When asymmetric aminocatalysis meets the vinylogy principle

Zwitterions and Unobserved Intermediates in Organocatalytic Diels–Alder Reactions of Linear and Cross-Conjugated Trienamines

(2013) Arne Dieckmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Organocatalytic Thio-Diels–Alder Reactions via Trienamine Catalysis

(2013) Hao Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 9-amino(9-deoxy)epi cinchona alkaloids, general chiral organocatalysts for the stereoselective functionalization of carbonyl compounds

(2013) Carlo Cassani et al.   Nature Protocols

Aminocatalytic Asymmetric exo-Diels–Alder Reaction with Methiodide Salts of Mannich Bases and 2,4-Dienals to Construct Chiral Spirocycles

(2013) Shan-Jun Zhang et al.   ORGANIC LETTERS

Aminocatalytic remote functionalization strategies

(2013) Hao Jiang et al.   Chemical Science

Aminocatalytic Asymmetric Diels–Alder Reactions via HOMO Activation

(2012) Jun-Long Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

Dienamine-Mediated Inverse-Electron-Demand Hetero-Diels-Alder Reaction by Using an Enantioselective H-Bond-Directing Strategy

(2012) Łukasz Albrecht et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aminocatalytic Enantioselective 1,6 Additions of Alkyl Thiols to Cyclic Dienones: Vinylogous Iminium Ion Activation

(2012) Xu Tian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Cyclobutanes by a Formal [2+2] Cycloaddition Controlled by Dienamine Catalysis

(2012) Alejandro Parra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Dienamine/Hydrogen-Bonding Catalysis: Enantioselective Formal [2+2] Cycloaddition of Enals with Nitroalkenes

(2012) Garazi Talavera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Concise Assembly of Electron-Deficient 2,4-Dienes and 2,4-Dienals: Regio- and Stereoselectiveexo-Diels-Alder and Redox Reactions through Sequential Amine and Carbene Catalysis

(2012) Chao Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Activation of Polycyclic Aromatic Compounds for Asymmetric Diels-Alder Reactions

(2012) Hao Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Extending the Aminocatalytic HOMO-Raising Activation Strategy: Where Is the Limit?

(2012) Elena Arceo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cinchona-based Primary Amine Catalysis in the Asymmetric Functionalization of Carbonyl Compounds

(2012) Paolo Melchiorre   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trienamine Catalysis with 2,4-Dienones: Development and Application in Asymmetric Diels-Alder Reactions

(2012) Xiao-Feng Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed Oxidative Macrolactonization: Total Synthesis of (+)-Dactylolide

(2012) Kiyoun Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic 1,4-Addition Reaction of α,β-γ,δ-Diunsaturated Aldehydes versus 1,6-Addition Reaction

(2012) Yujiro Hayashi et al.   ChemCatChem

Fluorinated Organocatalysts for the Enantioselective Epoxidation of Enals: Molecular Preorganisation by the Fluorine-Iminium Ion Gauche Effect

(2012) Eva-Maria Tanzer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Secondary Amine-Catalyzed Asymmetricγ-Alkylation ofα-Branched EnalsviaDienamine Activation

(2012) Mattia Silvi et al.   HELVETICA CHIMICA ACTA

Enantioselective Organocatalytic Intramolecular Diels–Alder Reactions: A Computational Study

(2012) Filipe J. S. Duarte et al.   JOURNAL OF ORGANIC CHEMISTRY

Curtin–Hammett Paradigm for Stereocontrol in Organocatalysis by Diarylprolinol Ether Catalysts

(2012) Jordi Burés et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-trienamines in Asymmetric Organocatalysis

(2012) Kim Søholm Halskov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio-, Diastereo-, and Enantioselective 1,6- and 1,8-Additions of Azlactones to Di- and Trienyl N-Acylpyrroles

(2012) Daisuke Uraguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Organocatalytic Formal [2 + 2]-Cycloadditions via Bifunctional H-Bond Directing Dienamine Catalysis

(2012) Łukasz Albrecht et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric trienamine catalysis: new opportunities in amine catalysis

(2012) Indresh Kumar et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantio- and Diastereoselective Synthesis of Substituted Tetrahydro-1H-isochromanes through a Dynamic Kinetic Resolution Proceeding under Dienamine Catalysis

(2012) Ane Orue et al.   ORGANIC LETTERS

Asymmetric Vinylogous Aldol Reaction via H-Bond-Directing Dienamine Catalysis

(2012) David Bastida et al.   ORGANIC LETTERS

Direct Catalytic Enantioselective Vinylogous Aldol Reaction of α-Branched Enals with Isatins

(2012) Carlo Cassani et al.   ORGANIC LETTERS

Multicatalytic Asymmetric Synthesis of Complex Tetrahydrocarbazoles via a Diels–Alder/Benzoin Reaction Sequence

(2012) Yankai Liu et al.   ORGANIC LETTERS

Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Propargylic Allylation of Propargylic Alcohols with α,β-Unsaturated Aldehydes

(2012) Masahiro Ikeda et al.   ORGANOMETALLICS

Asymmetric Diels–Alder reaction of β,β-disubstituted enals and chromone-fused dienes: construction of collections with high molecular complexity and skeletal diversity

(2012) Jun-Long Li et al.   Chemical Science

The Diarylprolinol Silyl Ether System: A General Organocatalyst

(2011) Kim L. Jensen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Organocatalytic 1,6-Conjugate Addition of Aldehydes to Dienic Sulfones

(2011) John J. Murphy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Catalytic Asymmetric Knoevenagel Condensation

(2011) Anna Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

exo-Selective Asymmetric Diels-Alder Reaction of 2,4-Dienals and Nitroalkenes by Trienamine Catalysis

(2011) Zhi-Jun Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Vinylogous Aldol and Related Addition Reactions: Ten Years of Progress†

(2011) Giovanni Casiraghi et al.   CHEMICAL REVIEWS

Squaramides: physical properties, synthesis and applications

(2011) R. Ian Storer et al.   CHEMICAL SOCIETY REVIEWS

Asymmetric Trienamine Catalysis for the Construction of Structurally Rigid Cyclic α,α-Disubstituted Amino Acid Derivatives

(2011) Hao Jiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Squaramides: Bridging from Molecular Recognition to Bifunctional Organocatalysis

(2011) José Alemán et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Aziridination of α,β-Unsaturated Aldehydes

(2011) Luca Deiana et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dienamine Activation in the Organocatalytic Asymmetric Synthesis of cis-3,4-Difunctionalized Chromans and Dihydrocoumarins

(2011) Dieter Enders et al.   Chemistry-An Asian Journal

Dienamine Catalysis: An Emerging Technology in Organic Synthesis

(2011) Dhevalapally B. Ramachary et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Organocatalyzed Michael Addition of Aldehydes to Nitro Alkenes - Generally Accepted Mechanism Revisited and Revised

(2011) Krystyna Patora-Komisarska et al.   HELVETICA CHIMICA ACTA

Mechanistic Rationalization of Organocatalyzed Conjugate Addition of Linear Aldehydes to Nitro-olefins

(2011) Jordi Burés et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Catalysis of Diels–Alder Reactions with in Situ Generated Heterocyclicortho-Quinodimethanes

(2011) Yankai Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trienamines in Asymmetric Organocatalysis: Diels−Alder and Tandem Reactions

(2011) Zhi-Jun Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Collective synthesis of natural products by means of organocascade catalysis

(2011) Spencer B. Jones et al.   NATURE

Recent advances in asymmetric catalysis with cinchona alkaloid-based primary amines

(2011) Lin Jiang et al.   Catalysis Science & Technology

Organocatalytic Asymmetric Inverse-Electron-Demand Diels-Alder Reaction of Electron-Deficient Dienes and Crotonaldehyde

(2010) Jun-Long Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Direct Vinylogous Aldol Reaction of Furanone Derivatives Catalyzed by an Axially Chiral Guanidine Base

(2010) Hitoshi Ube et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Disulfonimide-Catalyzed Asymmetric Vinylogous and Bisvinylogous Mukaiyama Aldol Reactions

(2010) Lars Ratjen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Emil Knoevenagel and the Roots of Aminocatalysis

(2010) Benjamin List   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Organocatalysis for the Asymmetric γ Alkylation of α-Branched Enals

(2010) Giulia Bergonzini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aminocatalytic asymmetric inverse-electron-demand aza-Diels–Alder reaction of N-Ts-1-aza-1,3-butadienes based on coumarin cores

(2010) Jun-Long Li et al.   CHEMICAL COMMUNICATIONS

Mechanisms in aminocatalysis

(2010) Martin Nielsen et al.   CHEMICAL COMMUNICATIONS

Conjugate addition reactions of carbon nucleophiles to electron-deficient dienes

(2010) Aurelio G. Csákÿ et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium/Chiral Diene-Catalyzed Asymmetric 1,6-Addition of Arylboroxines to α,β,γ,δ-Unsaturated Carbonyl Compounds

(2010) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic cascade reactions as a new tool in total synthesis

(2010) Christoph Grondal et al.   Nature Chemistry

Asymmetric Epoxidation of α-Substituted Acroleins Catalyzed by Diphenylprolinol Silyl Ether

(2010) Bojan P. Bondzic et al.   ORGANIC LETTERS

Enantioselective α- and γ-Alkylation of α,β-Unsaturated Aldehydes Using Dienamine Activation

(2010) Julian Stiller et al.   ORGANIC LETTERS

Direct asymmetric vinylogous Michael addition of cyclic enones to nitroalkenes via dienamine catalysis

(2010) G. Bencivenni et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Diels–Alder reaction conducted within the parameters of aqueous organocatalysis: still just smoke and mirrors

(2010) G. Neil Stowe et al.   TETRAHEDRON LETTERS

Organocatalytic Regio- and Stereoselective Inverse-Electron-Demand Aza-Diels-Alder Reaction of α,β-Unsaturated Aldehydes andN-Tosyl-1-aza-1,3-butadienes

(2009) Bo Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Alkylation of Aldehydes by SN1-Type Reaction of Alcohols

(2009) Pier Giorgio Cozzi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

In Situ Enamine Activation in Aqueous Salt Solutions: Highly Efficient Asymmetric Organocatalytic Diels-Alder Reaction of Cyclohexenones with Nitroolefins

(2009) Dan-Qian Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Targeting Structural and Stereochemical Complexity by Organocascade Catalysis: Construction of Spirocyclic Oxindoles Having Multiple Stereocenters

(2009) Giorgio Bencivenni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Organocatalytic Cascade Reactions with α-Substituted α,β-Unsaturated Aldehydes

(2009) Patrizia Galzerano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic enantioselective construction of all-carbon quaternary stereocenters by an organocatalytic Diels–Alder reaction of α-substituted α,β-unsaturated aldehydes

(2009) Taichi Kano et al.   CHEMICAL COMMUNICATIONS

Direct Asymmetric Michael Addition to Nitroalkenes: Vinylogous Nucleophilicity under Dinuclear Zinc Catalysis

(2009) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Carbon−Carbon Bond Formation γ to a Carbonyl Group: Phosphine-Catalyzed Addition of Nitromethane to Allenes

(2009) Sean W. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Crossed Intramolecular Rauhut−Currier-Type Reactions via Dienamine Activation

(2009) Eugenia Marqués-López et al.   ORGANIC LETTERS

Asymmetric Michael Addition of γ,γ-Disubstituted α,β-Unsaturated Aldehydes to Nitroolefins via Dienamine Catalysis

(2009) Bo Han et al.   ORGANIC LETTERS

A Short Route to α‐Tocopherol

(2008) Kegang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amine-Catalyzed Cyclizations of Tethered α,β-Unsaturated Carbonyl Compounds

(2008) Renata Marcia de Figueiredo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Enantioselective, Brønsted Acid Catalyzed, Vinylogous Mannich Reaction

(2008) Marcel Sickert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regiodivergent 1,4 versus 1,6 Asymmetric Copper-Catalyzed Conjugate Addition

(2008) Hélène Hénon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Aminocatalysis-Gold Rush in Organic Chemistry

(2008) Paolo Melchiorre et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Inverse-Electron-Demand Aza-Diels-Alder Reaction ofN-Sulfonyl-1-aza-1,3-butadienes and Aldehydes

(2008) Bo Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation and X-Ray Structures of Reactive Intermediates of Organocatalysis with Diphenylprolinol Ethers and with Imidazolidinones

(2008) Dieter Seebach et al.   HELVETICA CHIMICA ACTA

Chiral Squaramide Derivatives are Excellent Hydrogen Bond Donor Catalysts

(2008) Jeremiah P. Malerich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalysis Lost: Modern Chemistry, Ancient Chemistry, and an Unseen Biosynthetic Apparatus

(2007) Carlos F. Barbas   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective 1,6-Conjugate Addition of Grignard Reagents to Linear Dienoates

(2007) Tim den Hartog et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION