Journal
CRYSTAL GROWTH & DESIGN
Volume 14, Issue 7, Pages 3174-3178Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg5004353
Keywords
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Funding
- National Natural Science Foundation of China [21071028, 21001023, 21277022, 21371030, 21301026]
- Fundamental Research Funds for the Central Universities of China
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Solvothermal reaction of multidentate organic ligand, 5,5',5 '',5 ''',5],5]'-[1,2,3,4,5,6-phenylhexamethoxyl]-hexaisophthalic acid (H12L), with Cd(NO3)center dot 4H(2)O produced an anionic 3D metal-organic framework [(CH3)(2)NH2](4)[Cd-3(H2L)] (1), which features a novel cage-to-cage connection. Interestingly, the 1D channel, which is stacked by cages, is divided into uniform segments by molecular-scale bricks. The luminescent properties of compound 1 have been explored, which shows that 1 is a potential luminescent sensory material for nitrobenzene.
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