Journal
DALTON TRANSACTIONS
Volume 39, Issue 9, Pages 2188-2190Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b924644b
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The synthesis, the structural characterization and the magnetic properties of a heterotrimetallic decanuclear square, [(Mo(CN)(8))(2)(CuLTb)(4))](4+), noted MoCuTb, are described. This supramolecular compound, viewed as the first example of a metal-capped square, behaves as a single molecule magnet with a magnetic anisotropic barrier energy of U-eff = 13.40 cm(-1) (19.25 K).
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