Efficient imidation of C(sp3)–H bonds adjacent to oxygen atoms of aryl ethers under metal-free conditions

nBu4NI-Catalyzed oxidative imidation of ketones with imides: synthesis of α-amino ketones

(2014) Yunhe Lv et al.   CHEMICAL COMMUNICATIONS

n-Bu4NI/TBHP-catalyzed direct amination of allylic and benzylic C(sp3)–H with anilines under metal-free conditions

(2014) Xusheng Zhang et al.   CHEMICAL COMMUNICATIONS

A powerful combination: recent achievements on using TBAI and TBHP as oxidation system

(2014) Xiao-Feng Wu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Esterification of Alkylbenzenes with Cyclic Ethers and Cycloalkanes via C(sp3)–H Activation Following Cross-Dehydrogenative Coupling

(2014) Saroj Kumar Rout et al.   ORGANIC LETTERS

Transition-Metal-Assisted Radical/Radical Cross-Coupling: A New Strategy to the Oxidative C(sp3)–H/N–H Cross-Coupling

(2014) Liangliang Zhou et al.   ORGANIC LETTERS

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Functionalization of Tetrahydrofuran and 1,4-Dioxane: Nickel-Catalyzed Oxidative C(sp3)H Arylation

(2013) Dong Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds

(2013) Qicai Xue et al.   CHEMICAL COMMUNICATIONS

Oxidative C–H amination reactions

(2013) Marie-Laure Louillat et al.   CHEMICAL SOCIETY REVIEWS

Cu-Catalyzed Cross-Dehydrogenative Coupling Reactions of (Benzo)thiazoles with Cyclic Ethers

(2013) Zengyang Xie et al.   ORGANIC LETTERS

Copper-Catalyzed Intermolecular Dehydrogenative Amidation/Amination of Quinoline N-Oxides with Lactams/Cyclamines

(2013) Gang Li et al.   ORGANIC LETTERS

Metal-Free Oxidative C(sp3)–H Bond Thiolation of Ethers with Disulfides

(2013) Sheng-rong Guo et al.   ORGANIC LETTERS

A Metal-Free Oxidative Esterification of the Benzyl CH Bond

(2012) Jie Feng et al.   ADVANCED SYNTHESIS & CATALYSIS

Organocatalytic Amidation and Esterification of Aldehydes with Activating Reagents by a Cross-Coupling Strategy

(2012) Bin Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross Coupling of Acyl and Aminyl Radicals: Direct Synthesis of Amides Catalyzed by Bu4NI with TBHP as an Oxidant

(2012) Zhaojun Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free α-CH amination of ethers with hypervalent sulfonylimino-λ3-bromane that acts as an active nitrenoid

(2012) Masahito Ochiai et al.   CHEMICAL COMMUNICATIONS

nBu4NI-catalyzed C3-formylation of indoles with N-methylaniline

(2012) Lan-Tao Li et al.   CHEMICAL COMMUNICATIONS

nBu4NI-catalyzed direct synthesis of α-ketoamides from aryl methyl ketones with dialkylformamides in water using TBHP as oxidant

(2012) Wen-Peng Mai et al.   CHEMICAL COMMUNICATIONS

Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

(2012) Chun Zhang et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Formation of CO Bonds by Direct α-CH Bond Activation of Ethers Using Stoichiometric Amounts of Peroxide in Batch and Continuous-Flow Formats

(2012) G. Sathish Kumar et al.   CHEMISTRY-A EUROPEAN JOURNAL

C–H Bond Functionalization via Hydride Transfer: Formation of α-Arylated Piperidines and 1,2,3,4-Tetrahydroisoquinolines via Stereoselective Intramolecular Amination of Benzylic C–H Bonds

(2012) Paul A. Vadola et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed Intramolecular Allylic C–H Amination

(2012) Shauna M. Paradine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Oxidative Carbonylation of Benzylic C–H Bonds via Nondirected C(sp3)–H Activation

(2012) Pan Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Dehydrogenative Olefination of Vinylic C–H Bonds with Allylic Esters: General and Selective Access to Linear 1,3-Butadienes

(2012) Yuexia Zhang et al.   ORGANIC LETTERS

Copper-catalyzed N-alkoxyalkylation of nucleobases involving direct functionalization of sp3 C–H bonds adjacent to oxygen atoms

(2012) Rui Huang et al.   TETRAHEDRON

Copper-catalyzed decarboxylative alkenylation of sp3 C–H bonds with cinnamic acids via a radical process

(2012) Zili Cui et al.   Chemical Science

Highly Regioselective Copper-Catalyzed Benzylic CH Amination by N-Fluorobenzenesulfonimide

(2011) Zhikun Ni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis with In Situ-Generated (Hypo)iodite Ions for Oxidative Coupling Reactions

(2011) Muhammet Uyanik et al.   ChemCatChem

TBAI-catalyzed oxidative coupling of aminopyridines with β-keto esters and 1,3-diones—synthesis of imidazo[1,2-a]pyridines

(2011) Lijuan Ma et al.   CHEMICAL COMMUNICATIONS

Synthesis of tert-butyl peresters from aldehydes by Bu4NI-catalyzed metal-free oxidation and its combination with the Kharasch–Sosnovsky reaction

(2011) Wei Wei et al.   CHEMICAL COMMUNICATIONS

Metal-free, organocatalytic cascade formation of C–N and C–O bonds through dual sp3C–H activation: oxidative synthesis of oxazole derivatives

(2011) Jin Xie et al.   CHEMICAL COMMUNICATIONS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Microwave-assisted C–C bond forming cross-coupling reactions: an overview

(2011) Vaibhav P. Mehta et al.   CHEMICAL SOCIETY REVIEWS

Activation of “Inert” Alkenyl/Aryl CO Bond and Its Application in Cross-Coupling Reactions

(2011) Bi-Jie Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Podophyllotoxin and Deoxypodophyllotoxin in Juniperus bermudiana and 12 OtherJuniperusSpecies: Optimization of Extraction, Method Validation, and Quantification

(2011) Sullivan Renouard et al.   JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY

Metachromins U–W: Cytotoxic Merosesquiterpenoids from an Australian Specimen of the SpongeThorecta reticulata

(2011) Simon P. B. Ovenden et al.   JOURNAL OF NATURAL PRODUCTS

Palladium-Catalyzed C−H Aminations of Anilides withN-Fluorobenzenesulfonimide

(2011) Kai Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Diruthenium Catalyst for Selective, Intramolecular Allylic C–H Amination: Reaction Development and Mechanistic Insight Gained through Experiment and Theory

(2011) Mark Edwin Harvey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Metal-Free Amination of Benzoxazoles – The First Example of an Iodide-Catalyzed Oxidative Amination of Heteroarenes

(2011) Tanja Froehr et al.   ORGANIC LETTERS

Direct C2-Alkylation of Azoles with Alcohols and Ethers through Dehydrogenative Cross-Coupling under Metal-Free Conditions

(2011) Tao He et al.   ORGANIC LETTERS

Unorthodox chemistry for an unorthodox challenge: Exploration of new chemical reactivities for a sustainable future

(2011) Chao-Jun Li   Science China-Chemistry

Exploration of New C−O Electrophiles in Cross-Coupling Reactions

(2010) Da-Gang Yu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct Azole Amination: CH Functionalization as a New Approach to Biologically Important Heterocycles

(2010) Alan Armstrong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Traditional Cross Couplings: The Scope of the Cross Dehydrogenative Coupling Reaction

(2010) Caroline J. Scheuermann   Chemistry-An Asian Journal

Pyrrole Synthesis via Allylic sp3C−H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes

(2010) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope and Mechanism of Allylic C−H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)2Catalyst System: Insights into the Effect of Naphthoquinone

(2010) Guoyin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-CatalyzedN-Alkylation of Azoles via Oxidation of C−H Bond Adjacent to an Oxygen Atom

(2010) Shiguang Pan et al.   ORGANIC LETTERS

Catalytic Oxidative Coupling Reactions for the Formation of Carbon-Carbon Bonds without Carbon-Metal Intermediates

(2010) Martin Klussmann et al.   SYNTHESIS-STUTTGART

Catalytic C–H amination: recent progress and future directions

(2009) Florence Collet et al.   CHEMICAL COMMUNICATIONS

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

C−H Bond Oxidation Initiated Pummerer- and Knoevenagel-Type Reactions of Benzyl Sulfide and 1,3-Dicarbonyl Compounds

(2008) Zhiping Li et al.   ORGANIC LETTERS