Journal
CRYSTAL GROWTH & DESIGN
Volume 10, Issue 1, Pages 122-127Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg900587x
Keywords
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Funding
- NSF of China [60771005, 60728102]
- Beijing NSF [4092023]
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Using Ge sphere-capped ZnO nanowires as a model system, we investigate the evolution of catalyst droplets and their influence on nanowire growth in the processes including vapor-liquid-solid (VLS) growth and cooling processes. The diameter ratios between Ge particle and ZnO nanowire have approximately a normal distribution. The atomic ratio of Ge/Zn in the particle during the growing process is found to deviate enormously front the eutectic point in the Ge-Zn binary phase of diagram, indicating tertiary phase diagram has to be used. Slow cooling allows the elements separation and crystallization of Ge-Zn-O droplets and continuous growth of the nanowire at the nanowire/catalyst sphere interface. The present studies largely extend the understanding of the VLS mechanism.
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