Review
Cell Biology
Ewa Sikora, Anna Bielak-Zmijewska, Grazyna Mosieniak
Summary: Cellular senescence is a significant biological phenomenon that mainly participates in aging and aging-related diseases through secretion activity and cell cycle arrest. In this process, DNA damage, nuclear changes, and chromatin rearrangement play important roles.
AGEING RESEARCH REVIEWS
(2021)
Article
Orthopedics
Jean-David Werthel, Geoffrey Champain, Guy Villaret, Marc Soubeyrand, Gilles Walch
Summary: The fibers of the subscapularis do not all originate from the subscapularis fossa. An additional origin exists at the inferior part of the glenoid neck and in a depression at the infero-lateral part of the scapular pillar. The fibers which originate at this location all insert on the humerus at the muscular portion of the subscapularis humeral insertion. This portion, however, does not seem to correspond to the so-called subscapularis minor which has been previously described.
INTERNATIONAL ORTHOPAEDICS
(2022)
Article
Clinical Neurology
A. R. Stevens, B. F. Branstetter, P. Gardner, T. M. Pearce, G. A. Zenonos, K. Arani
Summary: This article discusses a benign notochordal remnant called ecchordosis physaliphora (EP) that has a considerable overlap in radiologic appearance with low-grade chordomas, which have growth potential. It proposes new pathologic and radiologic terminology and emphasizes the surgical importance and implications for patient care.
AMERICAN JOURNAL OF NEURORADIOLOGY
(2023)
Review
Dermatology
Razvigor Darlenski, Jana Kazandjieva, Nikolai Tsankov
Summary: Contact pemphigus, defined as pemphigus occurring at the site of local skin contact with different chemicals, has been a topic of debate for more than 50 years. Various products have been identified as potential aetiological factors, including pesticides, topical drugs, cosmetics, and garlic.
EUROPEAN JOURNAL OF DERMATOLOGY
(2021)
Article
Business, Finance
Yann Ferrat, Frederic Daty, Radu Burlacu
Summary: Using a sample of ESG ratings, this study examines the sustainability risk premium in developed and emerging markets from 2015 to the end of 2019. The results show that this premium is not distinguishable in developed equity markets, while it is highly positive in emerging markets. Furthermore, the study finds that both country development and firm size significantly impact the emergence of the risk premium.
EMERGING MARKETS REVIEW
(2022)
Review
Oncology
Alexandra M. Miggelbrink, Joshua D. Jackson, Selena J. Lorrey, Ethan S. Srinivasan, Jessica Waibl-Polania, Daniel S. Wilkinson, Peter E. Fecci
Summary: In chronic infections and cancer, persistent antigen stimulation can lead to T-cell exhaustion, with CD4 T-cell exhaustion being less studied but potentially clinically relevant in orchestrating immune responses and disease severity. Understanding phenotypic exhaustion in CD4 T cells and its impact on immune responses and disease severity is crucial for identifying novel therapeutic targets in cancer.
CLINICAL CANCER RESEARCH
(2021)
Editorial Material
Urology & Nephrology
Federica Piani, Richard J. Johnson
Summary: Gout is common in patients with CKD, and those with kidney dysfunction may have hyperechoic medullas, potentially linked to increased risk of hypertension and kidney dysfunction. More research is needed to validate these findings.
KIDNEY INTERNATIONAL
(2021)
Review
Nutrition & Dietetics
Itai Sharon, Narciso Martin Quijada, Edoardo Pasolli, Marco Fabbrini, Francesco Vitali, Valeria Agamennone, Andreas Doetsch, Evelyne Selberherr, Jose Horacio Grau, Martin Meixner, Karsten Liere, Danilo Ercolini, Carlotta de Filippo, Giovanna Caderni, Patrizia Brigidi, Silvia Turroni
Summary: The core microbiome, which represents consistent microbial features across populations, is of great interest in microbiome research. Understanding the core microbiome can lead to the identification of dysbiosis-causing elements and potential treatments for microbiome-related health conditions. However, defining the core microbiome is a complex task that requires collaboration between experts in various fields.
Article
Evolutionary Biology
Valentina Burskaia, Ilja Artyushin, Nadezhda A. Potapova, Kirill Konovalov, Georgii A. Bazykin
Summary: Research on bird mitochondrial genomes reveals genetic signals of parallel or convergent evolution in adaptation to high altitude, migration, diving, wintering, unusual flight abilities, or loss of flight. These signals indicate associations between genotype and phenotype changes, but most convergence events can be attributed to random coincidences rather than adaptation.
GENOME BIOLOGY AND EVOLUTION
(2021)
Letter
Clinical Neurology
Dimitrios Parissis, Nikoletta Smyrni, Panos Ioannidis, Nikolaos Grigoriadis
Summary: Acute myelitis with longitudinally extensive MRI pattern is a core feature of NMOSD. Recently, a rare case of ab initio progressive myelopathy attributed to aquaporin-4 autoimmunity has drawn attention, potentially altering the view on disease progression in NMOSD.
MULTIPLE SCLEROSIS AND RELATED DISORDERS
(2021)
Article
Urology & Nephrology
Mei-Yin Chen, Shih-Hsiang Ou, Nai-Ching Chen, Chun-Hao Yin, Chien-Liang Chen
Summary: Aluminum overload continues to exist in the era of reverse osmosis dialysis, despite the use of aluminum binders. Serum aluminum levels should be monitored in dialysis patients using aluminum-based phosphate binders.
Review
Rheumatology
Valerie Leclair, Antonella Notarnicola, Jiri Vencovsky, Ingrid E. Lundberg
Summary: Polymyositis has evolved from a broad term for inflammatory muscle diseases to a more specific definition based on histopathological and immunohistochemical features. The discovery of new subsets and distinct histopathological features has reduced the number of patients classified as polymyositis, making it a relatively rare entity within the spectrum of idiopathic inflammatory myopathies.
CURRENT OPINION IN RHEUMATOLOGY
(2021)
Review
Dermatology
Deborah Maria Gregersen, Peter Elsner
Summary: Recent research has found discrepancies in medical care based on skin color in Anglo-American countries. This is partly due to the fact that medical textbooks mainly feature examples and material related to white and fair skin types, raising concerns about whether current medical training and practice in Germany adequately address the needs of an increasingly diverse population.
JOURNAL DER DEUTSCHEN DERMATOLOGISCHEN GESELLSCHAFT
(2021)
Article
Anesthesiology
Anais Pesonen, Nawfel Ben-Hamouda, Antoine Schneider
Summary: Acute kidney injury (AKI) is common after cerebral insults, with factors such as intravascular volume depletion and systemic inflammatory response playing a role in its development. The complex brain-kidney crosstalk mechanisms suggest a causal relationship between brain and kidney injury.
MINERVA ANESTESIOLOGICA
(2021)
Article
Orthopedics
Kai-Yu Ho, Yu-Jen Chen, Shawn Farrokhi, Liang-Ching Tsai, Tzu-Chieh Liao, Nicole Haas, Christopher M. Powers
Summary: This study compared quadriceps muscle volumes between women with and without nontraumatic PFP using MRI scans and found no differences in individual or total muscle volumes between the two groups. These results do not support the concept of preferential atrophy of the vastus medialis or generalized quadriceps atrophy in women with nontraumatic PFP.
AMERICAN JOURNAL OF SPORTS MEDICINE
(2021)
Article
Chemistry, Multidisciplinary
Daniel Olsson, Junyi Li, Mats Jonsson
Summary: The interfacial radiation chemistry of UO2 is crucial for the development of corrosion rate prediction models for spent nuclear fuel in contact with groundwater. The oxidative dissolution of UO2 induced by radiolytically produced H2O2 is of great significance. Stable uranyl peroxo-carbonato complexes formed by UO22+ in water containing H2O2 and HCO3-/CO32- have been largely overlooked in previous studies. Experimental results show that these complexes have little to no reactivity with the solid UO2 surface under certain conditions. The dissolution rate depends on the UO22+ concentration and is limited by the free H2O2 fraction.
Article
Chemistry, Physical
Celice Carlsson, Benjamin Fegeant, Emelie Svensson, Love Wiklund, Mats Jonsson
Summary: This study investigates the selectivity and formaldehyde yield of Tris and methanol as probes for surface-bound hydroxyl radicals in homogeneous and heterogeneous systems. The experiments demonstrate that Br2 & BULL;− reduces the formaldehyde yield compared to hydroxyl radicals in the homogeneous methanol system, while Tris increases the yield. Similar trends are observed in the photocatalysis system. The paper discusses the reasons for these changes and the suitability of Tris and methanol as probes.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Materials Science, Multidisciplinary
A. Yu. Stroev, O. I. Gorbatov, Yu. N. Gornostyrev, P. A. Korzhavyi
Summary: In this study, the growth of precipitates during solid solution decomposition and the dissolution of small precipitates during the coarsening stage in ternary Al-Sc-Zr alloys were investigated using a statistical alloy theory based on the Master Equation approach with ab initio calculated interatomic interactions. The results showed that Zr alloying promoted the formation of core-shell nanoparticles in Al-Sc alloys, whose structure was highly sensitive to the solute diffusion rates. It was demonstrated that the core-shell structure of precipitates slowed down the dissolution of small particles, thus hindering microstructure coarsening at elevated temperatures.
COMPUTATIONAL MATERIALS SCIENCE
(2023)
Article
Chemistry, Physical
Marcela E. Trybula, Arkadiusz Zydek, Pavel A. Korzhavyi, Joanna Wojewoda-Budka
Summary: Aluminum oxide coating is resistant to weak acidic and alkaline aqueous solutions and naturally forms a passivation layer against corrosion. Molecular dynamics simulations were used to study the behavior of the Al/oxide surface when exposed to strong corrosive media. The mechanism of film growth on the Al/oxide surface during corrosion differs in alkaline and acidic solutions, leading to differences in structure and topography. The chemical composition of the formed films is pH-independent, and the films have a topologically complex amorphous nature.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Multidisciplinary Sciences
Yang Wang, Tingting Lian, Nadezda Tarakina, Jiayin Yuan, Markus Antonietti
Summary: By creating lamellar membranes with adaptive subnanochannels using polycation pillaring, researchers have overcome the selectivity-permeability trade-off in forward osmosis for traditional carbon nitride membranes. This finding positions carbon nitride as a rising building block to expand the functionality of 2D membranes for water desalination and purification applications.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Enis Oguzhan Eren, Evgeny Senokos, Zihan Song, Elif Beguem Yilmaz, Irina Shekova, Bolortuya Badamdorj, Iver Lauermann, Nadezda V. Tarakina, Majd Al-Naji, Markus Antonietti, Paolo Giusto
Summary: To enhance the electrochemical performance of sodium-ion batteries, sustainable and high-performance carbonaceous anode materials are needed. By depositing a tunable thickness of nm-sized conformal coating of carbon nitride, we were able to improve the electrochemical performance of anode material derived from sodium lignosulfonate. This resulted in significantly enhanced electrode performance, including first cycle efficiency, rate-capability, and specific capacity. The design of interactive electrochemical interfaces, such as a homogeneous carbon nitride coating, played a crucial role in improving the performance of carbonaceous anodes without adding much weight.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Inorganic & Nuclear
Junyi Li, Xianjie Liu, Mats Jonsson
Summary: This study experimentally investigated the change in UO2 reactivity after exposure to O2 or gamma-radiation. The results showed that the reactivity of UO2 decreased significantly over time, especially in consecutive exposures. Surface analysis revealed that UO2 surfaces were significantly oxidized under all exposure conditions, with the presence of U(V) and no U(VI) observed.
INORGANIC CHEMISTRY
(2023)
Article
Nanoscience & Nanotechnology
Junfang Zhang, Yuxin Liu, Christian Njel, Sebastian Ronneberger, Nadezda V. V. Tarakina, Felix F. F. Loeffler
Summary: Counterfeiting not only causes trillion-dollar economic losses annually, but also threatens human health, social equity, and national security. Researchers have developed a nanoprinting-assisted flash synthesis approach to create fluorescent nanofilms with physical unclonable function micropatterns in milliseconds. These unclonable patterns can be quickly and independently read out by fluorescence and topography scanning, greatly enhancing their security.
NATURE NANOTECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Jing Hou, Zihan Song, Mateusz Odziomek, Nadezda V. V. Tarakina
Summary: In this study, nitrogen-doped porous hollow carbon spheres were used to analyze the behavior of sodium storage in a commercial liquid electrolyte. It was found that during the sodiation process, a solvated ionic layer forms on the surface of the carbon spheres, followed by irreversible expansion due to solid-electrolyte interphase (SEI) formation. The N-PHCSs layer acts as a protective layer, preventing the growth of dendrites at the anode.
Article
Chemistry, Multidisciplinary
Yi Yang, Pavel A. Korzhavyi, Pavel A. Nikolaychuk, Elena F. Bazarkina, Kristina O. Kvashnina, Sergei M. Butorin, Nadezda V. Tarakina, Inna L. Soroka
Summary: Transition metal-based catalysts have the potential to replace Pt-based materials in energy conversion devices due to their low cost, reasonable activity, stability, and corrosion resistance. This study demonstrates the synthesis of homogeneous alloy nanoparticles with controlled structure and varying Ni-to-Co ratios using a gamma-radiolytic reduction method. The presence of structural defects in the obtained samples influenced the catalysts' activity towards the oxygen evolution reaction but had a less pronounced effect on the oxygen reduction reaction. The activity of Ni-Co catalysts in the hydrogen evolution reaction was found to be affected by the formation of Ni-OH bonds on the surface.
ADVANCED MATERIALS INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Maria Jerigova, Yevheniia Markushyna, Ivo F. Teixeira, Bolortuya Badamdorj, Mark Isaacs, Daniel Cruz, Iver Lauermann, Miguel Angel Munoz-Marquez, Nadezda V. Tarakina, Nieves Lopez-Salas, Oleksandr Savateev, Pablo Jimenez-Calvo
Summary: By pre-organization of precursors and further co-polymerization, tunable semiconductors can be synthesized through anionic doping. These S-doped/C3N4-based materials demonstrate enhanced optical, electronic, structural, textural, and morphological properties, leading to higher performance in organic benzylamine photooxidation, oxygen evolution, and energy storage.
Article
Crystallography
Marcela E. Trybula, Arkadiusz Zydek, Pavel A. Korzhvayi, Joanna Wojewoda-Budka
Summary: Oxidation conditions can be controlled to tailor the properties and structure of oxide films. Molecular dynamics simulations were used to study the thermal oxidation of polycrystalline Al substrates. The results showed that the density of O2 and the temperature had an impact on the formation of oxide films, which exhibited long-range order and a two-phase structure. Additionally, the roughness of the Al surface before oxidation affected the behavior of the metal/oxide interface and the structure of the oxide film.
Article
Chemistry, Multidisciplinary
Hannes Zschiesche, Inna L. Soroka, Mats Jonsson, Nadezda V. Tarakina
Summary: This study investigates the influence of irradiation dose on the growth mechanisms and morphology of CeO2 particles formed through the radiolytic oxidation of Ce3+ in aqueous solution. The results show that different dose rates do not affect the growth pathway of CeO2 particles and result in the formation of highly ordered structures. Additionally, locally applied irradiation induces Ce-ion concentration gradients, impacting the growth of CeO2 and leading to the appearance of branched morphologies.
Article
Chemistry, Inorganic & Nuclear
Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka
Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.
DALTON TRANSACTIONS
(2024)
Review
Chemistry, Inorganic & Nuclear
Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno
Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun
Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye
Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep
Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou
Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias
Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying
Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li
Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik
Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Mika Takeuchi, Yutaka Amao
Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.
DALTON TRANSACTIONS
(2024)
Article
Chemistry, Inorganic & Nuclear
Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang
Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.
DALTON TRANSACTIONS
(2024)