A Theoretical and Experimental Study of the Effects of Silyl Substituents in Enantioselective Reactions Catalyzed by Diphenylprolinol Silyl Ether

Organocatalytic Asymmetric Formation of Steroids

(2014) Kim Søholm Halskov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mukaiyama-Michael Reactions withtrans-2,5-Diarylpyrrolidine Catalysts: Enantioselectivity Arises from Attractive Noncovalent Interactions, Not from Steric Hindrance

(2014) Eeva K. Kemppainen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organocatalytic Asymmetric Conjugate Addition of Aldehydes to Nitroolefins: Identification of Catalytic Intermediates and the Stereoselectivity-Determining Step by ESI-MS

(2013) Florian Bächle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pot Economy in the Synthesis of Prostaglandin A1and E1Methyl Esters

(2013) Yujiro Hayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Michael Addition of Malonates to Isatylidene-3-acetaldehydes: Application to the Total Synthesis of (−)-Debromoflustramine E

(2013) Renrong Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

One-Pot Synthesis of (−)-Oseltamivir and Mechanistic Insights into the Organocatalyzed Michael Reaction

(2013) Takasuke Mukaiyama  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stoichiometric Reactions of Enamines Derived from Diphenylprolinol Silyl Ethers with Nitro Olefins and Lessons for the Corresponding Organocatalytic Conversions - a Survey

(2013) Dieter Seebach et al.   HELVETICA CHIMICA ACTA

The interplay of thermodynamics and kinetics in dictating organocatalytic reactivity and selectivity

(2013) Jordi Burés et al.   PURE AND APPLIED CHEMISTRY

Dihydrooxazine Oxides as Key Intermediates in Organocatalytic Michael Additions of Aldehydes to Nitroalkenes

(2012) Gokarneswar Sahoo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Michael Reaction of Nitroenamine Derivatives with Aldehydes: Short and Efficient Asymmetric Synthesis of (−)-Oseltamivir

(2012) Jiang Weng et al.   ChemCatChem

1,2-Oxazine N-Oxides as Catalyst Resting States in Michael Additions of Aldehydes to Nitro Olefins Organocatalyzed by α,α-Diphenylprolinol Trimethylsilyl Ether

(2012) Dieter Seebach et al.   HELVETICA CHIMICA ACTA

Secondary Amine-Catalyzed Asymmetricγ-Alkylation ofα-Branched EnalsviaDienamine Activation

(2012) Mattia Silvi et al.   HELVETICA CHIMICA ACTA

Curtin–Hammett Paradigm for Stereocontrol in Organocatalysis by Diarylprolinol Ether Catalysts

(2012) Jordi Burés et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thiol-Free Synthesis of Oseltamivir and Its Analogues via Organocatalytic Michael Additions of Oxyacetaldehydes to 2-Acylaminonitroalkenes

(2012) Július Durmis et al.   SYNTHESIS-STUTTGART

The Diarylprolinol Silyl Ether System: A General Organocatalyst

(2011) Kim L. Jensen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Inside Cover: One-Pot High-Yielding Synthesis of the DPP4-Selective Inhibitor ABT-341 by a Four-Component Coupling Mediated by a Diphenylprolinol Silyl Ether (Angew. Chem. Int. Ed. 12/2011)

(2011) Hayato Ishikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine Conformational Effects in Organocatalysis: An Emerging Strategy for Molecular Design

(2011) Lucie E. Zimmer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of (-)-Oseltamivir by Using a Microreactor in the Curtius Rearrangement

(2011) Hayato Ishikawa et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Organocatalyzed Michael Addition of Aldehydes to Nitro Alkenes - Generally Accepted Mechanism Revisited and Revised

(2011) Krystyna Patora-Komisarska et al.   HELVETICA CHIMICA ACTA

Mechanistic Rationalization of Organocatalyzed Conjugate Addition of Linear Aldehydes to Nitro-olefins

(2011) Jordi Burés et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic, Enantioselective Intramolecular [6 + 2] Cycloaddition Reaction for the Formation of Tricyclopentanoids and Insight on Its Mechanism from a Computational Study

(2011) Yujiro Hayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trienamines in Asymmetric Organocatalysis: Diels−Alder and Tandem Reactions

(2011) Zhi-Jun Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic asymmetric α-alkylation of aldehydesvia a SN2′-type addition-elimination pathway

(2011) Enrique Gómez-Bengoa et al.   Chemical Science

Distinct conformational preferences of prolinol and prolinol ether enamines in solution revealed by NMR

(2011) Markus B. Schmid et al.   Chemical Science

Asymmetric Synthesis with Silicon-Based Bulky Amino Organocatalysts

(2010) Li-Wen Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Organocatalytic Michael Addition of Aldehydes to Protected 2-Amino-1-Nitroethenes: The Practical Syntheses of Oseltamivir (Tamiflu) and Substituted 3-Aminopyrrolidines

(2010) Shaolin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High-Yielding Synthesis of the Anti-Influenza Neuraminidase Inhibitor (−)-Oseltamivir by Two “One-Pot” Sequences

(2010) Hayato Ishikawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereochemical Models for Discussing Additions toα,β-Unsaturated Aldehydes Organocatalyzed by Diarylprolinol or Imidazolidinone Derivatives - Is There an‘(E)/(Z)-Dilemma’?

(2010) Dieter Seebach et al.   HELVETICA CHIMICA ACTA

Asymmetric organocatalysis in total synthesis – a trial by fire

(2010) Eugenia Marqués-López et al.   NATURAL PRODUCT REPORTS

One-pot synthesis of chiral bicyclo[3.3.0]octatrienes using diphenylprolinol silyl ether-mediated ene-type reaction

(2010) Hiroaki Gotoh et al.   TETRAHEDRON

High-Yielding Synthesis of the Anti-Influenza Neuramidase Inhibitor (−)-Oseltamivir by Three “One-Pot” Operations

(2009) Hayato Ishikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The organocatalytic addition of bis(arylsulfonyl)methane to α,β-unsaturated aldehydes and the synthesis of optically-enriched 3-methyl-alkanols

(2009) José Luis García Ruano et al.   CHEMICAL COMMUNICATIONS

Diphenylprolinol silyl ether as a catalyst in an asymmetric, catalytic and direct α-benzoyloxylation of aldehydes

(2009) Hiroaki Gotoh et al.   CHEMICAL COMMUNICATIONS

Organocatalysis—after the gold rush

(2009) Søren Bertelsen et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Conjugate Additions of Geminal Bis(sulfone)s: Expanding the Chemistry of Sulfones as Simple Alkyl Anion Equivalents

(2009) Aitor Landa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Formal Highly Enantioselective Organocatalytic Addition of Alkyl Anions to α,β-Unsaturated Aldehydes: Application to the Synthesis of Isotope-Enantiomers

(2009) Andrea-Nekane Alba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structures of the Reactive Intermediates in Organocatalysis with Diarylprolinol Ethers

(2009) Uroš Grošelj et al.   HELVETICA CHIMICA ACTA

Diphenylprolinol Silyl Ether as a Catalyst in an Enantioselective, Catalytic, Formal Aza [3+3] Cycloaddition Reaction for the Formation of Enantioenriched Piperidines

(2008) Yujiro Hayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Aminocatalysis-Gold Rush in Organic Chemistry

(2008) Paolo Melchiorre et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Diels-Alder Reactions of α,β-Unsaturated Aldehydes Catalyzed by a Diarylprolinol Silyl Ether Salt in the Presence of Water

(2008) Yujiro Hayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Organocatalysis: From Infancy to Adolescence

(2008) Alessandro Dondoni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

α,α-Diarylprolinol Ethers: New Tools for Functionalization of Carbonyl Compounds

(2008) Antonia Mielgo et al.   Chemistry-An Asian Journal

Isolation and X-Ray Structures of Reactive Intermediates of Organocatalysis with Diphenylprolinol Ethers and with Imidazolidinones

(2008) Dieter Seebach et al.   HELVETICA CHIMICA ACTA

Conformational Preferences of α-Substituted Proline Analogues

(2008) Alejandra Flores-Ortega et al.   JOURNAL OF ORGANIC CHEMISTRY

The advent and development of organocatalysis

(2008) David W. C. MacMillan   NATURE

Diphenylprolinol Silyl Ether Catalysis in an Asymmetric Formal Carbo [3 + 3] Cycloaddition Reaction via a Domino Michael/Knoevenagel Condensation

(2008) Yujiro Hayashi et al.   ORGANIC LETTERS

Organocatalysis Lost: Modern Chemistry, Ancient Chemistry, and an Unseen Biosynthetic Apparatus

(2007) Carlos F. Barbas   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION