Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 27, Issue 9, Pages 1801-1804Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.200990303
Keywords
sulfide; sulfoxide; homoselectivity; silica Sulfuric acid; sodium nitrite (NaNO2)
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Highly efficient selective oxidation of sulfides to sulfoxides by NaNO2 and silica sulfuric acid catalyzed with KBr or NaBr has been reported. This oxidation was carried out in the presence of wet SiO2 (50% svhv) in acetonitrile at room temperature with good to excellent yields.
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