Enantioselective Construction of Spiroindolines with Three Contiguous Stereogenic Centers and Chiral Tryptamine Derivatives via Reactive Spiroindolenine Intermediates

Intramolecular Dearomative Oxidative Coupling of Indoles: A Unified Strategy for the Total Synthesis of Indoline Alkaloids

(2015) Weiwei Zi et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules

(2015) Yiyang Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Synthesis of Pyrrole-Based Spiro- and Polycyclic Derivatives by Iridium-Catalyzed Asymmetric Allylic Dearomatization and Controllable Migration Reactions

(2015) Chun-Xiang Zhuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Dearomatization of Indoles through a Michael/Friedel-Crafts-Type Cascade To Construct Polycyclic Spiroindolines

(2015) Xiaohu Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Enantioselective Allylic Alkylation with Functionalized Organozinc Bromides

(2015) James Y. Hamilton et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Synthesis of Alsmaphorazine B Demonstrates the Chemical Feasibility of a New Biogenetic Hypothesis

(2015) Allen Y. Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Syntheses of (−)-Mersicarpine, (−)-Scholarisine G, (+)-Melodinine E, (−)-Leuconoxine, (−)-Leuconolam, (−)-Leuconodine A, (+)-Leuconodine F, and (−)-Leuconodine C: Self-Induced Diastereomeric Anisochronism (SIDA) Phenomenon for Scholarisine G and Leuconodines A and C

(2015) Zhengren Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Arylative Dearomatization of Indoles via Pd-Catalyzed Intramolecular Reductive Heck Reactions

(2015) Chong Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formaldehyde N,N-Dialkylhydrazones as Neutral Formyl Anion Equivalents in Iridium-Catalyzed Asymmetric Allylic Substitution

(2015) Simon Breitler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Catalyzed Asymmetric Allylic Dearomatization Reactions

(2014) Chun-Xiang Zhuo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Michael/aza-Michael/Cyclization Organocascade to Tetracyclic Spiroindolines: Concise Total Synthesis of Kopsinine and Aspidofractine

(2014) Xiaoyu Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Organocatalytic Asymmetric Arylative Dearomatization of 2,3-Disubstituted Indoles Enabled by Tandem Reactions

(2014) Yu-Chen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Regio- and Enantioselective Synthesis of N-Substituted 2-Pyridones: Iridium-Catalyzed Intermolecular Asymmetric Allylic Amination

(2014) Xiao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Semisynthetic Analogues of Toxiferine I and Their Pharmacological Properties at α7 nAChRs, Muscle-Type nAChRs, and the Allosteric Binding Site of Muscarinic M2 Receptors

(2014) Darius P. Zlotos et al.   JOURNAL OF NATURAL PRODUCTS

Evolution of a Unified, Stereodivergent Approach to the Synthesis of Communesin F and Perophoramidine

(2014) Seo-Jung Han et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed Enantioselective Allyl–Alkene Coupling

(2014) James Y. Hamilton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote Ester Groups Switch Selectivity: Diastereodivergent Synthesis of Tetracyclic Spiroindolines

(2014) Jun Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent α-Allylation of Linear Aldehydes with Dual Iridium and Amine Catalysis

(2014) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in dearomatization of heteroaromatic compounds

(2014) Qiuping Ding et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed Asymmetric Cycloadditions of Vinylcyclopropanes and in Situ Formed Unsaturated Imines: Construction of Structurally and Optically Enriched Spiroindolenines

(2014) Ze-Shui Liu et al.   ORGANIC LETTERS

A Diastereodivergent Synthetic Strategy for the Syntheses of Communesin F and Perophoramidine

(2014) Seo-Jung Han et al.   ORGANIC LETTERS

Melosuavines A–H, Cytotoxic Bisindole Alkaloid Derivatives from Melodinus suaveolens

(2013) Ya-Ping Liu et al.   JOURNAL OF NATURAL PRODUCTS

Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters via Ir-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation and Applications in Sequential Pd Catalysis

(2013) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Functionalization of Indoles and Pyrroles via an in Situ-Formed Spiro Intermediate

(2013) Chun-Xiang Zhuo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Control of Diastereoselectivity for Iridium-Catalyzed Allylation of a Prochiral Nucleophile with a Phosphate Counterion

(2013) Wenyong Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio-, Diastereo-, and Regioselective Iridium-Catalyzed Asymmetric Allylic Alkylation of Acyclic β-Ketoesters

(2013) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Synthesis of Tetrahydrocarbolines via Iridium-Catalyzed Intramolecular Friedel–Crafts Type Allylic Alkylation Reactions

(2013) Qing-Long Xu et al.   ORGANIC LETTERS

Enantioselective Chlorocyclization of Indole Derived Benzamides for the Synthesis of Spiro-indolines

(2013) Qin Yin et al.   ORGANIC LETTERS

Enantio- and Diastereodivergent Dual Catalysis:  -Allylation of Branched Aldehydes

(2013) S. Krautwald et al.   SCIENCE

Enantioselective Synthesis of Spiro Cyclopentane-1,3′-indoles and 2,3,4,9-Tetrahydro-1H-carbazoles by Iridium-Catalyzed Allylic Dearomatization and Stereospecific Migration

(2012) Qing-Feng Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Allylic Thioetherification: The Effect of Phosphoric Acid Diester on Iridium-Catalyzed Enantioconvergent Transformations

(2012) Markus Roggen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Dearomatization Reactions

(2012) Chun-Xiang Zhuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Allylic Alkylation Reaction with N-Aryl Phosphoramidite Ligands: Scope and Mechanistic Studies

(2012) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Regioselective and Enantioselective Allylation of Trimethylsiloxyfuran

(2012) Wenyong Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Enantioselective Polyene Cyclization

(2012) Michael A. Schafroth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Enantioselective Allylic Vinylation

(2012) James Y. Hamilton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances and applications of iridium-catalysed asymmetric allylic substitution

(2012) Paolo Tosatti et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Gold-Catalyzed Synthesis of Polycyclic Indolines

(2012) Gianpiero Cera et al.   ORGANIC LETTERS

Total Synthesis of Indoline Alkaloids: A Cyclopropanation Strategy

(2011) Dan Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Michael/Mannich Polycyclization Cascade of Indolyl Enones Catalyzed by Quinine-Derived Primary Amines

(2011) Quan Cai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Total Syntheses of Communesins A and B

(2011) Zhiwei Zuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective synthesis of tetracyclic indolines via gold-catalyzed cascade cyclization reactions

(2011) Gianpiero Cera et al.   CHEMICAL COMMUNICATIONS

Collective synthesis of natural products by means of organocascade catalysis

(2011) Spencer B. Jones et al.   NATURE

Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution

(2010) John F. Hartwig et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Construction of Spiroindolenines by Ir-Catalyzed Allylic Alkylation Reactions

(2010) Qing-Feng Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of (+)-Perophoramidine and Determination of the Absolute Configuration

(2010) Haoxing Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alsmaphorazines A and B, Novel Indole Alkaloids fromAlstonia pneumatophora

(2010) Koichiro Koyama et al.   ORGANIC LETTERS

Monoterpenoid Indole Alkaloids fromAlstonia yunnanensis

(2009) Tao Feng et al.   JOURNAL OF NATURAL PRODUCTS

Asymmetric Syntheses of Oxindole and Indole Spirocyclic Alkaloid Natural Products

(2009) Barry Trost et al.   SYNTHESIS-STUTTGART