Synthesis, Structure and Reactivity of Iridium Hydrido Fluorido Complexes

C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales

(2011) Eric Clot et al.   ACCOUNTS OF CHEMICAL RESEARCH

Facile oxidative addition of water at iridium: reactivity of trans-[Ir(4-C5NF4)(H)(OH)(PiPr3)2] towards CO2 and NH3

(2011) Paul Kläring et al.   DALTON TRANSACTIONS

Nickel(ii) hydride and fluoride pincer complexes and their reactivity with Lewis acids BX3·L (X = H, L = thf; X = F, L = Et2O)

(2011) Andrea Rossin et al.   DALTON TRANSACTIONS

C-F Bond Activation of Highly Fluorinated Molecules at Rhodium: From Model Reactions to Catalysis

(2011) Thomas Braun et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Net Oxidative Addition of C(sp3)-F Bonds to Iridium via Initial C-H Bond Activation

(2011) J. Choi et al.   SCIENCE

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluoropyridine

(2010) David Breyer et al.   DALTON TRANSACTIONS

Cross coupling reactions of polyfluoroarenes via C–F activation

(2010) Alex D. Sun et al.   DALTON TRANSACTIONS

Synthesis and characterisation of some iridium-carbonyl-fluoride complexes. Crystal structures of [IrF(CO){P(C6H4-2-CH3)3}2] and [IrF2(COD)py2][BF4]

(2010) John Fawcett et al.   DALTON TRANSACTIONS

Stabilisation of iridium(iii) fluoride complexes with NHCs

(2010) John Fawcett et al.   DALTON TRANSACTIONS

Palladium-Catalyzed C−F Activation of Polyfluoronitrobenzene Derivatives in Suzuki−Miyaura Coupling Reactions

(2010) Matthew R. Cargill et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides

(2010) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Activation of theorthoC−F Bond in Pentafluoropyridine by Zerovalent Nickel: Reaction via a Metallophosphorane Intermediate Stabilized by Neighboring Group Assistance from the Pyridyl Nitrogen

(2010) Ainara Nova et al.   ORGANOMETALLICS

The Organometallic Fluorine Chemistry of Palladium and Rhodium: Studies toward Aromatic Fluorination

(2009) Vladimir V. Grushin   ACCOUNTS OF CHEMICAL RESEARCH

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Activation of ethylene and ammonia at iridium: C–H versus N–H oxidative addition

(2009) Marcel Ahijado Salomon et al.   DALTON TRANSACTIONS

Synthesis and reactivity of palladium(II) fluoride complexes containing nitrogen-donor ligands

(2009) Nicholas D. Ball et al.   DALTON TRANSACTIONS

Conversion of Carbon-Fluorine Bonds α to Transition Metal Centers to Carbon-Hydrogen, Carbon-Carbon, and Carbon-Heteroatom Bonds

(2009) Russell P. Hughes   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

trans-Difluoro Complexes of Palladium(II)

(2009) Vladimir V. Grushin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex

(2009) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Versatile Pd(OTf)2·2H2O-Catalyzedortho-Fluorination Using NMP as a Promoter

(2009) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Combined Experimental and Computational Study of Unexpected C−F Bond Activation Intermediates and Selectivity in the Reaction of Pentafluorobenzene with a (PEt3)2Ni Synthon

(2009) Samuel A. Johnson et al.   ORGANOMETALLICS

Selective Platinum-Catalyzed C−F Bond Activation as a Route to Fluorinated Aryl Methyl Ethers

(2009) Heather L. Buckley et al.   ORGANOMETALLICS

User-Friendly Precatalyst for the Methylation of Polyfluoroaryl Imines

(2009) Heather L. Buckley et al.   ORGANOMETALLICS

Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides

(2009) D. A. Watson et al.   SCIENCE

Iridium derivatives of fluorinated aromatics by C–H activation: isolation of classical and non-classical hydrides

(2008) Marcel Ahijado Salomon et al.   DALTON TRANSACTIONS

Carbon−Fluorine Reductive Elimination from a High-Valent Palladium Fluoride

(2008) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unexpected Intermediates and Products in the C−F Bond Activation of Tetrafluorobenzenes with a Bis(triethylphosphine)Nickel Synthon: Direct Evidence of a Rapid and Reversible C−H Bond Activation by Ni(0)

(2008) Samuel A. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations

(2008) Thomas Schaub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Competing C−F Activation Pathways in the Reaction of Pt(0) with Fluoropyridines: Phosphine-Assistance versus Oxidative Addition

(2008) Ainara Nova et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insight into the Mechanism of Platinum-Catalyzed Cross-Coupling of Polyfluoroaryl Imines

(2008) Tongen Wang et al.   ORGANOMETALLICS

Xenon Difluoride Induced Aryl Iodide Reductive Elimination:  a Simple Access to Difluoropalladium(II) Complexes

(2007) Ariela W. Kaspi et al.   INORGANIC CHEMISTRY