Neighboring Acetal-Assisted Brønsted-Acid-Catalyzed Si-H Bond Activation: Divergent Synthesis of Functional Siloxanes through Silylation and Hydrolytic Oxidation of Organosilanes

The First General, Highly Enantioselective Lewis Base Organo- catalyzed Hydrosilylation of Benzoxazinones and Quinoxalinones

(2010) Zhou-Yang Xue et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Synthesis with Silicon-Based Bulky Amino Organocatalysts

(2010) Li-Wen Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Silicon-Based Cross-Coupling Reactions in the Total Synthesis of Natural Products

(2010) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction to Selective Functionalization of C−H Bonds

(2010) Robert H. Crabtree   CHEMICAL REVIEWS

Formamidines - Versatile Ligands for Zinc-Catalyzed Hydrosilylation and Iron-Catalyzed Epoxidation Reactions

(2010) Stephan Enthaler et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed (Z)-Trialkylsilylation of Terminal Olefins

(2010) Biao Lu et al.   JOURNAL OF ORGANIC CHEMISTRY

Si−H Bond Activation of Alkynylsilanes by Group 4 Metallocene Complexes

(2010) Martin Lamač et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide

(2010) Andreas Berkefeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cationic Silane σ-Complexes of Ruthenium with Relevance to Catalysis

(2010) Dmitry V. Gutsulyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu24O24Si8R8: Organic Soluble 56-Membered Copper(I) Siloxane Cage and Its Use in Homogeneous Catalysis

(2010) Gengwen Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Si–O coupling of alcohols

(2010) Andreas Weickgenannt et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Bis(pyridyl)siloxane Oligomeric Ligands for Palladium(II) Acetate: Synthesis and Binding Properties

(2010) Michael N. Missaghi et al.   ORGANOMETALLICS

Convenient Enantioselective Hydrosilylation of Ketones Catalyzed by Zinc-Macrocyclic Oligoamine Complexes

(2009) Jadwiga Gajewy et al.   ADVANCED SYNTHESIS & CATALYSIS

A Convenient and Efficient Rhenium-Catalyzed Hydrosilylation of Ketones and Aldehydes

(2009) Hailin Dong et al.   ADVANCED SYNTHESIS & CATALYSIS

Ruthenium-Catalyzed CH Bond Activation of Michael Acceptors: An Unusual Reactivity Leading to Allylsilanes

(2009) Marc-Olivier Simon et al.   ADVANCED SYNTHESIS & CATALYSIS

Construction of Heterocycle ScaffoldsviaTransition Metal- Catalyzedsp2CH Functionalization

(2009) Ming Zhang   ADVANCED SYNTHESIS & CATALYSIS

The Photochemical Irradiation of R3SiH in the Presence of [(η5-C5H5)Fe(CO)2CH3] in DMF Leads to Disiloxanes not Disilanes

(2009) Hemant K. Sharma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal Silylenes Generated by Double Silicon-Hydrogen Activation: Key Intermediates in the Rhodium-Catalyzed Hydrosilylation of Ketones

(2009) Nathanaëlle Schneider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric SiO Coupling of Simple Achiral Silanes and Chiral Donor-Functionalized Alcohols

(2009) Andreas Weickgenannt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Water as green oxidant: a highly selective conversion of organosilanes to silanols with water

(2009) Bhanu P. S. Chauhan et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

(2009) Ramesh Giri et al.   CHEMICAL SOCIETY REVIEWS

Potassiumtert-Butoxide-Catalyzed Dehydrogenative SiO Coupling: Reactivity Pattern and Mechanism of an Underappreciated Alcohol Protection

(2009) Andreas Weickgenannt et al.   Chemistry-An Asian Journal

1,1′-Binaphthyldiamine-Based Lewis Bases as Readily Available and Efficient Organocatalysts for the Reduction ofN-Aryl andN-Alkyl Ketimines

(2009) Stefania Guizzetti et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

B(C6F5)3-Catalyzed Reduction of Ketones and Imines Using Silicon-Stereogenic Silanes: Stereoinduction by Single-Point Binding

(2009) Daniel T. Hog et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

New Chiral Lewis Bases Derived from L-Pipecolinic Acid Showing Stereocontrol Highly Dependent on the Catalyst Design in the Hydrosilylation ofN-Phenyl Ketimines

(2009) Juan F. Collados et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Influence of Lewis Acid and Solvent in the Hydrosilylation of Aldehydes and Ketones with Et3SiH; Tris(pentafluorophenyl)borane B(C6F5)3 versus Metal Triflates [M(OTf)3; M = Sc, Bi, Ga, and Al] - Mechanistic Implications

(2009) Peter Bach et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Transition-Metal-Catalyzed Hydroarylation Reactions of Alkynes Through Direct Functionalization of C-H Bonds: A Convenient Tool for Organic Synthesis

(2009) Tsugio Kitamura   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Hydrosilylation of functionalised olefins catalysed by rhodium siloxide complexes in ionic liquids

(2009) Hieronim Maciejewski et al.   GREEN CHEMISTRY

Asymmetric hydrogenation using Wilkinson-type rhodium complexes immobilized onto mesoporous silica

(2009) Reine Sayah et al.   GREEN CHEMISTRY

Catalyst-free silylation of alcohols and phenols by promoting HMDS in CH3NO2as solvent

(2009) Santosh T. Kadam et al.   GREEN CHEMISTRY

Lewis Base-Promoted Hydrosilylation of Cyclic Malonates: Synthesis of β-Substituted Aldehydes and γ-Substituted Amines

(2009) Christopher G. Frost et al.   JOURNAL OF ORGANIC CHEMISTRY

Formation of Two- and Three-Dimensional Hybrid Mesostructures from Branched Siloxane Molecules

(2009) Shigeru Sakamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling Reactions of Aromatic and Heteroaromatic Silanolates with Aromatic and Heteroaromatic Halides

(2009) Scott E. Denmark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Organic−Inorganic Hybrid Gels from Siloxane or Silsesquioxane and α,ω-Nonconjugated Dienes by Means of a Photo Hydrosilylation Reaction

(2009) Naofumi Naga et al.   MACROMOLECULES

Thermotropic Liquid Crystalline Polyimides with Siloxane Linkages: Synthesis, Characterization, and Liquid Crystalline Behavior

(2009) Yu Shoji et al.   MACROMOLECULES

Si−H Bond Activation by Electrophilic Phosphinidene Complexes

(2009) Kandasamy Vaheesar et al.   ORGANOMETALLICS

An efficient and simple method for the preparation of symmetrical disiloxanes from hydrosilanes by Lewis acid-catalyzed air oxidation

(2009) Madabhushi Sridhar et al.   TETRAHEDRON LETTERS

Catalytic Deprotonative Functionalization of Propargyl Silyl Ethers with Imines

(2008) Hiroshi Naka et al.   ADVANCED SYNTHESIS & CATALYSIS

Supported Silver-Nanoparticle-Catalyzed Highly Efficient Aqueous Oxidation of Phenylsilanes to Silanols

(2008) Takato Mitsudome et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation

(2008) Sebastian Rendler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Alcohol Silylation by Dehydrogenative Si-O Coupling: Scope, Limitations, and Mechanism of the Cu-H-Catalyzed Non-Enzymatic Kinetic Resolution with Silicon-Stereogenic Silanes

(2008) Sebastian Rendler et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Acid Hydrolysis Mechanism of Acetals Catalyzed by a Supramolecular Assembly in Basic Solution

(2008) Michael D. Pluth et al.   JOURNAL OF ORGANIC CHEMISTRY

Dehydrogenative Cyclocondensation of Aldehydes, Alkynes, and Dialkylsilanes

(2008) Ryan D. Baxter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane

(2008) Betül Karatas et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Tandem Silylformylation−Crotylsilylation/Tamao Oxidation of Internal Alkynes: A Remarkable Example of Generating Complexity from Simplicity

(2008) Jared T. Spletstoser et al.   ORGANIC LETTERS

An Efficient Copper−Aluminum Hydrotalcite Catalyst for Asymmetric Hydrosilylation of Ketones at Room Temperature

(2008) M. Lakshmi Kantam et al.   ORGANIC LETTERS

Homogeneous silicone modified primary amine-Brønsted acid salt catalyzed aldol reaction: unexpected synergistic effect of polysiloxane with remarkable improvement of efficiency and stereoselectivity

(2008) Li-Wen Xu et al.   TETRAHEDRON LETTERS

Rapid Assembly of Complex 3D Siloxane Architectures

(2007) David B. Thompson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly efficient indium-catalyzed chemoselective allylation–etherification and reductive etherification of aromatic aldehydes with functional silanes

(2007) Ming-Song Yang et al.   TETRAHEDRON LETTERS