Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions

Catalytic Dinitrogen Reduction to Ammonia at a Triamidoamine-Titanium Complex

(2018) Laurence R. Doyle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes

(2018) Yoshiya Sekiguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation and reactivity of iron complexes bearing anionic carbazole-based PNP-type pincer ligands toward catalytic nitrogen fixation

(2018) Junichi Higuchi et al.   DALTON TRANSACTIONS

Nitrogen Fixation Catalyzed by Transition Metal Complexes: Recent Developments

(2018) Nadja Stucke et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Fe-Mediated Nitrogen Fixation with a Metallocene Mediator: Exploring pKa Effects and Demonstrating Electrocatalysis

(2018) Matthew J. Chalkley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands

(2018) Yoshiya Sekiguchi et al.   DALTON TRANSACTIONS

Synthesis and Reactivity of Iron- and Cobalt-Dinitrogen Complexes Bearing PSiP-Type Pincer Ligands toward Nitrogen Fixation

(2017) Ryuji Imayoshi et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Reduction of C1 Substrates to Hydrocarbons by the Homometallic Precursor and Synthetic Mimic of the Nitrogenase Cofactor

(2017) Nathaniel S. Sickerman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Nitrogen-to-Ammonia Conversion by Osmium and Ruthenium Complexes

(2017) Javier Fajardo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reduction of Dinitrogen to Ammonia Catalyzed by Molybdenum Diamido Complexes

(2017) Lasantha A. Wickramasinghe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The structure of vanadium nitrogenase reveals an unusual bridging ligand

(2017) Daniel Sippel et al.   Nature Chemical Biology

Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation

(2017) Aya Eizawa et al.   Nature Communications

Catalytic N2-to-NH3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET

(2017) Matthew J. Chalkley et al.   ACS Central Science

Examining the relationship between coordination mode and reactivity of dinitrogen

(2017) Richard J. Burford et al.   Nature Reviews Chemistry

Interplay between Theory and Experiment for Ammonia Synthesis Catalyzed by Transition Metal Complexes

(2016) Hiromasa Tanaka et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands

(2016) Shogo Kuriyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nitrogenases-A Tale of Carbon Atom(s)

(2016) Yilin Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes

(2016) Yoshiaki Tanabe et al.   CHEMICAL RECORD

Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation

(2016) Shogo Kuriyama et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Selective Catalytic Reduction of N2 to N2H4 by a Simple Fe Complex

(2016) Peter J. Hill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand

(2016) Shogo Kuriyama et al.   Nature Communications

Cobalt-Catalyzed Transformation of Molecular Dinitrogen into Silylamine under Ambient Reaction Conditions

(2015) Ryuji Imayoshi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Evaluating Molecular Cobalt Complexes for the Conversion of N2 to NH3

(2015) Trevor J. Del Castillo et al.   INORGANIC CHEMISTRY

Recent Progress in Transition-Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions

(2015) Yoshiaki Nishibayashi   INORGANIC CHEMISTRY

Catalytic Reduction of Dinitrogen to Ammonia by Use of Molybdenum–Nitride Complexes Bearing a Tridentate Triphosphine as Catalysts

(2015) Kazuya Arashiba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site

(2015) Shogo Kuriyama et al.   Chemical Science

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum–Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand

(2014) Shogo Kuriyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unique behaviour of dinitrogen-bridged dimolybdenum complexes bearing pincer ligand towards catalytic formation of ammonia

(2014) Hiromasa Tanaka et al.   Nature Communications

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store

(2012) Masaaki Kitano et al.   Nature Chemistry

Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions

(2012) Masahiro Yuki et al.   Nature Communications

Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands

(2011) Hiromasa Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

(2011) T. Spatzal et al.   SCIENCE

X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

(2011) K. M. Lancaster et al.   SCIENCE

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

(2010) Kazuya Arashiba et al.   Nature Chemistry

Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum: Theory versus Experiment

(2008) Richard R. Schrock   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

How a century of ammonia synthesis changed the world

(2008) Jan Willem Erisman et al.   Nature Geoscience