Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 30, Issue 11, Pages 2664-2668Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201200944
Keywords
asymmetric catalysis; hydrogenation; iridium; 2H-1; 4-benzoxazine; phosphine-aminophosphine ligand
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Funding
- Dalian Institute of Chemical Physics (CAS)
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Unsymmetrical hybrid chiral phosphine-aminophosphine ligand derived from 1,2,3,4-tetrahydro-1-naphthylamine has been found to be highly efficient in the Ir-catalyzed asymmetric hydrogenation of various 3-aryl-2H-1,4-benzoxazines, providing good enantioselectivities (up to 95% ee) and high catalytic activity (S/C up to 5000).
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