4.7 Article

Rhenium variations in molybdenite (MoS2): Evidence for progressive subsurface oxidation

Journal

EARTH AND PLANETARY SCIENCE LETTERS
Volume 366, Issue -, Pages 1-5

Publisher

ELSEVIER
DOI: 10.1016/j.epsl.2013.01.034

Keywords

mineral evolution; molybdenite; rhenium; Great Oxidation Event; supercontinent cycle

Funding

  1. Carnegie Institution of Washington
  2. NASA Astrobiology Institute
  3. Deep Carbon Observatory
  4. NSF-NASA Collaborative Research Grant
  5. DOE Grant [DE-FG02-96ER-14616]
  6. Directorate For Geosciences
  7. Division Of Earth Sciences [1023865] Funding Source: National Science Foundation

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Temporal trends in Earth's near-surface mineralogy correlate with major events in Earth's geochemical and tectonic history. New and published analyses of 422 molybdenite (MoS2) specimens from 135 localities with known ages from 2.91 billion years (Ga) to 6.3 million years (Ma) reveal two statistically significant trends. First, systematic increases in average and maximum trace concentrations of Re in molybdenite since 3.0 Ga point to enhanced oxidative weathering by subsurface fluids. In addition, episodic molybdenum mineralization correlates with five intervals of supercontinent assembly from similar to 2.7 Ga (Kenorland) to 300 Ma (Pangaea). (C) 2013 Elsevier B.V. All rights reserved.

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