Silicon-Based Bulky Group-Induced Remote Control and Conformational Preference in the Synthesis and Application of Isolable Atropisomeric Amides with Secondary Alcohol or Amine Moieties

The Supersilyl Group as a Carboxylic Acid Protecting Group: Application to Highly Stereoselective Aldol and Mannich Reactions

(2013) Jiajing Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation of Organolithium Compounds bearing Super Silyl Ester and their Application to Matteson Rearrangement

(2013) Susumu Oda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Foldamer-Mediated Remote Stereocontrol: >1,60 Asymmetric Induction

(2013) Liam Byrne et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unique Structural Properties of 2,4,6-Tri-tert-butylanilide: Isomerization and Switching between Separable Amide Rotamers through the Reaction of Anilide Enolates

(2013) Shiori Tsukagoshi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium- and Rhodium-Catalyzed Dehydrogenative Silylations of C(sp3)H Bonds Adjacent to a Nitrogen Atom Using Hydrosilanes

(2013) Tsuyoshi Mita et al.   Chemistry-An Asian Journal

Synthesis of Acylsilanes via Nickel-Catalyzed Reactions of α-Hydroxyallylsilanes

(2013) Gangireddy PavanKumar Reddy et al.   ORGANIC LETTERS

Reactive 2-quinolones dearomatized by steric repulsion between 1-methyl and 8-substituted groups

(2013) Xin Chen et al.   TETRAHEDRON

Increasing appendage diversity on 3,4-dihydro-3-oxo-2H-1,4-benzoxazines via Aphos–Pd(OAc)2-catalyzed Suzuki–Miyaura cross-coupling of aryl chlorides

(2013) Gongli Yu et al.   TETRAHEDRON

Cooperativity between steric repulsion and crossed diene coordination governs the enantioselectivity in rhodium(i)/chiral, 1,4- and 1,5-diene-catalysed 1,4-addition reaction: a DFT study

(2013) Eric Assen B. Kantchev   Chemical Science

Molecular Rotors: What Lies Behind the High Sensitivity of the Thioflavin-T Fluorescent Marker

(2012) Nadav Amdursky et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rapid and Stereochemically Flexible Synthesis of Polypropionates: Super-Silyl-Governed Aldol Cascades

(2012) Patrick B. Brady et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbosilane glycodendrimers

(2012) Ken Hatano et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Huisgen and Oxidative Huisgen Coupling Reactions Controlled by Polysiloxane-Supported Amines (AFPs) for the Divergent Synthesis of Triazoles and Bistriazoles

(2012) Zhan-Jiang Zheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Observations and Descriptions versus Explanations-An Example: Does Nature, Does Theory Know About Steric Hindrance?

(2012) W. H. Eugen Schwarz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aromatic-Amide-Derived Olefins as a Springboard: Isomerization-Initiated Palladium-Catalyzed Hydrogenation of Olefins and Reductive Decarbonylation of Acyl Chlorides with Hydrosilane

(2012) Xing-Feng Bai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rapid Total Syntheses Utilizing “Supersilyl” Chemistry

(2011) Brian J. Albert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalysed cross-coupling of organosilicon reagents

(2011) Hannah F. Sore et al.   CHEMICAL SOCIETY REVIEWS

Ligand Effects in the Formation of Tertiary Carbanions from Substituted Tertiary Aromatic Amides

(2011) Alison Campbell Smith et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Zinc-Catalyzed Hydrosilylation of Ketones using Pybox or Pybim Ligands

(2011) Kathrin Junge et al.   Chemistry-An Asian Journal

Peterson Olefination: Unexpected Rearrangement in the Overcrowded Polycyclic Aromatic Ene Series

(2011) Naela Assadi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Substituted Functional Olefins Through Lateral Sequential Lithiation/Silylation/Condensation of Tertiary Aromatic Amides: A Ligand for Phosphane-Free Palladium-Catalyzed Suzuki Coupling Reactions

(2011) Li-Wen Xu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Regioselective Lithium Diisopropylamide-Mediated Ortholithiation of 1-Chloro-3-(trifluoromethyl)benzene: Role of Autocatalysis, Lithium Chloride Catalysis, and Reversibility

(2011) Alexander C. Hoepker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Free Radical and RAFT Polymerization of Bulky Silyl Methacrylates for Tacticity and Molecular Weight Controlled Poly(methacrylic acid)

(2011) Kenji Ishitake et al.   MACROMOLECULES

A Highly Efficient Conversion of a Simple Derivative of the Amino Acid Proline into a Nearly Enantiomerically Pure N-Protected Allyl Amine: Use of Thionyl Chloride to Promote the Peterson Olefination

(2011) Guoqing Wei et al.   SYNLETT

Asymmetric Synthesis with Silicon-Based Bulky Amino Organocatalysts

(2010) Li-Wen Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

The recent synthesis and application of silicon-stereogenic silanes: A renewed and significant challenge in asymmetric synthesis

(2010) Li-Wen Xu et al.   CHEMICAL SOCIETY REVIEWS

Molecular Rotors and Motors: Recent Advances and Future Challenges

(2009) Josef Michl et al.   ACS Nano

The Interplay between Steric and Electronic Effects in SN2 Reactions

(2009) Israel Fernández et al.   CHEMISTRY-A EUROPEAN JOURNAL

Memory of Chirality of Tertiary Aromatic Amides: A Simple and Efficient Method for the Enantioselective Synthesis of Quaternary α-Amino Acids

(2009) Mathieu Branca et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transmission of stereochemical information over nanometre distances in chemical reactions

(2008) Jonathan Clayden   CHEMICAL SOCIETY REVIEWS

N,N′-Diarylureas: A New Family of Atropisomers Exhibiting Highly Diastereoselective Reactivity

(2008) Jonathan Clayden et al.   JOURNAL OF ORGANIC CHEMISTRY

Tertiary Aromatic Amide for Memory of Chirality: Access to Enantioenriched α-Substituted Valine

(2008) Mathieu Branca et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An improved synthesis of α-phosphonoenamines based on a modified Peterson olefination

(2007) James McNulty et al.   TETRAHEDRON LETTERS