Organocatalytic Synthesis of Optically Active Organophosphorus Compounds

Catalytic Asymmetric 1,2-Addition of α-Isothiocyanato Phosphonates: Synthesis of Chiral β-Hydroxy- or β-Amino-Substituted α-Amino Phosphonic Acid Derivatives

(2014) Yi-Ming Cao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Access to Enantioenriched Dihydropyran Phosphonates via an Inverse-Electron-Demand Hetero-Diels–Alder Reaction

(2014) Christian F. Weise et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalytic Asymmetric Synthesis of Chiral Phosphonates

(2014) Ana Maria Faísca Phillips   MINI-REVIEWS IN ORGANIC CHEMISTRY

Cinchona-derived thiourea catalyzed hydrophosphonylation of ketimines—an enantioselective synthesis of α-amino phosphonates

(2014) Akshay Kumar et al.   TETRAHEDRON

Asymmetric organocatalytic conjugate addition of dialkyl phosphites to N-unprotected isatylidene malononitriles: access to 3-phospho-2-oxindoles with chiral quaternary stereocenters

(2014) Zhao-Min Liu et al.   TETRAHEDRON

Regioselective asymmetric stereoablative O-alkylation of α-nitrophosphonates via o-azaxylylene intermediates generated in situ from 3-bromooxindoles

(2014) Xiaohua Xie et al.   RSC Advances

Enantioselective Synthesis of α-Amino-γ-sulfonyl Phosphonates with a Tetrasubstituted Chiral α-CarbonviaQuinine-Squaramide-Catalyzed Michael Addition of Nitrophosphonates to Vinyl Sulfones

(2013) Kalisankar Bera et al.   ADVANCED SYNTHESIS & CATALYSIS

A Catalytic Michael/Horner-Wadsworth-Emmons Cascade Reaction for Enantioselective Synthesis of Thiochromenes

(2013) Abhijnan Ray Choudhury et al.   ADVANCED SYNTHESIS & CATALYSIS

When asymmetric aminocatalysis meets the vinylogy principle

(2013) Igor D. Jurberg et al.   CHEMICAL COMMUNICATIONS

A Synthetic Study of Chiral α-Hydroxy-H-Phosphinates Based on Proline Catalysis

(2013) Qiuli Yao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Inverse-Electron-Demand Hetero-Diels-Alder Reactions Catalyzed by Modularly Designed Organocatalysts

(2013) Debarshi Sinha et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Efficient Organocatalysis: A One-Pot Highly Enantioselective Synthesis of α-Aminophosphonates

(2013) Prashant B. Thorat et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Organocatalytic Asymmetric Allylic Alkylation of Morita-Baylis-Hillman Carbonates with Phosphorus Ylides: Synthesis of Chiral 3-Substituted 2,4-Functionalized 1,4-Pentadienes

(2013) Aijun Lin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Michael Addition of 4-Hydroxycoumarins to β,γ-Unsaturated α-Oxophosphonates Catalysed by a Bifunctional Squaramide Bearing a Structurally Rigid 9,10-Ethylene-9,10-dihydroanthracene Skeleton

(2013) Xufang Chang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Organocatalytic Synthesis of α-Cyclopropylphosphonates through a Domino Michael Addition/Intramolecular Alkylation Reaction

(2013) Ana Maria Faísca Phillips et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Stereodivergent Michael addition of diphenylphosphite to α-nitroalkenes in the presence of squaramide-derived tertiary amines: an enantioselective organocatalytic reaction in supercritical carbon dioxide

(2013) Ilya V. Kuchurov et al.   GREEN CHEMISTRY

Asymmetric Synthesis of β-Hydroxy-α-amino Phosphonic Acid Derivatives via Organocatalytic Direct Aldol Reaction of α-Isothiocyanato Phosphonates with Aldehydes

(2013) Wen-Yong Han et al.   JOURNAL OF ORGANIC CHEMISTRY

First example of quinine-squaramide catalyzed enantioselective addition of diphenyl phosphite to ketimines derived from isatins

(2013) Jimil George et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Organocatalytic enantioselective hydrophosphonylation of aldehydes

(2013) Juan V. Alegre-Requena et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Highly Enantioselective Michael Addition of α-Substituted Nitrophosphonates to a Vinyl Sulfone

(2013) Yixin Lu et al.   SYNTHESIS-STUTTGART

Aminocatalytic asymmetric Diels–Alder reaction of phosphorus dienophiles and 2,4-dienals

(2013) Qing-Qing Zhou et al.   TETRAHEDRON

Construction of highly substituted pyrazole derivatives with P–C bond: access to racemic and enantioselective forms by conjugate addition of diarylphosphane oxides to α,β-unsaturated pyrazolones

(2013) Zhi-Cong Geng et al.   TETRAHEDRON

Organocatalyzed asymmetric Michael reaction of β-aryl-α-ketophosphonates and nitroalkenes

(2013) Jie Guang et al.   TETRAHEDRON LETTERS

Cinchona based squaramide catalysed enantioselective Michael addition of α-nitrophosphonates to aryl acrylates: enantioselective synthesis of quaternary α-aminophosphonates

(2013) Truong Son Pham et al.   TETRAHEDRON-ASYMMETRY

Aminocatalytic remote functionalization strategies

(2013) Hao Jiang et al.   Chemical Science

Highly Enantioselective Preparation of Fluorinated Phosphonates by Michael Addition of α-Fluoro-β-ketophosphonates to Nitroalkenes

(2013) Jacek Kwiatkowski et al.   Asian Journal of Organic Chemistry

Aminocatalytic Asymmetric Diels–Alder Reactions via HOMO Activation

(2012) Jun-Long Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Cyanation of α-Ketiminophosphonates Catalyzed byCinchonaAlkaloids: Enantioselective Synthesis of Tetrasubstituted α-Aminophosphonic Acid Derivatives from Trisubstituted α-Aminophosphonates

(2012) Javier Vicario et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Domino Nitro-Michael/Horner-Wadsworth-Emmons Reaction for Disubstituted Cyclohexenecarboxylate Annulation: Efficient Synthesis of Dipeptidyl Peptidase IV Inhibitor ABT-341 and Influenza Neuraminidase Inhibitor

(2012) Jiang Weng et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Synthesis of Tertiary α-Hydroxy Phosphonates Catalyzed by Carbohydrate/Cinchona Alkaloid Thiourea Organocatalysts

(2012) Shasha Kong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Highly Functionalized Phosphonate-Substituted Pyrans or Dihydropyrans Through Asymmetric [4+2] Cycloaddition of β,γ-Unsaturated α-Ketophosphonates with Allenic Esters

(2012) Cheng-Kui Pei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cinchona-based Primary Amine Catalysis in the Asymmetric Functionalization of Carbonyl Compounds

(2012) Paolo Melchiorre   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Catalyzed Direct Aldolization of α-Alkyl-α-Hydroxy Trialkyl Phosphonoacetates

(2012) Michael T. Corbett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organophosphorus Reagents in Organocatalysis: Synthesis of Optically Active α-Methylene-δ-lactones and δ-Lactams

(2012) Anna Albrecht et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Michael addition of 3-aryloxindoles to a vinyl bisphosphonate ester catalyzed by a cinchona alkaloid derived thiourea catalyst

(2012) Mei-Xin Zhao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric trienamine catalysis: new opportunities in amine catalysis

(2012) Indresh Kumar et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Synthesis of Quaternary α-Aminophosphonates via Conjugate Addition of α-Nitrophosphonates to Enones

(2012) Kalisankar Bera et al.   ORGANIC LETTERS

Acetylphosphonate as a Surrogate of Acetate or Acetamide in Organocatalyzed Enantioselective Aldol Reactions

(2012) Jie Guang et al.   ORGANIC LETTERS

Catalytic Asymmetric Synthesis of α,β-Disubstituted α,γ-Diaminophosphonic Acid Precursors by Michael Addition of α-Substituted Nitrophosphonates to Nitroolefins

(2012) Chandra Bhushan Tripathi et al.   ORGANIC LETTERS

The Diarylprolinol Silyl Ether System: A General Organocatalyst

(2011) Kim L. Jensen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Organocatalytic Enantioselective Sulfenylation of β-Keto Phosphonates: A Convenient Approach to Construct Hetero- Quaternary Stereocenters

(2011) Aijun Lin et al.   ADVANCED SYNTHESIS & CATALYSIS

Organocatalytic Highly Enantioselective Synthesis of β-Formyl-α-hydroxyphosphonates

(2011) Sandun Perera et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Phospha-Michael Reaction of Diphenyl Phosphonate with Nitroolefins Utilizing Conformationally Flexible Guanidinium/Bisthiourea Organocatalyst: Assembly-State Tunability in Asymmetric Organocatalysis

(2011) Yoshihiro Sohtome et al.   ADVANCED SYNTHESIS & CATALYSIS

Modulating the Acidity: Highly Acidic Brønsted Acids in Asymmetric Catalysis

(2011) Magnus Rueping et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Organocatalytic Electrophilic Phosphination

(2011) Martin Nielsen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Simple Recipe for Sophisticated Cocktails: Organocatalytic One-Pot Reactions-Concept, Nomenclature, and Future Perspectives

(2011) Łukasz Albrecht et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Brønsted acids in enantioselective carbonyl activations – activation modes and applications

(2011) Magnus Rueping et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in metal catalyzed asymmetric addition of phosphorus nucleophiles

(2011) Depeng Zhao et al.   CHEMICAL SOCIETY REVIEWS

Recyclable Tertiary Amine Modified Diarylprolinol Ether as Aminocatalyst for the Sequential Asymmetric Synthesis of Functionalized Cyclohexanes and Chromenes

(2011) Hao Shen et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Chiral Thiourea-Catalyzed Asymmetric Michael Addition of β-Oxo Phosphonate to Nitro Olefins: Convenient Synthesis of Optically Active β-Oxo Phosphonates

(2011) Kuang Hu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Recent Advances in the Synthesis of α-Alkylidene-Substituted δ-Lactones, γ-Lactams and δ-Lactams

(2011) Anna Albrecht et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Organocatalyzed Synthesis of Tertiary α-Hydroxyphosphonates by a Highly Regioselective Modified Pudovik Reaction

(2011) Maria Teresa Barros et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Organocatalyzed Enantioselective Michael Addition of 2-Hydroxy-1,4-naphthoquinone to β,γ-Unsaturated α-Ketophosphonatesθ

(2011) Tao Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthetic Application and Structural Elucidation of Axially Chiral Dicarboxylic Acid: Asymmetric Mannich-type Reaction with Diazoacetate, (Diazomethyl)phosphonate, and (Diazomethyl)sulfone

(2011) Takuya Hashimoto et al.   JOURNAL OF ORGANIC CHEMISTRY

Trienamines in Asymmetric Organocatalysis: Diels−Alder and Tandem Reactions

(2011) Zhi-Jun Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thiourea catalyzed organocatalytic enantioselective Michael addition of diphenyl phosphite to nitroalkenes

(2011) Ana Alcaine et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of geminal bisphosphonates via organocatalyzed enantioselective Michael additions of cyclic ketones and 4-piperidones

(2011) Ana Maria Faísca Phillips et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A one-pot catalysis: the strategic classification with some recent examples

(2011) Nitin T. Patil et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Organocatalytic Asymmetric Michael-Type/Wittig Reaction of Phosphorus Ylides: Synthesis of Chiral α-Methylene-δ-Ketoesters

(2011) Aijun Lin et al.   ORGANIC LETTERS

Quinidine thiourea-catalyzed enantioselective synthesis of β-nitrophosphonates: beneficial effects of molecular sieves

(2011) Santhi Abbaraju et al.   TETRAHEDRON

Highly effective and enantioselective Phospho-Aldol reaction of diphenyl phosphite with N-alkylated isatins catalyzed by quinine

(2011) Lin Peng et al.   TETRAHEDRON LETTERS

Enantioselective Mannich reaction of a highly reactive Horner–Wadsworth–Emmons reagent with imines catalyzed by a bifunctional thiourea

(2011) Depeng Zhao et al.   Chemical Science

Enantioselective organocatalytic phospha-Michael reaction of α,β-unsaturated aldehydes

(2011) Xiaoyan Luo et al.   RSC Advances

Enantioselective organocatalytic phospha-Michael reaction of α,β-unsaturated ketones

(2010) Shigang Wen et al.   CHEMICAL COMMUNICATIONS

Enantioselective construction of allylic phosphine oxides through substitution of Morita–Baylis–Hillman carbonates with phosphine oxides

(2010) Liang Hong et al.   CHEMICAL COMMUNICATIONS

Asymmetric Organocatalytic Conjugate Addition of Diarylphosphane Oxides to Chalcones

(2010) Alessio Russo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Acyl Phosphonates: Good Hydrogen Bond Acceptors and Ester/Amide Equivalents in Asymmetric Organocatalysis

(2010) Hao Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sequential one-pot combination of multi-component and multi-catalysis cascade reactions: an emerging technology in organic synthesis

(2010) Dhevalapally B. Ramachary et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Base-Accelerated Enantioselective Substitution of Morita−Baylis−Hillman Carbonates with Dialkyl Phosphine Oxides

(2010) Wangsheng Sun et al.   ORGANIC LETTERS

Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations

(2010) Masahiro Terada   SYNTHESIS-STUTTGART

N-Carbamate α-aminoalkyl-p-tolylsulfones—convenient substrates in the nitro-Mannich synthesis of secondary N-carbamate protected syn-2-amino-1-nitroalkanephosphonates

(2010) Roman Błaszczyk et al.   TETRAHEDRON

Enantioselective Michael addition of diethyl cyanomethylphosphonate to chalcones using bifunctional cinchona-derived organocatalysts: synthesis of chiral precursors of α-substituted β-aminophosphonates

(2010) Truong Son Pham et al.   TETRAHEDRON-ASYMMETRY

Squaramide-Catalyzed Enantioselective Michael Addition of Diphenyl Phosphite to Nitroalkenes

(2009) Ye Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High-Yielding Synthesis of the Anti-Influenza Neuramidase Inhibitor (−)-Oseltamivir by Three “One-Pot” Operations

(2009) Hayato Ishikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Phosphonylation of Aromatic Azaheterocycles

(2009) Sarah Van der Jeught et al.   CHEMICAL REVIEWS

Organocatalytic Asymmetric Synthesis of Organophosphorus Compounds

(2009) Łukasz Albrecht et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organocatalytic Formation of Quaternary Stereocenters

(2009) Marco Bella et al.   SYNTHESIS-STUTTGART

Catalytic Enantioselective Hydrophosphonylation of Aldehydes and Imines

(2008) Pedro Merino et al.   ADVANCED SYNTHESIS & CATALYSIS

Modularly Designed Organocatalytic Assemblies for Direct Nitro-Michael Addition Reactions

(2008) Tanmay Mandal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Aminocatalysis-Gold Rush in Organic Chemistry

(2008) Paolo Melchiorre et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Organocatalysis: From Infancy to Adolescence

(2008) Alessandro Dondoni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION