4.5 Article

Highly Efficient and Stable Palladium Nanoparticles Supported on an Ionic Liquid Silica Sol-Gel Modified Electrode

Journal

ELECTROANALYSIS
Volume 23, Issue 7, Pages 1536-1542

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201000767

Keywords

Palladium; Nanoparticles; Sol-gel; Electrocatalysts

Funding

  1. Shiraz University Research Council

Ask authors/readers for more resources

A carbon ionic liquid electrode modified with a thin layer of silica sol-gel containing phosphinite ionic liquid was prepared for deposition of palladium nanoparticles. Palladium nanoparticles were formed easily by simple contact of the modified electrode with palladium chloride solution. The novel material overcomes the shortcomings of conventionally modified electrodes with a thin layer of silica sol-gel, due to the existence of ionic liquid in silica matrix. A crack-free sol-gel matrix was obtained and also, the uniform porous structure of the ionic liquid-sol-gel matrix resulted in a fast mass transport and increased ionic conductivity. The electrode exhibits high electrocatalytic effects towards hydrazine and ascorbic acid. It is very stable against repetitive cycling in the applied potential window.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.5
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Inorganic & Nuclear

Carbon nanodots as fluorescent platforms for recognition of fluoride ion via the inner filter effect of simple arylboronic acids. Experimental and theoretical investigations

Zahra Mohammadpour, Afsaneh Safavi, Akbar Omidvar, Afshan Mohajeri, Nabiollah Mobaraki, Mojtaba Shamsipur

JOURNAL OF FLUORINE CHEMISTRY (2016)

Article Chemistry, Analytical

Highly selective aggregation assay for visual detection of mercury ion based on competitive binding of sulfur-doped carbon nanodots to gold nanoparticles and mercury ions

Mojtaba Shamsipur, Afsaneh Safavi, Zahra Mohammadpour, Raheleh Ahmadi

MICROCHIMICA ACTA (2016)

Article Chemistry, Multidisciplinary

Fluorescent pH nanosensor based on carbon nanodots for monitoring minor intracellular pH changes

Afsaneh Safavi, Raheleh Ahmadi, Zahra Mohammadpour, Jie Zhou

RSC ADVANCES (2016)

Article Chemistry, Analytical

Design and application of a composite electrode using molecular wire as the binder

Afsaneh Safavi, Maryam Mohammadzadeh, Mohsen Sorouri

MICROCHEMICAL JOURNAL (2017)

Article Chemistry, Analytical

Colorimetric sensing of silver ion based on anti aggregation of gold nanoparticles

Afsaneh Safavi, Raheleh Ahmadi, Zahra Mohammadpour

SENSORS AND ACTUATORS B-CHEMICAL (2017)

Article Chemistry, Analytical

Blue-emitting copper nanoparticles as a fluorescent probe for detection of cyanide ions

Safieh Momeni, Raheleh Ahmadi, Afsaneh Safavi, Iraj Nabipour

TALANTA (2017)

Review Biophysics

Nucleic acid-based electrochemical nanobiosensors

Alireza Abi, Zahra Mohammadpour, Xiaolei Zuo, Afsaneh Safavi

BIOSENSORS & BIOELECTRONICS (2018)

Article Environmental Sciences

Assessment of cytotoxicity of choline chloride-based natural deep eutectic solvents against human HEK-293 cells: A QSAR analysis

Raheleh Ahmadi, Bahram Hemmateenejad, Afsaneh Safavi, Zahra Shojaeifard, Maryam Mohabbati, Omidreza Firuzi

CHEMOSPHERE (2018)

Article Engineering, Biomedical

Synthesis of highly stable and biocompatible gold nanoparticles for use as a new X-ray contrast agent

Pooya Iranpour, Maral Ajamian, Afsaneh Safavi, Nasser Iranpoor, Abdolkarim Abbaspour, Sanaz Javanmardi

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE (2018)

Article Chemistry, Physical

Deep eutectic-water binary solvent associations investigated by vibrational spectroscopy and chemometrics

R. Ahmadi, B. Hemmateenejad, A. Safavi, Z. Shojaeifard, A. Shahsavar, A. Mohajeri, M. Heydari Dokoohaki, A. R. Zolghadr

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2018)

Article Chemistry, Analytical

A carbon dot-based fluorescence method for selective quantification of sulfide in environmental samples

Alireza Abi, Ghasem Kazemi, Afsaneh Safavi

SENSORS AND ACTUATORS B-CHEMICAL (2018)

Article Chemistry, Analytical

Shaker-assisted liquid-liquid microextraction of methylene blue using deep eutectic solvent followed by back-extraction and spectrophotometric determination

Raheleh Ahmadi, Ghasem Kazemi, Amir M. Ramezani, Afsaneh Safavi

MICROCHEMICAL JOURNAL (2019)

No Data Available