Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 32, Issue 6, Pages 513-520Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201300924
Keywords
dye-sensitized solar cells; SalenZn complexes; salicylic acid; anchoring group
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Funding
- National Natural Science Foundation of China [21173106]
- Foundation of State Key Laboratory of Coal Conversion [J14-15-913-1]
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A series of SalenZn based dyes with triphenylamine derivatives as the donor, benzoic acid as the acceptor, and coplanar Salen complexes as the spacer have been designed and synthesized for dye-sensitized solar cells. The absorption, electrochemical, and photovoltaic properties for all sensitizers have been systematically investigated. When the tail length of the alkyl substituents is increased from C-0 to C-8 on the donor part, the efficiency of its DSSC augments evidently. It is found that the incorporation of bis-carboxyl groups instead of the single carboxyl group as anchoring groups induces a remarkable enhancement of the electron injection efficiency from the excited dyes to the TiO2 semiconductor and generates higher electron density and voltage.
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