Journal
CRYSTAL GROWTH & DESIGN
Volume 14, Issue 12, Pages 6521-6527Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg501425x
Keywords
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Funding
- National Natural Science Foundation of China [21271117]
- Shandong Natural Science Fund [JQ201003]
- National Science Foundation of Shandong Province [BS2011CL041]
- Fundamental Research Funds for the Central Universities [13CX05010A, 13CX02006A]
- [NCET-11-0309]
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Two 2-fold interpenetrating metal-organic frameworks based on 1,3,5-tris[2-(4-carboxyphenyl)-1-ethynyl]-2,4,6-trimethylbenzene (H3LMe), [Mn-3(LMe)(2)(DMF)(4)(H2O)]center dot 1.5DMF center dot 3.5H(2)O (1) and [Cd-3(LMe)(2)(DMF)][Cd-3(LMe)(2)(DMF)(2)(H2O)]center dot 5DMF center dot 3.5H(2)O (2), have been synthesized by using rigid trigonal H3LMe and nitrate under solvothermal conditions. Complex 1 displays a three-dimensional open framework with rare (3,6)-connected 2-nodal sit topology, whereas complex 2 features a new (3,3,6)-connected topology. Both 1 and 2 are blue fluorescent, and the magnetic measurement of 1 indicates that metal centers within the trinuclear cluster exhibit antiferromagnetic coupling interactions. Significantly, although complexes 1 and 2 have similar total solvent-accessible volumes, 2 demonstrates a higher Brunauer-Emmett-Teller surface area than that of 1, further indicating the influence of pore structure on gas absorption.
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