Article
Chemistry, Multidisciplinary
Yihang Fang, Seungyeol Lee, Huifang Xu, Gabriela A. Farfan
Summary: This study provides the first overview of the effects of the physiochemical properties of amino acids and chitins on the mineralogy, composition, and morphology of Ca-Mg carbonates in solutions and on solid surfaces. Through in vitro experiments, it was discovered that acidic, negatively charged, hydrophilic amino acids (aspartic and glutamic) and chitins can induce the precipitation of high-magnesium calcite (HMC) and disordered dolomite in solution and on solid surfaces with these adsorbed biosubstrates. Therefore, acidic amino acids and chitins are expected to be among the controlling factors in biomineralization, used in different combinations to control the mineral phases, compositions, and morphologies of Ca-Mg carbonate biomineral crystals.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Multidisciplinary Sciences
Nicolai Schleinkofer, Jacek Raddatz, David Evans, Axel Gerdes, Sascha Floegel, Silke Voigt, Janina Vanessa Buescher, Max Wisshak
Summary: Acesta excavata, a slow-growing bivalve from the Limidae family, shows compositional variability in elemental ratios, indicating strong vital effects and associations with seawater temperature and salinity. Additional techniques, such as clumped isotopes, are recommended to accurately determine and quantify these effects.
Article
Engineering, Chemical
Yuki Kezuka, Eita Tochigi, Hidenobu Murata, Maya Yoshida, Atsushi Nakahira, Yuichi Ikuhara, Masahiko Tajika
Summary: In this study, calcite-core/Mg-calcite nanorods were synthesized by bubbling CO2 gas into Ca(OH)2 aqueous slurry with Mg2+ doping. The nanorods doped with higher Mg2+ concentrations showed excellent thermal stability in both water and air. The microscopic structures characterized by XRD and TEM revealed that Mg-calcite nanoclusters played a crucial role in enhancing the particle morphology stability.
ADVANCED POWDER TECHNOLOGY
(2021)
Article
Environmental Sciences
Yang Wu, Stewart J. Fallon, Neal E. Cantin, Janice M. Lough
Summary: This study utilized coral-based proxies to reconstruct sea surface temperatures, finding that U/Ca was the most reliable and stable temperature proxy for corals from the Great Barrier Reef over long-term timescales. Sr/Ca was also reliable, but less sensitive to annual SST changes. Li/Mg and B/Mg showed clearer periodicity and strong correlation with SST. Empirical calibrations from a multi-proxy approach can enhance the certainty of temperature reconstructions, especially when a single proxy may not perform well. Additionally, site- and colony-specific SST calibrations provide an opportunity to improve the universal multi-trace element calibration of sea surface temperatures.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Engineering, Environmental
Weila Li, Yunhao Zhang, Varenyam Achal
Summary: This study investigated the potential of urease-aided carbonate precipitation and its impact on free cadmium ions. The results showed that the type and morphology of carbonate largely depend on the calcium and magnesium ratios in the pure EICP system, and have little correlation when cadmium is added.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Electrochemistry
Isao Nakatsugawa, Koji Yamada, Tomoko Yamashita, Takashi Nishikawa, Yasuhito Taniguchi, Yasumasa Chino
Summary: Magnesium alloys exposed to coastal environments undergo corrosion, and the corrosion products and corrosion rate are influenced by alloy composition and environmental conditions.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Andrew J. Lew, Cayla A. Stifler, Alexandra Tits, Connor A. Schmidt, Andreas Scholl, Astrid Cantamessa, Laura Mueller, Yann Delaunois, Philippe Compere, Davide Ruffoni, Markus J. Buehler, Pupa U. P. A. Gilbert
Summary: Biominerals, the hardest and toughest tissues in living organisms, are often polycrystalline with varying mesostructures. Marine biominerals such as coral skeletons and nacre, consisting of different calcium carbonate polymorphs, share a common characteristic of slight crystal misorientation. Nanoindentation and molecular dynamics simulations show that this slight misorientation can significantly increase fracture toughness. This phenomenon can be utilized in the synthesis of bioinspired materials without the need for multiple materials or specific top-down architecture.
ADVANCED MATERIALS
(2023)
Article
Geochemistry & Geophysics
Kai Zhao, Li-Qun Dai, Wei Fang, Yong-Fei Zheng, Zi-Fu Zhao, Fei Zheng
Summary: Chemical metasomatism of the mantle wedge by slab-derived fluids is an important mechanism for the compositional features of mafic magmas above oceanic subduction zones. The decoupling of Mg and Ca isotopes in alkali basalts from the South Qinling Orogen in central China indicates possible physicochemical differentiation during the transport of metasomatic agents. These basalts exhibit OIB-like trace element distribution patterns and show decoupling between Mg and Ca isotopes, providing new insights into the differentiation behaviors of subduction zone fluids.
Article
Chemistry, Physical
Yi-Ming Ju, Fang Huang, Xin Ding, Li-Bo Mao, Shu-Hong Yu
Summary: This study clarifies the different mineralization pathways of CaCO3 under different Mg2+ ion concentrations by tracing Mg isotope fractionation. The detailed regulatory role of Mg2+ ions at different stages of mineralization is proposed.
Article
Chemistry, Physical
Yi-Ming Ju, Fang Huang, Xin Ding, Li-Bo Mao, Shu-Hong Yu
Summary: This study investigates the mechanism of Mg2+ ion-regulated mineralization of CaCO3 by tracing Mg isotope fractionation. The different mineralization pathways of CaCO3 under different Mg2+ ion concentrations are clarified, and the detailed regulatory role of Mg2+ ions at different stages of mineralization is proposed. These results provide important insights for finely controlling the phase of crystalline products.
Article
Biotechnology & Applied Microbiology
Shuquan Zhang, Chaokun Tang, Jiangtao Feng, Qi Wang, Chenguang Li, Weihao Zhang, Fengxin Zhou, Feng Xue, Baoshan Xu, Shaoyuan Lyu, Minfang Chen, Hao Wang
Summary: The effect of Zn/Ca ratio on the corrosion behavior of Mg-3Zn-0.2Ca-1.0MgO (3ZX) and Mg-1Zn-0.2Ca-1.0MgO (ZX) was investigated. It was found that the low Zn/Ca ratio led to increased grain size and a change in the nature of second phase. The absence of MgZn phase in ZX contributed to the alleviation of local galvanic corrosion and exhibited good corrosion performance in vivo experiment.
FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Lama Khalil, Cyrine Ernandes, Jose Avila, Adrien Rousseau, Pavel Dudin, Nikolai D. Zhigadlo, Guillaume Cassabois, Bernard Gil, Fabrice Oehler, Julien Chaste, Abdelkarim Ouerghi
Summary: In this study, we demonstrate the stable growth of p-type hexagonal boron nitride (h-BN) by using Mg atoms as substitutional impurities. Our experiments involving micro-Raman spectroscopy, nano-ARPES, and KPFM show that Mg-doping significantly alters the electronic properties of h-BN. The Mg dopants shift the valence band maximum and result in a reduced Fermi level difference between pristine and Mg-doped h-BN crystals. This research establishes Mg-doping as a promising method for high-quality p-type doped h-BN films, which are crucial for applications in deep ultraviolet LEDs and wide bandgap optoelectronic devices.
NANOSCALE ADVANCES
(2023)
Article
Materials Science, Multidisciplinary
Koji Hagihara, Shuhei Shakudo, Toko Tokunaga, Takayoshi Nakano
Summary: This paper attempts to establish a control strategy for the degradation behavior of dual-phase alloys composed of two phases in a Ca-Mg-Zn system, in order to develop a novel biodegradable alloy. By combining two phases with different dissolution behavior, the biodegradable alloys are expected to exhibit multiple functions. The study found that by combining IM3 and IM1 intermetallic phases with the compositions of Ca2Mg5Zn13 and Ca3Mg4.6Zn10.4, the expected degradation behavior can be achieved.
Article
Chemistry, Physical
Anastasia Kalashnova, Georgyi Sh Shekhtman
Summary: The glycine-nitrate method was used to synthesize samples in the Li6-2xMxZr2O7 (M = Mg, Ca, Zn) systems, and the synthesized solid solutions exhibited significantly higher conductivity than undoped Li6Zr2O7. The study also investigated the influence of M dopants' electronegativity on the transport properties of the solid electrolytes.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Cong Li, Weiwei Li, Xiaoliang Zhang, Liangcong Du, H. W. Sheng
Summary: In this study, the stability of magnesium-aluminum compounds under high pressure conditions was systematically explored using ab initio structural prediction methods. Three new thermodynamically stable compounds were discovered, which are essentially electrides with excess electrons confined in interstitial voids. This research has significant implications for the understanding of materials chemistry under high pressure and provides a basis for further experimental studies on the new structures of magnesium-aluminum systems.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Mineralogy
Antonio Sanchez-Navas, Elisa Macaione, Rita De Cassia Oliveira-Barbosa, Antonia Messina, Agustin Martin-Algarra
EUROPEAN JOURNAL OF MINERALOGY
(2016)
Article
Soil Science
Javier Cuadros, Jose L. Diaz-Hernandez, Antonio Sanchez-Navas, Antonio Garcia-Casco, Jorge Yepes
Article
Archaeology
Olimpia Lopez Cruz, Ana Garcia Bueno, Victor Jesus Medina Florez, Antonio Sanchez-Navas
JOURNAL OF CULTURAL HERITAGE
(2016)
Article
Meteorology & Atmospheric Sciences
Jose L. Diaz-Hernandez, Antonio Sanchez-Navas
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
(2016)
Article
Archaeology
Jose Antonio Lozano, Encarnacion Puga, Antonio Garcia-Casco, Francisco Martinez-Sevilla, Francisco Contreras Cortes, Javier Carrasco Rus, Agustin Martin-Algarra
GEOARCHAEOLOGY-AN INTERNATIONAL JOURNAL
(2018)
Article
Geosciences, Multidisciplinary
Rosario Rodriguez-Canero, Antonio Jabaloy-Sanchez, Pilar Navas-Parejo, Agustin Martin-Algarra
INTERNATIONAL JOURNAL OF EARTH SCIENCES
(2018)
Article
Geology
Antonio Sanchez-Navas, Antonio Garcia-Casco, Stefano Mazzoli, Agustin Martin-Algarra
JOURNAL OF GEOLOGY
(2017)
Item Withdrawal
Geosciences, Multidisciplinary
C. Rodriguez, E. Aragon, A. Castro, R. Pedreira, A. Sanchez-Navas, J. Diaz-Alvarado, F. D'Eramo, L. Pinotti, Y. Aguilera, C. Cavarozzi, M. Demartis, I. R. Hernando, T. Fuentes
JOURNAL OF SOUTH AMERICAN EARTH SCIENCES
(2017)
Article
Geochemistry & Geophysics
J. L. Diaz-Hernandez, A. Sanchez-Navas, A. Delgado, J. Yepes, A. Garcia-Casco
GEOCHIMICA ET COSMOCHIMICA ACTA
(2018)
Article
Multidisciplinary Sciences
Adrian Lopez-Quiros, Carlota Escutia, Antonio Sanchez-Navas, Fernando Nieto, Antonio Garcia-Casco, Agustin Martin-Algarra, Dimitris Evangelinos, Ariadna Salabarnada
SCIENTIFIC REPORTS
(2019)
Article
Geology
Alejandro Ruiz-Fuentes, Angela Cabrera-Porras, Agustin Martin-Algarra
Summary: The Malaguide Complex is located in the highest position of an Alpine thrust stack and consists of sedimentary and low-grade metamorphic rocks. The complex underwent severe shearing and stretching along the Betic suture zone after the Burdigalian due to collision with the South-Eastern Iberian Paleomargin. The orogenic evolution in the backstop region involved pre-collisional shortening and thrust stacking, followed by folding and thrusting and a final phase of post-orogenic extension.
INTERNATIONAL GEOLOGY REVIEW
(2022)
Article
Geology
I. F. Blanco-Quintero, A. Martin-Algarra, E. Santamaria-Perez, J. M. Gonzalez-Jimenez, A. Sanchez Navas, D. Benavente, J. C. Canaveras, A. Garcia-Casco
Summary: The sedimentary successions in southern Spain contain shallow-intrusive basic bodies of Mesozoic age, which have experienced low-grade Alpine metamorphism. The magmatic protoliths are subalkaline (tholeiitic) to alkaline basaltic magmas enriched in incompatible elements. The metamorphic minerals include magnesioriebeckite, actinolite, albite, stilpnomelane, phengite, and chlorite. The P-T conditions suggest a collisional (Barrovian) event and metamorphic correlation with the accreted passive margin of South Iberia.
INTERNATIONAL GEOLOGY REVIEW
(2023)
Article
Geology
Antonio Sanchez-Navas, Agustin Martin-Algarra, Idael Blanco-Quintero, Antonio Garcia-Casco
Summary: This study investigates the medium and high grade graphitic metapelites in the Torrox Unit of the Western Mediterranean. The research reveals the presence of kyanite-andalusite-kyanite replacements and different types of coexisting garnet, indicating two distinct orogenic cycles. These findings provide valuable insights into the geological evolution of the area.
INTERNATIONAL GEOLOGY REVIEW
(2023)