Journal
CRYSTAL GROWTH & DESIGN
Volume 14, Issue 3, Pages 923-927Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg4008894
Keywords
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Funding
- Russian Foundation for Basic Research [11-02-98002-r, 12-02-00056]
- integration project SB RAS [28, SS-4828.2012.2]
- Federal Special Program Scientific and scientific-pedagogical staff of innovative Russia [8379]
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The lambda-shaped line width broadening anomalies of octahedron group vibrations in Rb2KMoO3F3 disordered crystal have been revealed in the wide temperature range by Raman technique. The line width of Mo-O and Mo-F vibrations in this crystal is connected with the lattice disorder. The dependence of ordering degree passing the phase transition point history has been discovered. Wide temperature line width area is found below structural phase transition where different lattice disorder can be obtained at a given temperature by varying the rate of sample cooling. The current study demonstrates the ability of a dynamic temperature regime to control ordering processes in crystals.
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