A Decade of Octacyanides in Polynuclear Molecular Materials

A Docosanuclear {Mo8Mn14} Cluster Based on [Mo(CN)7]4−

(2010) Xin-Yi Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A new family of oxime-based hexanuclear manganese(iii) single molecule magnets with high anisotropy energy barriers

(2010) Adrian-Raul Tomsa et al.   CHEMICAL COMMUNICATIONS

Cobalt(ii) single-molecule magnets

(2010) Mark Murrie   CHEMICAL SOCIETY REVIEWS

Strategies towards single-chain magnets

(2010) Hao-Ling Sun et al.   COORDINATION CHEMISTRY REVIEWS

{MnII9WV6}nNanowires Organized into Three-Dimensional Hybrid Network of I1O2Topology

(2010) Robert Podgajny et al.   CRYSTAL GROWTH & DESIGN

Octacyanotungstate(v)-based square W2M2 (M = Co, Mn) complexes: synthesis, structure and magnetic properties

(2010) Jun Wang et al.   DALTON TRANSACTIONS

Heterotrimetallic 3d-4d-4f decanuclear metal-capped square showing single-molecule magnet behavior

(2010) Jérôme Long et al.   DALTON TRANSACTIONS

Humidity-Sensitive Magnet Composed of a Cyano-Bridged CoII-NbIV Dimetallic Assembly

(2010) Kenta Imoto et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Syntheses, Crystal Structures, and the Phase Transformation of Octacyanometallate-Based LnIII-WV Bimetallic Assemblies with Two-Dimensional Corrugated Layers

(2010) Ai-Hua Yuan et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Magneto-Structural Correlations in Discrete MnII-WV Cyano-Bridged Assemblies with Polyimine Ligands

(2010) Robert Podgajny et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Manganese(II)-Octacyanometallate(V) Bimetallic Ferrimagnets withTcfrom 41 to 53 K Obtained in Acidic Media

(2010) Tian-Wei Wang et al.   INORGANIC CHEMISTRY

Efficient Synthetic Strategy to Construct Three-Dimensional 4f−5d Networks Using Neutral Two-Dimensional Layers As Building Blocks

(2010) Hu Zhou et al.   INORGANIC CHEMISTRY

Magnetic Properties versus Network Dimensionality of Cerium(III) Octacyanotungstate(V) Compounds

(2010) Marcin Kozieł et al.   INORGANIC CHEMISTRY

Series of MI[Co(bpy)3][Mo(CN)8]·nH2O (MI= Li (1), K (2), Rb (3), Cs (4);n= 7−8) Exhibiting Reversible Diamagnetic to Paramagnetic Transition Coupled with Dehydration−Rehydration Process

(2010) Marcin Kozieł et al.   INORGANIC CHEMISTRY

Eicosanuclear Cluster [Cu13W7] of Copper-Octacyanotungstate Bimetallic Assembly: Synthesis, Structure, and Magnetic Properties

(2010) Jun Wang et al.   INORGANIC CHEMISTRY

Nature of Magnetic Interactions in 3D {[MII(pyrazole)4]2[NbIV(CN)8]·4H2O}n(M = Mn, Fe, Co, Ni) Molecular Magnets

(2010) Dawid Pinkowicz et al.   INORGANIC CHEMISTRY

Enhanced Ion Anisotropy by Nonconventional Coordination Geometry: Single-Chain Magnet Behavior for a [{FeIIL}2{NbIV(CN)8}] Helical Chain Compound Designed with Heptacoordinate FeII

(2010) Thengarai S. Venkatakrishnan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Critical behavior of two molecular magnets probed by complementary experiments

(2010) M. Czapla et al.   PHYSICAL REVIEW B

Design and synthesis of metal–organic frameworks using metal–organic polyhedra as supermolecular building blocks

(2009) John J. Perry IV et al.   CHEMICAL SOCIETY REVIEWS

Secondary building units, nets and bonding in the chemistry of metal–organic frameworks

(2009) David J. Tranchemontagne et al.   CHEMICAL SOCIETY REVIEWS

Photoreversible Switching of Magnetic Coupling in a Two-dimensional Copper Octacyanomolybdate

(2009) Hiroko Tokoro et al.   CHEMISTRY LETTERS

Diamond- and Graphite-Like Octacyanometalate-Based Polymers Induced by Metal Ions

(2009) Ying Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

First Heterotrimetallic {3 d-4 d-4 f} Single Chain Magnet, Constructed from Anisotropic High-Spin Heterometallic Nodes and Paramagnetic Spacers

(2009) Diana Visinescu et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Secondary Reagent-Assisted Synthesis of A Novel NiII−MoIVChiral Coordination Polymer

(2009) Wen Zhang et al.   CRYSTAL GROWTH & DESIGN

Heterobimetallic Tungsten/Molybdenum(IV)−Copper(II) MOFs Constructed by a Unique 2D → 3D Architecture and Exhibiting New Topology and Magnetic Properties

(2009) Jun Qian et al.   CRYSTAL GROWTH & DESIGN

1-D hydrogen-bonded organization of hexanuclear {3d-4f-5d} complexes: evidence for slow relaxation of the magnetization for [{LMe2Ni(H2O)Ln(H2O)4.5}2{W(CN)8}2] with Ln = Tb and Dy

(2009) Sébastien Dhers et al.   CRYSTENGCOMM

Towards high Tc octacyanometalate-based networks

(2009) Barbara Sieklucka et al.   CRYSTENGCOMM

Magnetization-induced second harmonic generation in a three-dimensional manganese octacyanoniobate-based pyroelectric ferrimagnet

(2009) Yoshihide Tsunobuchi et al.   CRYSTENGCOMM

Molecules based on M(v) (M = Mo, W) and Ni(ii) ions: a new class of trigonal bipyramidal cluster and confirmation of SMM behavior for the pentadecanuclear molecule {NiII[NiII(tmphen)(MeOH)]6[Ni(H2O)3]2[μ-CN]30[WV(CN)3]6}

(2009) Matthew G. Hilfiger et al.   DALTON TRANSACTIONS

Iron Spin-Crossover compounds: from fundamental studies to practical applications

(2009) Patrick Gamez et al.   DALTON TRANSACTIONS

Iron(II)-octacyanoniobate(IV) ferromagnet with TC 43 K

(2009) Dawid Pinkowicz et al.   DALTON TRANSACTIONS

New photomagnetic cyanido-bridged CuII–MoIV oligonuclear complexes: slight modification of the blocking ligands induces different structures

(2009) Catalin Maxim et al.   DALTON TRANSACTIONS

Some suggested perspectives for multifunctional hybrid porous solids

(2009) Gérard Férey   DALTON TRANSACTIONS

Magnetostructural Correlations in CuII−NC−WVLinkage: The Case of [CuII(diimine)]2+−[WV(CN)8]3−0D Assemblies

(2009) Tomasz Korzeniak et al.   INORGANIC CHEMISTRY

Octacyanometalate-Based Ferrimagnetic MVMnIII(M = Mo, W) Bimetallic Chain Racemates with Slow Magnetic Relaxations

(2009) Houng Sik Yoo et al.   INORGANIC CHEMISTRY

Vanadium Octacyanoniobate-Based Magnet with a Curie Temperature of 138 K

(2009) Wataru Kosaka et al.   INORGANIC CHEMISTRY

Hetero-Metallic {3d-4f-5d} Complexes: Preparation and Magnetic Behavior of Trinuclear [(LMe2Ni−Ln){W(CN)8}] Compounds (Ln = Gd, Tb, Dy, Ho, Er, Y; LMe2= Schiff base) and Variable SMM Characteristics for the Tb Derivative

(2009) Jean-Pascal Sutter et al.   INORGANIC CHEMISTRY

Luminescent and Magnetic Cyano-Bridged Coordination Polymers Containing 4d−4f Ions: Toward Multifunctional Materials

(2009) Elena Chelebaeva et al.   INORGANIC CHEMISTRY

Slow Dynamics of the Magnetization in One-Dimensional Coordination Polymers: Single-Chain Magnets

(2009) Hitoshi Miyasaka et al.   INORGANIC CHEMISTRY

1D Ladder-Like Structure Motif Assembled from Edge-Sharing Rhombic Squares of Sm2Mo2 Based on [Mo(CN)8]4− and Sm3+ Ions as Building Blocks

(2009) Shu-Lin Ma et al.   Journal of Inorganic and Organometallic Polymers and Materials

Photoinduced Magnetization on Mo Ion in Copper Octacyanomolybdate: An X-ray Magnetic Circular Dichroism Investigation

(2009) Marie-Anne Arrio et al.   Journal of Physical Chemistry C

Two new cyanide-bridged complexes, {[Cu(men)2][Ni(CN)4]} n and [Mn(bpy)2]4[Mo(CN)8]2·0.5MeOH·0.75H2O: Syntheses and crystal structures

(2009) X. Chen et al.   JOURNAL OF STRUCTURAL CHEMISTRY

Electric-Field-Induced Charge-Transfer Phase Transition: A Promising Approach Toward Electrically Switchable Devices

(2009) Tarik Mahfoud et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Large Magnetization-Induced Second Harmonic Generation in an Enantiopure Chiral Magnet

(2009) Cyrille Train et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A high-spin cyanide-bridged Mo6Mn9 cluster: crystal structure and magnetism

(2009) Shu-Lin Ma et al.   STRUCTURAL CHEMISTRY

Three-Dimensional Manganese Octacyanoniobate-Based Pyroelectric Ferrimagnet

(2008) Wataru Kosaka et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Crystal Structure, Charge-Transfer-Induced Spin Transition, and Photoreversible Magnetism in a Cyano-Bridged Cobalt−Tungstate Bimetallic Assembly

(2008) Shin-ichi Ohkoshi et al.   CHEMISTRY OF MATERIALS

Thermal and Light-Induced Spin Crossover Phenomena in New 3D Hofmann-Like Microporous Metalorganic Frameworks Produced As Bulk Materials and Nanopatterned Thin Films

(2008) Gloria Agustí et al.   CHEMISTRY OF MATERIALS

Ferrimagnetic Heisenberg Chains Derived From [M(CN)8]3−(M=MoV, WV) Building-Blocks

(2008) Stefania Tanase et al.   CHEMPHYSCHEM

Dissimilar supramolecular organization for the heterotrimetallic assemblage [{LNiLn}{W(CN)8}] with Ln=Y and La (L=Schiff-base derivative)

(2008) Jean-Pascal Sutter et al.   COMPTES RENDUS CHIMIE

Three-dimensional bimetallic octacyanidometalates [MIV{(μ-CN)4MnII(H2O)2}2·4H2O]n (M=Nb, Mo, W): Synthesis, single-crystal X-ray diffraction and magnetism

(2008) Juan Manuel Herrera et al.   COMPTES RENDUS CHIMIE

Reversible photomagnetic properties of the molecular compound [{CuII(bipy)2}2{MoIV(CN)8}]·9H2O·CH3OH

(2008) Corine Mathonière et al.   COMPTES RENDUS CHIMIE

Syntheses and functions of porous metallosupramolecular networks

(2008) Myunghyun Paik Suh et al.   COORDINATION CHEMISTRY REVIEWS

Testing the High Spin MnII9WV6Cluster as Building Block for Three-Dimensional Coordination Networks

(2008) Robert Podgajny et al.   CRYSTAL GROWTH & DESIGN

Theoretical study of the exchange coupling substituting MoV with WV in four cyano-bridged M′9M6 (M′ = MnII or NiII; M = MoV or WV) systems

(2008) Yi-Quan Zhang et al.   DALTON TRANSACTIONS

3D coordination metal–organic frameworks of octacyanometalate bridging between Cu4 magnetic units

(2008) Zhao-Xi Wang et al.   DALTON TRANSACTIONS

Design and its limitations in the construction of bi- and poly-nuclear coordination complexes and coordination polymers (aka MOFs): a personal view

(2008) R. Robson   DALTON TRANSACTIONS

Diol-type ligands as central ‘players’ in the chemistry of high-spin molecules and single-molecule magnets

(2008) Anastasios J. Tasiopoulos et al.   DALTON TRANSACTIONS

A Facially Capped Body‐Centered Ni9W6Cubane Modified with Sulfur‐Containing Bidentate Ligands: Structure and Magnetic Properties

(2008) Jeong Hak Lim et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Observation of Ferroelectricity in Paramagnetic Copper Octacyanomolybdate

(2008) Kosuke Nakagawa et al.   INORGANIC CHEMISTRY

A Luminescent and Magnetic Cyano-Bridged Tb3+−Mo5+Coordination Polymer:  toward Multifunctional Materials

(2008) Elena Chelebaeva et al.   INORGANIC CHEMISTRY

Room-Temperature and Near-Room-Temperature Molecule-Based Magnets

(2008) Mark D. Harvey et al.   INORGANIC CHEMISTRY

New 3D and Chiral 1D CuIICrIIICoordination Polymers Exhibiting Ferromagnetism

(2008) Olha Sereda et al.   INORGANIC CHEMISTRY

Tetranuclear [{Ni(HL3)}{W(CN)8}]2Square: A Case of Antiferromagnetic {NiIIWV} Interactions

(2008) Thengarai S. Venkatakrishnan et al.   INORGANIC CHEMISTRY

Magnetic Spongelike Behavior of 3D Ferrimagnetic {[MnII(imH)]2[NbIV(CN)8]}nwithTc= 62 K

(2008) Dawid Pinkowicz et al.   INORGANIC CHEMISTRY

New Optical Supramolecular Compound Constructed from a Polyoxometalate Cluster and an Organic Substrate

(2008) Yi-Ming Xie et al.   INORGANIC CHEMISTRY

Photoswitchable Heterotrimetallic Chain Based on Octacyanomolybdate, Copper, and Nickel: Synthesis, Characterization, and Photomagnetic Properties

(2008) Jérôme Long et al.   INORGANIC CHEMISTRY

Influence of octacyanoniobate(IV)-bridging geometry on Tc in Mn2Nb ferrimagnets of identical 3D topology

(2008) Dawid Pinkowicz et al.   INORGANICA CHIMICA ACTA

Crystal structure, magnetic and thermal properties of the one-dimensional complex [Nd(pzam)3(H2O)Mo(CN)8]·H2O

(2008) Stefania Tanase et al.   INORGANICA CHIMICA ACTA

First example of photomagnetic effects in ionic pairs [Ni(bipy)3]2[Mo(CN)8]·12H2O

(2008) Tomasz Korzeniak et al.   INORGANICA CHIMICA ACTA

Octanuclear {Co6W2} aggregate versus mixed valence {Co}3 cluster in the assembling of Co(phen)2Cl2 (phen=1,10-phenanthroline) with octacyano metallates: A case of non-isostructurality between {W(CN)8}4− and {Nb(CN)8}4−

(2008) Thengarai S. Venkatakrishnan et al.   INORGANICA CHIMICA ACTA

The assembly, synthesis and properties of a trinuclear cyano-bridged CuII–MoIV–CuIIcomplex

(2008) Shu-Zhong Zhan et al.   JOURNAL OF COORDINATION CHEMISTRY

Synthesis, crystal structure and magnetic property of an octacyanometalate-bridged complex

(2008) Jie Qu et al.   JOURNAL OF COORDINATION CHEMISTRY

Crystal structure and magnetic properties of a copper(II)–octacyanotungstate(V) bimetallic complex coordinated with macrocyclic ligand

(2008) Ai-Hua Yuan et al.   JOURNAL OF MOLECULAR STRUCTURE

Reversible Structural Transition in MIL-53 with Large Temperature Hysteresis

(2008) Yun Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Redox-Switchable Single-Molecule Magnet Incorporating [Re(CN)7]3-

(2008) Danna E. Freedman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pressure Response of Three-Dimensional Cyanide-Bridged Bimetallic Magnets

(2008) Masaaki Ohba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Prediction of the Conditions for Breathing of Metal Organic Framework Materials Using a Combination of X-ray Powder Diffraction, Microcalorimetry, and Molecular Simulation

(2008) Philip L. Llewellyn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Strong magneto-chiral dichroism in enantiopure chiral ferromagnets

(2008) Cyrille Train et al.   NATURE MATERIALS

A kinetic model for photoswitching of magnetism in the high spin molecule [Mo(iv)(CN)2(CN–Cu(ii)(tren))6](ClO4)8

(2008) Rajamani Raghunathan et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Magnetic ordering in the double-layered molecular magnetCu(tetren)[W(CN)8]: Single-crystal study

(2008) Maria Bałanda et al.   PHYSICAL REVIEW B

Three novel octacyanomolybdate(IV)–M(II) [M = Mn and Cu] bimetallic assemblies: crystal structures and magnetic properties

(2008) Shu-Lin Ma et al.   STRUCTURAL CHEMISTRY

Three types of heterometallic structural motifs based on [Mo(CN)8]3−/4− anion and MnII cation as building blocks

(2008) Shu-Lin Ma et al.   STRUCTURAL CHEMISTRY

Structure and magnetic properties of cyanide-bridged NiII9MoV6 cluster modified by bidentate capping ligands

(2007) Jung Hak Lim et al.   POLYHEDRON