Journal
CRYSTAL GROWTH & DESIGN
Volume 10, Issue 11, Pages 4976-4986Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg101078f
Keywords
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Funding
- Department of Science & Technology (DST), New Delhi, India
- IACS
- CSIR
- DST
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A crystal engineering based design strategy for metallogels has been demonstrated in a series of mixed ligand based Cu-11/Co-11 coordination polymers derived from two bis-pyridyl-bis-amide liands namely N,N'-bis-(3-pyridyl)-isophthalamide (L1) and N,N'-bis-(3-pyridyl)terephthalamide (L2) and various dicarboxylates. These mixed ligand coordination polymers are shown to form gels as well as X-ray quality crystals under different conditions. The crystal structures of the gel fibers in the xerogels have been determined by using powder and single-crystal X-ray diffraction data. The results support the proof of the concept based on which the metallogels are designed.
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