Aromatic-Amide-Derived Olefins as a Springboard: Isomerization-Initiated Palladium-Catalyzed Hydrogenation of Olefins and Reductive Decarbonylation of Acyl Chlorides with Hydrosilane

Catalytic Asymmetric Intramolecular Hydroacylation with Rhodium/Phosphoramidite-Alkene Ligand Complexes

(2011) Thomas J. Hoffman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Sulfoxide-Olefin Ligands: Completely Switchable Stereoselectivity in Rhodium-Catalyzed Asymmetric Conjugate Additions

(2011) Guihua Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile synthesis of 4-vinyl- and 4-fluorovinyl-1,2,3-triazoles via bifunctional “click-olefination” reagents

(2011) Rakesh Kumar et al.   CHEMICAL COMMUNICATIONS

Highly Enantioselective Rhodium-Catalyzed Asymmetric 1,4-Addition Reactions of Arylboronic Acids to Acyclic α,β-Unsaturated Compounds: The Formal Synthesis of (−)-Indatraline

(2011) Wei-Ting Wei et al.   CHEMISTRY-A EUROPEAN JOURNAL

Peterson Olefination: Unexpected Rearrangement in the Overcrowded Polycyclic Aromatic Ene Series

(2011) Naela Assadi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Substituted Functional Olefins Through Lateral Sequential Lithiation/Silylation/Condensation of Tertiary Aromatic Amides: A Ligand for Phosphane-Free Palladium-Catalyzed Suzuki Coupling Reactions

(2011) Li-Wen Xu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed Stereospecific Activation of Olefinic C–H Bonds with Grignard Reagent for Synthesis of Substituted Olefins

(2011) Laurean Ilies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Regio- and Stereoselective Hydrometalation of Alkynes with a Combination of Carboxylic Acids and Group 10 Transition Metal Complexes: Selective Hydrogenation of Alkynes with Formic Acid

(2011) Ruwei Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterization and Dynamics of Substituted Ruthenacyclobutanes Relevant to the Olefin Cross-Metathesis Reaction

(2011) Anna G. Wenzel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic Resolution of Hindered Morita–Baylis–Hillman Adducts by Rh(I)-Catalyzed Asymmetric 1,4-Addition/β-Hydroxyelimination

(2011) Yazhou Wang et al.   ORGANIC LETTERS

α,β-Divinyl Tetrahydropyrroles as Chiral Chain Diene Ligands in Rhodium(I)-Catalyzed Enantioselective Conjugated Additions

(2011) Qian Li et al.   ORGANIC LETTERS

Access to Functionalized Steroid Side Chains via Modified Julia Olefination

(2011) Enver Cagri Izgu et al.   ORGANIC LETTERS

Design of Chiral Sulfoxide–Olefins as a New Class of Sulfur-Based Olefin Ligands for Asymmetric Catalysis

(2011) Wei-Yi Qi et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric Addition of Potassium Organotrifluoroborates toN-Sulfonyl Ketimines

(2011) Ryo Shintani et al.   ORGANIC LETTERS

Asymmetric Synthesis of β-Substituted γ-Lactams via Rhodium/Diene-Catalyzed 1,4-Additions: Application to the Synthesis of (R)-Baclofen and (R)-Rolipram

(2011) Cheng Shao et al.   ORGANIC LETTERS

A Highly Efficient Conversion of a Simple Derivative of the Amino Acid Proline into a Nearly Enantiomerically Pure N-Protected Allyl Amine: Use of Thionyl Chloride to Promote the Peterson Olefination

(2011) Guoqing Wei et al.   SYNLETT

Asymmetric Cyclopropanation of Alkenes with Dimethyl Diazomalonate Catalyzed by Chiral Diene-Rhodium Complexes

(2010) Takahiro Nishimura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Synthesis of Spirocarbocycles: Arylboron Reagents as Surrogates of 1,2-Dimetalloarenes

(2010) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Polysubstituted Olefins through Ni-Catalyzed Direct Activation of Alkenyl CO of Substituted Alkenyl Acetates

(2010) Chang-Liang Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

Role of hydrogen in olefin isomerization and hydrogenation: a molecular beam study on Pd model supported catalysts

(2010) Wiebke Ludwig et al.   DALTON TRANSACTIONS

In Situ Generated Bulky Palladium Hydride Complexes as Catalysts for the Efficient Isomerization of Olefins. Selective Transformation of Terminal Alkenes to 2-Alkenes

(2010) Delphine Gauthier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Tunable Stereoselective Olefination of Semistabilized Triphenylphosphonium Ylides withN-Sulfonyl Imines

(2010) De-Jun Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Diene as the Ligand for the Synthesis of Axially Chiral Compounds via Palladium-Catalyzed Suzuki−Miyaura Coupling Reaction

(2010) Shu-Sheng Zhang et al.   ORGANIC LETTERS

Wittig Olefination between Phosphine, Aldehyde, and Allylic Carbonate: A General Method for Stereoselective Synthesis of Trisubstituted 1,3-Dienes with Highly Variable Substituents

(2010) Rong Zhou et al.   ORGANIC LETTERS

Dicationic Alkylidene−, Olefin−, and Alkoxyalkenylcarbene−Osmium Complexes Stabilized by a NHC Ligand

(2010) María L. Buil et al.   ORGANOMETALLICS

Copper(I)−Olefin Complexes: The Effect of the Trispyrazolylborate Ancillary Ligand in Structure and Reactivity

(2010) Carmen Martín et al.   ORGANOMETALLICS

1-tert-Butyl-1H-tetrazol-5-yl fluoromethyl sulfone (TBTSO2CH2F): a versatile fluoromethylidene synthon and its use in the synthesis of monofluorinated alkenes via Julia–Kocienski olefination

(2010) Lingui Zhu et al.   TETRAHEDRON

Selective Wittig olefination in aqueous media for the rapid preparation of unsaturated 7,3-lactone-α-d-xylofuranose derivatives

(2010) Elsie Ramirez et al.   TETRAHEDRON LETTERS

Stereochemical Control by an Ester Group or Olefin Ligand in Platinum-Catalyzed Carboalkoxylation of 6-(1-Alkoxyethoxy)- hex-2-ynoates

(2009) Itaru Nakamura et al.   ADVANCED SYNTHESIS & CATALYSIS

Acceleration of Reductive Elimination of [Ar-Pd-C sp 3] by a Phosphine/Electron-Deficient Olefin Ligand: A Kinetic Investigation

(2009) Heng Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Wittig-Type Olefination of Alcohols Promoted by Nickel Nanoparticles: Synthesis of Polymethoxylated and Polyhydroxylated Stilbenes

(2009) Francisco Alonso et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of (+)-Varitriol Analogues via Novel and Versatile Building Blocks Based on Julia Olefination

(2009) Annamalai Senthilmurugan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Facile Pd(II)- and Ni(II)-Catalyzed Isomerization of Terminal Alkenes into 2-Alkenes

(2009) Hwan Jung Lim et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium catalyzed isomerization of alkenes: a pronounced influence of an o-phenol hydroxyl group

(2009) Jinmin Fan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Novel, Efficient Alkene-Phosphinite Hybrid Ligand Based ond-Glucose

(2009) Tobias Minuth et al.   ORGANIC LETTERS

C1-Symmetric Monosubstituted Chiral Diene Ligands in Asymmetric Rhodium-Catalyzed 1,4-Addition Reactions

(2008) Thomas Gendrineau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Olefins as Steering Ligands in Asymmetric Catalysis

(2008) Christian Defieber et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isomerization and Hydrogenation ofcis-2-Butene on Pd Model Catalyst

(2008) Björn Brandt et al.   Journal of Physical Chemistry C

Alkynes as Stille Reaction Pseudohalides:  Gold- and Palladium-Cocatalyzed Synthesis of Tri- and Tetra-Substituted Olefins

(2008) Yili Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Investigation of an Efficient Palladium-Catalyzed C(sp)−C(sp) Cross-Coupling Reaction Using Phosphine−Olefin Ligand: Application and Mechanistic Aspects

(2008) Wei Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient and Selective Syntheses of (all-E)- and (6E,10Z)-2′-O-Methylmyxalamides D via Pd-Catalyzed Alkenylation−Carbonyl Olefination Synergy

(2008) Guangwei Wang et al.   ORGANIC LETTERS

Palladium(0)-Catalyzed Cis−Trans Alkene Isomerizations

(2008) Luciano Canovese et al.   ORGANOMETALLICS

More than Bystanders: The Effect of Olefins on Transition-Metal-Catalyzed Cross-Coupling Reactions

(2007) Jeffrey B. Johnson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel fluorophore based on a multi-substituted olefin skeleton with enhanced three-photon absorption in the femtosecond regime

(2007) Tzu-Chau Lin et al.   CHEMICAL COMMUNICATIONS

An improved synthesis of α-phosphonoenamines based on a modified Peterson olefination

(2007) James McNulty et al.   TETRAHEDRON LETTERS