Kinetico-mechanistic studies of cyclometalating C–H bond activation reactions on Pd(ii) and Rh(ii) centres: The importance of non-innocent acidic solvents in the process

Chelating Base Effects in Palladium-Mediated Activation of Molecular Oxygen

(2012) Jason M. Keith et al.   ORGANOMETALLICS

From Molten Salts to Ionic Liquids: A “Nano” Journey

(2011) Jairton Dupont   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of a Palladium(IV) Complex by Oxidative Addition of an Aryl Halide to Palladium(II) and Its Use as Precatalyst in a CC Coupling Reaction

(2011) José Vicente et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed Selective Monofluorination of Benzoic Acids Using a Practical Auxiliary: A Weak-Coordination Approach

(2011) Kelvin S. L. Chan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Phenanthridinones from N-Methoxybenzamides and Arenes by Multiple Palladium-Catalyzed CH Activation Steps at Room Temperature

(2011) Jaganathan Karthikeyan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Double CH Activation Directed by Sulfoxides in the Synthesis of Dibenzothiophenes

(2011) Rajarshi Samanta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(iii)-catalyzed oxidative carbonylation of benzamides with carbon monoxide

(2011) Ya Du et al.   CHEMICAL COMMUNICATIONS

Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

(2011) Olivier Baudoin   CHEMICAL SOCIETY REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed ortho-Acylation of Acetanilides with Aldehydes through Direct CH Bond Activation

(2011) Chengliang Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

2-Pyridyl Sulfoxide: A Versatile and Removable Directing Group for the PdII-Catalyzed Direct CH Olefination of Arenes

(2011) Alfonso García-Rubia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Kinetico-mechanistic studies of the acidolysis of Rh–C bonds in monocyclometallated dirhodium(ii) acetato complexes; influence of electronic and steric effects

(2011) Julio Esteban et al.   DALTON TRANSACTIONS

The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates

(2011) John F. Berry   DALTON TRANSACTIONS

C-H Bond Activation of Palladium Complexes That Feature Pendant Benzamidinate Ligands and Their Catalytic Behaviours

(2011) Ming-Tsz Chen et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

The Cause for Tremendous Acceleration of Chloride Substitution via Base Catalysis in the Chloro Pentaammine Cobalt(III) Ion

(2011) Basile F. E. Curchod et al.   INORGANIC CHEMISTRY

Kinetico-Mechanistic Information about Alkene Hydroamination with Aniline in Bromide-Rich Ionic Media: Importance of Solvolysis

(2011) Gabriel Aullón et al.   INORGANIC CHEMISTRY

Regioselective Orthopalladation of (Z)-2-Aryl-4-Arylidene-5(4H)-Oxazolones: Scope, Kinetico-Mechanistic, and Density Functional Theory Studies of the C–H Bond Activation

(2011) Gheorghe-Doru Roiban et al.   INORGANIC CHEMISTRY

Coordination of 1,10-Phenanthroline and 2,2′-Bipyridine to Li+in Different Ionic Liquids. How Innocent Are Ionic Liquids?

(2011) Matthias Schmeisser et al.   INORGANIC CHEMISTRY

Structure of Complexes Formed by Dissolution of Palladium Diacetate in Methanol and Chloroform. In Situ NMR Study

(2011) Valentina M. Nosova et al.   INORGANIC CHEMISTRY

Enantiomer Recognition of Amides by Dirhodium(II) Tetrakis[methyl 2-oxopyrrolidine-5(S)-carboxylate]

(2011) Xichen Xu et al.   INORGANIC CHEMISTRY

Kinetics of the Reversible Reaction of CO2(aq) with Ammonia in Aqueous Solution

(2011) Xiaoguang Wang et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Aerobic Pd-Catalyzed sp3C−H Olefination: A Route to Both N-Heterocyclic Scaffolds and Alkenes

(2011) Kara J. Stowers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlling Site Selectivity in Pd-Catalyzed Oxidative Cross-Coupling Reactions

(2011) Thomas W. Lyons et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Theoretical Analysis of the Mechanism of Palladium(II) Acetate-Catalyzed Oxidative Heck Coupling of Electron-Deficient Arenes with Alkenes: Effects of the Pyridine-Type Ancillary Ligand and Origins of themeta-Regioselectivity

(2011) Songlin Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H Bond Activation at Palladium(IV) Centers

(2011) Joy M. Racowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sensitive and Selective Chromogenic Sensing of Carbon Monoxide via Reversible Axial CO Coordination in Binuclear Rhodium Complexes

(2011) María E. Moragues et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Promoted C3-Selective Arylation of Pyridines with Pd Catalysts: Gram-Scale Synthesis of (±)-Preclamol

(2011) Mengchun Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Intermolecular C–H Amination with Alkylamines

(2011) Eun Jeong Yoo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facial Tridentate Ligands for Stabilizing Palladium(IV) Complexes

(2011) Ansis Maleckis et al.   ORGANOMETALLICS

Palladium(II) Agostic Complex: Exchange of Aryl–Pd and Alkyl–Pd Bonds

(2011) Helen R. Thomas et al.   ORGANOMETALLICS

A New Method for High-Yield Cyclopalladation of Primary and Secondary Amines. Atom-Efficient Open-to-Air Inexpensive Synthesis of Buchwald-Type Precatalysts

(2011) José Vicente et al.   ORGANOMETALLICS

Deactivation of the Cobalt Catalyst for the Cyclotrimerization of Acetylenes in Ionic Liquids: Solvent Effects on the Mechanism and Thermal and Pressure Activation Parameters

(2011) Teresa Avilés et al.   ORGANOMETALLICS

Participation of Carbonyl Oxygen in Carbon–Carboxylate Bond-Forming Reductive Elimination from Palladium

(2011) J. Brannon Gary et al.   ORGANOMETALLICS

Palladium(II)-Catalyzed CH Bond Arylation of Electron-Deficient Arenes at Room Temperature

(2010) Matthew J. Tredwell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of benzolactams by Pd(ii)-catalyzed carbonylation of N-unprotected arylethylamines

(2010) Blanca López et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

C—H Bond Activation in Transition Metal Species from a Computational Perspective

(2010) David Balcells et al.   CHEMICAL REVIEWS

Understanding chemical reaction mechanisms in ionic liquids: successes and challenges

(2010) Colin D. Hubbard et al.   CHEMICAL SOCIETY REVIEWS

Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism

(2010) Keary M. Engle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides

(2010) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ortho-Palladation of (Z)-2-Aryl-4-Arylidene-5(4H)-Oxazolones. Structure and Functionalization

(2010) Gheorghe-Doru Roiban et al.   ORGANOMETALLICS

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High-Oxidation-State Palladium Catalysis: New Reactivity for Organic Synthesis

(2009) Kilian Muñiz   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends

(2009) Martin Albrecht   CHEMICAL REVIEWS

Striking AcOH Acceleration in Direct Intramolecular Allylic Amination Reactions

(2009) Fady Nahra et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cyclometallation of amino-imines on palladium complexes. The effect of the solvent on the experimental and calculated mechanism

(2009) Gabriel Aullón et al.   DALTON TRANSACTIONS

Enthalpy of ligand substitution in cis organopalladium complexes with monodentate ligands

(2009) Gorka Salas et al.   DALTON TRANSACTIONS

Mechanisms of C–H bond activation: rich synergy between computation and experiment

(2009) Youcef Boutadla et al.   DALTON TRANSACTIONS

Mechanistic Studies on Fast Ligand Substitution Reactions of Pt(II) in Different Ionic Liquids: Role of Solvent Polarity and Ion-Pair Formation

(2008) Svetlana Begel et al.   INORGANIC CHEMISTRY

Hydrogen Tunneling in Protonolysis of Platinum(II) and Palladium(II) Methyl Complexes: Mechanistic Implications

(2008) John E. Bercaw et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon–heteroatom bond formation catalysed by organometallic complexes

(2008) John F. Hartwig   NATURE

Activation of C–H and C–Br bonds in cyclopalladation reactions of Schiff base ligands: Influence of the benzylidene ring substituents

(2007) Leticia Naya et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY