Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 28, Issue 9, Pages 1635-1639Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201090277
Keywords
elimination; natural products; allenes; alkynes; sulfoxides
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Funding
- National Basic Research Program of China (973 Program) [2010CB833200]
- National Natural Science Foundation of China [20921091, 20672129, 20621062, 20772143]
- Chinese Academy of Sciences [KJCX2.YW.H08]
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1,2-Elimination of optically-active vinyl sulfoxide-allylic acetates led to corresponding allenynes in excellent yields. When the chirality of the sulfinyl group matched that at the allylic position, the chirality at the allylic stereogenic center could be efficiently transferred to the allenic axis.
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