of Cu2+, Co2+, and Ni2+ ions are not significantly affected. There is a notable competitive effect of Cu2+, Co2+, and Ni2+ ions on the adsorption of Ag+ ions. Modelling analysis demonstrates that the adsorption of Cu2+, Co2+, and Ni2+ ions is a multi-ionic process at all tested temperatures, while the adsorption of Ag+ ions is a multi-ionic process only at low temperatures. The statistical physics model confirms that the adsorption energies correspond to physical interactions forces and water molecule adsorption plays a crucial role in removing these trace metals.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Environmental Sciences
Mery L. G. Vieira, Claudio P. Pinheiro, Keli A. Silva, Tito R. S. Cadaval, Guilherme L. Dotto, Luiz A. A. Pinto
Summary: In this study, glass particles were coated with bioblends of Spirulina sp. LEB-18/chitosan for potential use as adsorbents for acid and basic dyes. The coated particles showed high removal percentages for both types of dyes in batch adsorption and exhibited good adsorption capacities in fixed bed column operation. These bioblends coated glass particles can be applied as effective adsorbents for different types of dyes in adsorption column.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Engineering, Chemical
Valeria V. L. Carvalho, Diana Pinto, Nina P. G. Salau, Luiz A. A. Pinto, Tito R. S. Cadaval, Luis F. O. Silva, Toni J. Lopes, Guilherme L. Dotto
Summary: The use of smart packaging is a global trend, and this study focuses on the adsorption of anthocyanins onto chitosan films. The Freundlich model and PVSDM model were used to represent the adsorption data and elucidate the mass transfer. The results showed that the mechanisms inside the particle controlled the adsorption process.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Chemistry, Applied
Jenifer Ines Engelmann, Bruna Silva de Farias, Andrei Vallerao Igansi, Patrick Peres Silva, Tito Roberto Santana Cadaval Jr, Marcos Alexandre Gelesky, Valeria Terra Crexi, Luiz Antonio de Almeida Pinto
Summary: Chitosan nanocapsules containing polyunsaturated fatty acid concentrates from tuna oil with EPA and DHA were developed and their particle size and zeta potential were evaluated. It was found that chitosan concentration and stirring speed significantly affected the particle size and zeta potential of the nanocapsules. The nanocapsules prepared with 1.5-2% chitosan showed improved physical characteristics and oxidative stability, making them suitable for application in the food industry.
FOOD SCIENCE AND TECHNOLOGY INTERNATIONAL
(2023)
Article
Food Science & Technology
Vanessa Barbosa da Silva, Andrei Vallerao Igansi, Patrick Peres da Silva, Jenifer Ines Engelmann, Tito Roberto Sant'Anna Cadaval Jr, Luiz Antonio de Almeida Pinto
Summary: This study aimed to extract oil from catfish heads using CO2 supercritical fluid (SFE-CO2), with varying conditions of extraction time, temperature, and pressure. The yield of crude oil from catfish heads using thermal-mechanical extraction was 86%, with concentrations of EPA and DHA at 9.0% and 11.9% respectively. Supercritical extraction resulted in a yield of 84% at 25 MPa and 40°C in 3 hours, with lower concentrations of EPA and DHA at 2.1% and 9.1% respectively. The highest EPA and DHA concentration of 18.3% was achieved at 25 MPa, 40°C, and 1 hour. The oil obtained through SFE-CO2 showed similar characteristics to oil obtained through thermal-mechanical extraction and chemical refinement, suggesting its potential as a sustainable food production method through green technology.
INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY
(2023)
Article
Biotechnology & Applied Microbiology
Andrei Vallerao Igansi, Patrick Peres da Silva, Jenifer Ines Engelmann, Paola Silveira Moraes, Nauro da Silveira, Ricardo Goncalves de Faria Correa, Joana Siqueira de Souza, Luiz Antonio de Almeida Pinto, Rafael Lipinski Paes, Tito Roberto Sant'Anna Cadaval
Summary: Waste from the fish processing industry can be used to produce profitable biofuels and fishmeal. The study highlights the potential of neutralized tilapia oil as a valuable raw material for biodiesel production. Economic evaluation shows that biodiesel and fishmeal production is economically attractive in large-scale plants.
BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR
(2023)
Article
Chemistry, Physical
Joelma Roda Zitha Vilanculos, Bruna Silva de Farias, Jenifer Ines Engelmann, Eduardo Silveira Ribeiro, Patricia Diaz de Oliveira, Tito Roberto Sant'Anna Cadaval Jr, Luiz Antonio de Almeida Pinto
Summary: This study aimed to develop new delivery carriers based on chitosan-xanthan gum nanoemulsions with tuna oil. The results showed that electrostatic interactions between chitosan and xanthan gum improved the electrostatic stability of the nanoemulsions, while the increased viscosity due to xanthan gum reduced the diffusivity of dissolved oxygen and increased the oxidative stability. Moreover, electrostatic interactions between chitosan and xanthan gum increased the steric and oxidative stabilities of the nanoemulsions.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Multidisciplinary Sciences
Bruna Silva de Farias, Francisca Zuchoski Rizzi, Eduardo Silveira Ribeiro, Patricia Silva Diaz, Tito Roberto Sant'Anna Cadaval Junior, Guilherme Luiz Dotto, Mohammad Rizwan Khan, Salim Manoharadas, Luiz Antonio de Almeida Pinto, Glaydson Simoes dos Reis
Summary: This study explores the fabrication of nanofibers using different types of gelatins, highlighting their potential to produce nanofibers with distinct physicochemical properties.
SCIENTIFIC REPORTS
(2023)
Article
Biotechnology & Applied Microbiology
Marcos Aurelio Dahlem Junior, Wendell Dall Agnol, Natalia Neitzke, Adriani Cristina Felipe dos Santos, Vanessa Mendonca Esquerdo, Daniel Neutzling Lehn, Luiz Antonio de Almeida Pinto, Claucia Fernanda Volken de Souza
Summary: This study aims to develop an encapsulation method using dairy by-products as wall materials to protect chia oil. The results showed that the mixture of cheese whey and whey permeate exhibited the highest encapsulation efficiency and ability to protect the chia seed oil.
FOOD TECHNOLOGY AND BIOTECHNOLOGY
(2022)
Article
Biotechnology & Applied Microbiology
Mohamad Rais Hasan, Che Azurahanim Che Abdullah, Mustapha Nor Afizah, Mohd Sabri Mohd Ghazali, Mohd Adzahan Noranizan
Summary: This study evaluates the efficacy of ultrasound in the extraction process of calcium hydroxyapatite (HAp). The findings show that low-intensity and moderate-intensity ultrasonication reduce the whiteness index and yield of HAp, while high-intensity ultrasonication reduces particle size and improves crystallinity.
FOOD AND BIOPRODUCTS PROCESSING
(2024)
Article
Biotechnology & Applied Microbiology
Barbara Flaibam, Rosana Goldbeck
Summary: This study evaluated the possibility of extracting proteins and obtaining hydrolysates from non-animal agro-industrial waste using enzymes for the production of cultured meat inputs. Results showed that the application of enzymes can maximize the use of protein from these wastes, providing a low-cost and environmentally friendly route with nutritional potential for cultured meat.
FOOD AND BIOPRODUCTS PROCESSING
(2024)
Article
Biotechnology & Applied Microbiology
Robson Costa de Sousa, Ariany Binda Silva Costa, Marcos Daniel Martins Freitas, Maisa Tonon Bitti Perazzini, Hugo Perazzini
Summary: This study investigated the drying kinetics of black pepper through experimental and mathematical modeling approaches. The models developed provided valuable insights into the coupling between heat and mass transfers during the drying process, and accurately described the drying behavior of black pepper.
FOOD AND BIOPRODUCTS PROCESSING
(2024)
Article
Biotechnology & Applied Microbiology
Ali Nikkhah, Hasan Nikkhah, Amir Shahbazi, Mona Kamelan Zargar Zarin, Duygu Beykal Iz, Mohammad-Taghi Ebadi, Mohammad Fakhroleslam, Burcu Beykal
Summary: Cumin and eucalyptus essential oils were enriched to meet ISO standards using a dynamic fractional distillation process. The optimization results showed low operating costs and potential for improving process efficiency.
FOOD AND BIOPRODUCTS PROCESSING
(2024)
Article
Biotechnology & Applied Microbiology
Sakshi Gupta, Gargi Ghoshal
Summary: A study was conducted to prepare green gram protein hydrogel enriched with curcumin and evaluate its physicochemical properties. The results showed that the hydrogel had high encapsulation efficiency, swelling capacity, and antioxidant property. Furthermore, applying the hydrogel as a coating on tomatoes and apples proved to be effective.
FOOD AND BIOPRODUCTS PROCESSING
(2024)
Article
Biotechnology & Applied Microbiology
Calvin Lo, Rene H. Wijffels, Michel H. M. Eppink
Summary: This study developed a novel strategy to separate dissolved oils from imidazole/hexanoic acid mixture and regenerate the solvent using polar antisolvents. By adding small amounts of water and methanol, high recovery of lipids was achieved, while ethanol required a large amount and caused solvent dilution.
FOOD AND BIOPRODUCTS PROCESSING
(2024)
Article
Biotechnology & Applied Microbiology
Manoj Sawale, Patnarin Benyathiar, Pablo Coronel, Ajay Rawat, Josip Simunovic, Ferhan Ozadali, Dharmendra K. Mishra
Summary: Microwave and ohmic heating are popular choices for aseptic processing due to their rapid heating capabilities and better product quality. This study aims to find an alternative approach to simulate processing conditions by modeling and validating the process using surrogate particles and microorganisms. A mathematical model was used to simulate heat transfer in fluid and solid particles. The process was validated using simulated particles and surrogate microorganisms, with magnetic implants in spherical particles to measure residence time distribution. The microwave aseptic system was successfully validated for producing shelf-stable particulate food products.
FOOD AND BIOPRODUCTS PROCESSING
(2024)