Synthesis and molecular structure of pentadienyl complexes of the rare-earth metals

Monomeric Fe(iii) half-sandwich complexes [Cp′FeX2] – synthesis, properties and electronic structure

(2018) Matthias Reiners et al.   DALTON TRANSACTIONS

Molecular magnetic hysteresis at 60 kelvin in dysprosocenium

(2017) Conrad A. P. Goodwin et al.   NATURE

Reduction of Diphenylacetylene Mediated by Rare-Earth Ferrocene Diamide Complexes

(2017) Jonathan L. Brosmer et al.   ORGANOMETALLICS

Reductive Disproportionation of CO2 with Bulky Divalent Samarium Complexes

(2017) Mathieu Xémard et al.   ORGANOMETALLICS

Formation and ligand-based reductive chemistry of bridged bis-alkylidene scandium(iii) complexes

(2017) Wangyang Ma et al.   Chemical Science

Reactivity studies on [Cp′Fe(μ-I)]2: nitrido-, sulfido- and diselenide iron complexes derived from pseudohalide activation

(2017) Matthias Reiners et al.   Chemical Science

Closing the Gap: Preparation and Characterization of the First Half-Open and Open Manganocene Complexes

(2016) Matthias Reiners et al.   ORGANOMETALLICS

N-Heterocyclic carbene adducts to [Cp′FeI]2: synthesis and molecular and electronic structure

(2016) Matthias Reiners et al.   Inorganic Chemistry Frontiers

The First Lutetacyclopentadienes: Synthesis, Structure, and Diversified Insertion/CH Activation Reactivity

(2015) Ling Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molecular and electronic structures of donor-functionalized dysprosium pentadienyl complexes

(2015) Benjamin M. Day et al.   DALTON TRANSACTIONS

Divalent Tetra- and Penta-phenylcyclopentadienyl Europium and Samarium Sandwich and Half-Sandwich Complexes: Synthesis, Characterization, and Remarkable Luminescence Properties

(2015) Rory P. Kelly et al.   ORGANOMETALLICS

Small Molecule Activation Mediated by a Thorium Terminal Imido Metallocene

(2015) Enwei Zhou et al.   ORGANOMETALLICS

Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation

(2015) Ling Xu et al.   ORGANOMETALLICS

C–H bond activation induced by thorium metallacyclopropene complexes: a combined experimental and computational study

(2015) Bo Fang et al.   Chemical Science

Experimental and Computational Studies on the Reactivity of a Terminal Thorium Imidometallocene towards Organic Azides and Diazoalkanes

(2014) Wenshan Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pentadienyl chemistry of the heavy alkaline-earth metals revisited

(2014) Matthias Reiners et al.   DALTON TRANSACTIONS

How big is a Cp? Novel cycloheptatrienyl zirconium complexes with tri-, tetra- and pentasubstituted cyclopentadienyl ligands

(2014) Heiko Bauer et al.   DALTON TRANSACTIONS

Two [1,2,4-(Me3C)3C5H2]2CeH Molecules are Involved in Hydrogenation of Pyridine to Piperidine as Shown by Experiments and Computations

(2014) Lionel Perrin et al.   INORGANIC CHEMISTRY

The coordination chemistry of 2,4-di( tert -butyl)pentadienyl revisited

(2014) Matthias Reiners et al.   INORGANICA CHIMICA ACTA

An Actinide Metallacyclopropene Complex: Synthesis, Structure, Reactivity, and Computational Studies

(2014) Bo Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Realgar as a Building Block for Lanthanide Clusters: Encapsulation of a Copper Cluster by a Lanthanide Cluster

(2014) Nicholas Arleth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of [Cp′Fe(η3-BH4)] and Its Conversion to [Cp′FeBH2]3

(2013) Miyuki Maekawa et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Completing the Series of +2 Ions for the Lanthanide Elements: Synthesis of Molecular Complexes of Pr2+, Gd2+, Tb2+, and Lu2+

(2013) Matthew R. MacDonald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural Influences in Lithium Pentadienylsilane Complexes

(2013) Benjamin M. Day et al.   ORGANOMETALLICS

Is the bipyridyl thorium metallocene a low-valent thorium complex? A combined experimental and computational study

(2013) Wenshan Ren et al.   Chemical Science

How big is a Cp? Cycloheptatrienyl zirconium complexes with bulky cyclopentadienyl and indenyl ligands

(2012) Andreas Glöckner et al.   DALTON TRANSACTIONS

Reactivity Studies on [Cp′FeI]2: Monomeric Amido, Phenoxo, and Alkyl Complexes

(2012) Marc D. Walter et al.   INORGANIC CHEMISTRY

Cleaving bonds in CH3OSO2CF3with [1,2,4-(Me3C)3C5H2]2CeH; an experimental and computational study

(2012) Evan L. Werkema et al.   NEW JOURNAL OF CHEMISTRY

Selectivity in the C–H Activation Reaction of CH3OSO2CH3 with [1,2,4-(Me3C)3C5H2]2CeH or [1,2,4-(Me3C)3C5H2][1,2-(Me3C)2-4-(Me2CCH2)C5H2]Ce: To Choose or Not To Choose

(2012) Evan L. Werkema et al.   ORGANOMETALLICS

Synthesis, Structure, and Reactivity of a Thorium Metallocene Containing a 2,2′-Bipyridyl Ligand

(2012) Wenshan Ren et al.   ORGANOMETALLICS

Reactivity studies on [Cp′MnX(thf)]2: manganese amide and polyhydride synthesis

(2012) Miyuki Maekawa et al.   Chemical Science

A donor-functionalized, silyl-substituted pentadienyllithium: structural insight from experiment and theory

(2011) Sophia A. Solomon et al.   CHEMICAL COMMUNICATIONS

A Base-Free Thorium-Terminal-Imido Metallocene: Synthesis, Structure, and Reactivity

(2011) Wenshan Ren et al.   CHEMISTRY-A EUROPEAN JOURNAL

Thorium Oxo and Sulfido Metallocenes: Synthesis, Structure, Reactivity, and Computational Studies

(2011) Wenshan Ren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[Cp′FeI]2 as convenient entry into iron-modified pincer complexes: bimetallic η6,κ1-POCOP-pincer iron iridium compounds

(2011) Marc D. Walter et al.   NEW JOURNAL OF CHEMISTRY

Reactivity studies on [Cp′FeI]2: From iron hydrides to P4-activation

(2011) Marc D. Walter et al.   Chemical Science

Open metallocenes XI. A pentadienyl compound of heavier rare earth element [2,4-(CH3)2-η5-C5H5]3Tb·1/2THF

(2010) Xin Qiu et al.   CHINESE JOURNAL OF CHEMISTRY

The reaction of bis(1,2,4-tri-t-butylcyclopentadienyl)ceriumbenzyl, Cp′2CeCH2Ph, with methylhalides: a metathesis reaction that does not proceed by a metathesis transition state

(2010) Evan L. Werkema et al.   DALTON TRANSACTIONS

Splitting a C–O bond in dialkylethers with bis(1,2,4-tri-tert-butylcyclopentadienyl)cerium hydride does not occur by a σ-bond metathesis pathway: a combined experimental and DFT computational study

(2010) Evan L. Werkema et al.   NEW JOURNAL OF CHEMISTRY

Bridging Silyl Groups in σ-Bond Metathesis and [1,2]-Shifts. Experimental and Computational Study of the Reaction between Cerium Metallocenes and MeOSiMe3†

(2010) Evan L. Werkema et al.   ORGANOMETALLICS

2,4-Dimethylpentadienyl-Komplexe des Neodyms, Lanthans und Yttriums als Präkatalysatoren für die stereoselektive Butadienpolymerisation. 2,4-Dimethylpentadienyl Complexes of Neodymium, Lanthanum and Yttrium as Precatalysts for the Stereoselective Polymeri

(2010) Michael R. Kunze et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Diamagnetic Corrections and Pascal's Constants

(2009) Gordon A. Bain et al.   JOURNAL OF CHEMICAL EDUCATION

Hydrogen for X-Group Exchange in CH3X (X = Cl, Br, I, OMe, and NMe2) by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Support for a Carbenoid Mechanism

(2009) Evan L. Werkema et al.   ORGANOMETALLICS

Remarkable Stability of Metallocenes with Superbulky Ligands: Spontaneous Reduction of SmIII to SmII

(2008) Christian Ruspic et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dinitrogen Reduction and CH Activation by the Divalent Organoneodymium Complex [(C5H2tBu3)2Nd(μ-I)K([18]crown-6)]

(2008) Florian Jaroschik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine for Hydrogen Exchange in the Hydrofluorobenzene Derivatives C6HxF(6-x),wherex= 2, 3, 4 and 5 by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: The Solid State Isomerization of [1,2,4-(Me3C)3C5H2]2Ce(2,3,4,5-C6HF4) to [1,2,4-(Me3C)3C5H2]2Ce(2,3,4,6-C6HF4)

(2008) Evan L. Werkema et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lanthanoidorganische und Hauptgruppenmetallorganische Verbindungen in einem ungewöhnlichen supramolekularen Verbund: {[Ln(2,4-Me2C5H5)3]2·[NaAlEt4]4} (Ln = Nd, La)

(2008) Michael R. Kunze et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

The Oxidation of Metals with Liebig Acids

(2007) Gerd Meyer   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE