Experimental and Computational Studies on the Reactivity of a Terminal Thorium Imidometallocene towards Organic Azides and Diazoalkanes

Synthesis and Characterization of an f-Block Terminal Parent Imido [U═NH] Complex: A Masked Uranium(IV) Nitride

(2014) David M. King et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of (Bisimido)niobium(V) Complexes with Organic Azides: [3 + 2] Cycloaddition and Reversible Cleavage of β-Diketiminato Ligands Involving Nitrene Transfer

(2014) Andreas H. Obenhuber et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organothorium complexes containing terminal metal-ligand multiple bonds

(2014) GuoFu Zi   Science China-Chemistry

Si–H addition followed by C–H bond activation induced by a terminal thorium imido metallocene: a combined experimental and computational study

(2014) Wenshan Ren et al.   Chemical Science

Recent developments in actinide–ligand multiple bonding

(2013) Trevor W. Hayton   CHEMICAL COMMUNICATIONS

Progress in Terminal-Imido Organoactinide Complexes

(2013) Wenshan Ren et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Bringing Redox Reactivity to a Redox Inactive Metal Center - E-I (E = C, Si) Bond Cleavage with a Thorium Bis(α-diimine) Complex

(2013) Agnes Mrutu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Diniobium Inverted Sandwich Complexes with μ-η6:η6-Arene Ligands: Synthesis, Kinetics of Formation, and Electronic Structure

(2013) Thomas L. Gianetti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning Uranium–Nitrogen Multiple Bond Formation with Ancillary Siloxide Ligands

(2013) Clément Camp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chameleon Behavior of a Newly Synthesized Scandium Nitrilimine Derivative

(2013) Jiaxiang Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An actinide milestone

(2013) Trevor W. Hayton   Nature Chemistry

Isolation and characterization of a uranium(VI)–nitride triple bond

(2013) David M. King et al.   Nature Chemistry

Is the bipyridyl thorium metallocene a low-valent thorium complex? A combined experimental and computational study

(2013) Wenshan Ren et al.   Chemical Science

Intramolecular C–H bond activation induced by a scandium terminal imido complex

(2012) Zhongbao Jian et al.   CHEMICAL COMMUNICATIONS

Synthesis of U(iv) imidos from Tp*2U(CH2Ph) (Tp* = hydrotris(3,5-dimethylpyrazolyl)borate) by extrusion of bibenzyl

(2012) Ellen M. Matson et al.   DALTON TRANSACTIONS

Diazoalkane Reduction for the Synthesis of Uranium Hydrazonido Complexes

(2012) Ellen M. Matson et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Observation of the Inverse Trans Influence (ITI) in a Uranium(V) Imide Coordination Complex: An Experimental Study and Theoretical Evaluation

(2012) Oanh P. Lam et al.   INORGANIC CHEMISTRY

Evidence for the Existence of Terminal Scandium Imidos: Mechanistic Studies Involving Imido–Scandium Bond Formation and C–H Activation Reactions

(2012) Benjamin F. Wicker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of a Terminal Scandium Imido Complex

(2012) Terry Chu et al.   ORGANOMETALLICS

Synthesis, Structure, and Reactivity of a Thorium Metallocene Containing a 2,2′-Bipyridyl Ligand

(2012) Wenshan Ren et al.   ORGANOMETALLICS

Synthesis and Structure of a Terminal Uranium Nitride Complex

(2012) D. M. King et al.   SCIENCE

Reactivity of a Scandium Terminal Imido Complex Towards Unsaturated Substrates

(2011) Jiaxiang Chu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Uranium-mediated activation of small molecules

(2011) Polly L. Arnold   CHEMICAL COMMUNICATIONS

A Base-Free Thorium-Terminal-Imido Metallocene: Synthesis, Structure, and Reactivity

(2011) Wenshan Ren et al.   CHEMISTRY-A EUROPEAN JOURNAL

The ThC double bond: an experimental and computational study of thorium poly-carbene complexes

(2011) Wenshan Ren et al.   DALTON TRANSACTIONS

A General and Modular Synthesis of Monoimidouranium(IV) Dihalides

(2011) Robert. E. Jilek et al.   INORGANIC CHEMISTRY

Thorium Oxo and Sulfido Metallocenes: Synthesis, Structure, Reactivity, and Computational Studies

(2011) Wenshan Ren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The first group 4 metal bis(imido) and tris(imido) complexes

(2011) Andrew D. Schwarz et al.   Chemical Science

Exploring the coordination modes of pyrrolyl ligands in bis(imido) uranium(vi) complexes

(2010) Douglas L. Swartz II et al.   DALTON TRANSACTIONS

Comparison of the Redox Chemistry of Primary and Secondary Amides of U(IV): Isolation of a U(VI) Bis(imido) Complex or a Homoleptic U(VI) Amido Complex

(2010) Lani A. Seaman et al.   INORGANIC CHEMISTRY

Uranium azide photolysis results in C–H bond activation and provides evidence for a terminal uranium nitride

(2010) Robert K. Thomson et al.   Nature Chemistry

Challenging the Metallocene Dominance in Actinide Chemistry with a Soft PNP Pincer Ligand: New Uranium Structures and Reactivity Patterns

(2009) Thibault Cantat et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cation-Cation Interactions, Magnetic Communication, and Reactivity of the Pentavalent Uranium Ion [U(NtBu)2]+

(2009) Liam P. Spencer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pentavalent uranium chemistry—synthetic pursuit of a rare oxidation state

(2009) Christopher R. Graves et al.   CHEMICAL COMMUNICATIONS

Selenate and tellurate complexes of pentavalent uranium

(2009) Christopher R. Graves et al.   CHEMICAL COMMUNICATIONS

Metal–ligand multiple bonding in uranium: structure and reactivity

(2009) Trevor W. Hayton   DALTON TRANSACTIONS

Oxidative Addition to U(V)−U(V) Dimers: Facile Routes to Uranium(VI) Bis(imido) Complexes

(2009) Liam P. Spencer et al.   INORGANIC CHEMISTRY

Uranium(VI) Bis(imido) Chalcogenate Complexes: Synthesis and Density Functional Theory Analysis

(2009) Liam P. Spencer et al.   INORGANIC CHEMISTRY

Uranium Metallocene Complexes of the 1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidinato Ligand, (hpp)−

(2009) William J. Evans et al.   INORGANIC CHEMISTRY

Synthesis of Heteroleptic Uranium (μ−η6:η6-C6H6)2−Sandwich Complexes via Facile Displacement of (η5-C5Me5)1−by Ligands of Lower Hapticity and Their Conversion to Heteroleptic Bis(imido) Compounds

(2009) William J. Evans et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Is Thorium a d Transition Metal or an Actinide? An Answer from a DFT Study of the Reaction between PyridineN-Oxide and Cp2M(CH3)2with M = Zr, Th, and U

(2009) Ahmed Yahia et al.   ORGANOMETALLICS

Synthesis and reactivity of bis(imido) uranium(vi) cyclopentadienyl complexes

(2008) Liam P. Spencer et al.   CHEMICAL COMMUNICATIONS

Probing the Chemistry, Electronic Structure and Redox Energetics in Organometallic Pentavalent Uranium Complexes

(2008) Christopher R. Graves et al.   INORGANIC CHEMISTRY

Evidence for the Involvement of 5f Orbitals in the Bonding and Reactivity of Organometallic Actinide Compounds: Thorium(IV) and Uranium(IV) Bis(hydrazonato) Complexes

(2008) Thibault Cantat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Imido Exchange in Bis(imido) Uranium(VI) Complexes with Aryl Isocyanates

(2008) Liam P. Spencer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organometallic Uranium(V)−Imido Halide Complexes: From Synthesis to Electronic Structure and Bonding

(2008) Christopher R. Graves et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon Dioxide Activation with Sterically Pressured Mid- and High-Valent Uranium Complexes

(2008) Suzanne C. Bart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Towards uranium catalysts

(2008) Alexander R. Fox et al.   NATURE

Tetravalent and Pentavalent Uranium Acetylide Complexes Prepared by Oxidative Functionalization with CuCCPh

(2008) Christopher R. Graves et al.   ORGANOMETALLICS

Recent advances in organothorium and organouranium catalysis

(2007) Tamer Andrea et al.   CHEMICAL SOCIETY REVIEWS