Journal
CRYSTAL GROWTH & DESIGN
Volume 13, Issue 9, Pages 4066-4070Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg4009009
Keywords
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Funding
- National Research Foundation of Korea
- Korean Government [013-2011-1-C00039]
- Basic Science Research Program of NRF Korea [2012R1A1A2004333]
- National Research Foundation of Korea [013-2011-1-C00039, 2013-PAL, 2012R1A1A2004333] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A Co(II)-Ti(IV) heterometallic approach is successfully adopted to synthesize charge-neutral metal-organic frameworks based on oxo-centered trinuclear cluster and linear dicarboxylate linkers. Unlike their homonuclear predecessors, the cobalt-titanium-organic frameworks not only display a permanent porosity but also show an irreversible phase transition between two stable forms as unambiguously characterized by single-crystal and powder X-ray diffraction studies.
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