Journal
CRYSTAL GROWTH & DESIGN
Volume 14, Issue 11, Pages 5634-5639Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg5009279
Keywords
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Funding
- Advanced Low Carbon Technology Research and Development Program (ALCA), Japan Science and Technology Agency
- Research and Development Program for Innovative Energy Efficiency Technology, New Energy and Industrial Technology Development Organization (NEDO) of Japan [23-0712004]
- Grants-in-Aid for Scientific Research [25249089] Funding Source: KAKEN
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Thin layers of densely packed idiomorphic Li4Ti5O12 crystals were prepared directly on a Pt substrate by using a LiClNaCl mixed flux. The thin film of colloidal anatase nanoparticles with an similar to 30 nm diameter was fully converted into Li4Ti5O12 crystals with a diameter of 100-200 nm having polyhedral shapes with well-defined {111} faces during the evaporation-driven flux growth. Cross-sectional structure analysis revealed that the interface between the crystals and the substrate seemed to be atomically bonded. Galvanometric charge and discharge properties strongly supported our consideration of interface formation. The Li4Ti5O12 crystal layer exhibited a large capacity close to its theoretical value under 0.1C rate with no assistance from additional electroconductive materials and binders, meaning that the interfaces provide seamless charge transportation pathways. We also addressed the formation mechanism of the Li4Ti5O12 crystal layer accompanied by the experimental results of in situ X-ray diffraction, thermogravimetric and differential thermal analysis, and scanning electron microscopy observation.
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