Cleavage of the CN Bond in Carbodiimides via Release of High Ring Strain: A New Strategy for the Selective Synthesis of 2-Aminoaryl Alkynyl Imines

Mechanistic Study on the Cleavage and Reorganization of C(sp3)H and CN Bonds in Carbodiimides: Synthesis of 1,2-Dihydrothiopyrimidines and 2,3-Dihydropyrimidinthiones through Four-Component Coupling

(2013) Yang Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient Approach to 4-Sulfonamidoquinolines via Copper(I)-Catalyzed Cascade Reaction of Sulfonyl Azides with Alkynyl Imines

(2013) Guolin Cheng et al.   ORGANIC LETTERS

A Closer Look at Aryne Chemistry: Details that Remain Mysterious

(2013) Chunrui Wu et al.   Asian Journal of Organic Chemistry

Arynes in Transition-Metal-Free Multicomponent Coupling Reactions

(2012) Sachin Suresh Bhojgude et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Comprehensive History of Arynes in Natural Product Total Synthesis

(2012) Pamela M. Tadross et al.   CHEMICAL REVIEWS

Recent advances in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions using arynes

(2012) Anup Bhunia et al.   CHEMICAL SOCIETY REVIEWS

Regioselective Ring Expansion of 2,4-Diiminoazetidines via Cleavage of C–N and C(sp3)–H Bonds: Efficient Construction of 2,3-Dihydropyrimidinesulfonamides

(2012) Yang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single molecules put a ring on it

(2012) John T. S. Yeoman et al.   NATURE

Use of benzynes for the synthesis of heterocycles

(2012) Anton V. Dubrovskiy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Three-Component Coupling of Arynes and Organic Bromides

(2011) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Procedure-Controlled Selective Synthesis of 5-Acyl-2-iminothiazolines and their Selenium and Tellurium Derivatives by Convergent Tandem Annulation

(2011) Yang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-Catalyzed Cleavage of a Carbon-Carbon Single Bond between Carbonyl Carbon and α-Carbon Atoms of Ketones

(2011) Yoichiro Kuninobu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Oxidation of C–O and C–N Bonds Using Oxidases

(2011) Nicholas J. Turner   CHEMICAL REVIEWS

CuBr/FeCl3 Catalysis: a Novel and Efficient Method for the Preparation of New Aryl (Iminomethyl)propargyl Ether Derivatives via CH Activation of Aryl Propargyl Ethers

(2011) Gautham Santhosh Kumar et al.   HELVETICA CHIMICA ACTA

Synthesis, Structures, and Reactivity of Yttrium Alkyl and Alkynyl Complexes with Mixed TpMe2/Cp Ligands

(2011) Weiyin Yi et al.   INORGANIC CHEMISTRY

Recent Progress in Half-sandwich Rare-earth-catalyzed Organic Synthesis

(2011) Toshiaki Suzuki et al.   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

Ti-amide Catalyzed Synthesis of Cyclic Guanidines from Di-/Triamines and Carbodiimides

(2011) Hao Shen et al.   ORGANIC LETTERS

C–H Activation via Carbodiimide Insertion into Yttrium–Carbon Alkynide Bonds: An Organometallic Alder-ene Reaction

(2011) Ian J. Casely et al.   ORGANOMETALLICS

The Benzyne Story

(2010) Curt Wentrup   AUSTRALIAN JOURNAL OF CHEMISTRY

Half-Sandwich Rare Earth Metal Complexes as Novel Catalysts for Olefin Polymerization and Other Chemical Transformations

(2010) Masayoshi Nishiura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

A New Strategy for the Synthesis of Poly-Substituted 3-H, 3-Fluoro, or 3-Trifluoromethyl Pyridines via the Tandem C−F Bond Cleavage Protocol

(2010) Zixian Chen et al.   ORGANIC LETTERS

A Multicomponent Reaction of Arynes, Isocyanides, and Terminal Alkynes: Highly Chemo- and Regioselective Synthesis of Polysubstituted Pyridines and Isoquinolines

(2009) Feng Sha et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Natural Product Synthesis Using Multicomponent Reaction Strategies

(2009) Barry B. Touré et al.   CHEMICAL REVIEWS

Syntheses and Transformations of 2-Methyleneaziridines and 2-Methyleneazetidines

(2009) Kourosch Tehrani et al.   CURRENT ORGANIC CHEMISTRY

A Convenient Synthesis of 5-Amino-Substituted 1,2,4-Oxadiazole Derivatives via Reactions of Amidoximes with Carbodiimides

(2009) Konstantina C. Fylaktakidou et al.   HETEROCYCLES

Efficient One-Pot Synthesis of 2,3-Dihydropyrimidinthiones via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur, and Carbodiimides

(2009) Zitao Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Azetidines: New Tools for the Synthesis of Nitrogen Heterocycles

(2009) François Couty et al.   SYNLETT

Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes

(2008) Wen-Xiong Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multicomponent, One-Pot Sequential Synthesis of 1,3,5- and 1,3,5,5-Substituted Barbiturates†

(2008) Alessandro Volonterio et al.   JOURNAL OF ORGANIC CHEMISTRY

Divalent Lanthanide Complexes: Highly Active Precatalysts for the Addition of N−H and C−H Bonds to Carbodiimides

(2008) Zhu Du et al.   JOURNAL OF ORGANIC CHEMISTRY

Experimental and Computational Study of the Conrotatory Ring Opening of Various 3-Chloro-2-azetines

(2008) Sven Mangelinckx et al.   JOURNAL OF ORGANIC CHEMISTRY

Titanacarborane mediated C–N bond forming/breaking reactions

(2008) Hao Shen et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Asymmetric Synthesis of Bicyclic Amidines via Rhodium-Catalyzed [2+2+2] Cycloaddition of Carbodiimides

(2008) Robert T. Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic addition of alkyne C–H, amine N–H, and phosphine P–H bonds to carbodiimides: an efficient route to propiolamidines, guanidines, and phosphaguanidines

(2008) Wen-Xiong Zhang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of highly substituted 2-perfluoroalkyl quinolines by electrophilic iodocyclization of perfluoroalkyl propargyl imines/amines

(2008) Pravin R. Likhar et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

β-Diketiminato Calcium Acetylides: Synthesis, Solution Dimerization, and Catalytic Carbon−Carbon Bond Formation

(2008) Anthony G. M. Barrett et al.   ORGANOMETALLICS

Coupling of Terminal Alkynes and Isonitriles by Organoactinide Complexes: Scope and Mechanistic Insights

(2008) Eyal Barnea et al.   ORGANOMETALLICS

Metal-free synthesis of alkynyl imines using an oxophosphonium-mediated approach at ambient temperatures

(2008) Qing-Li Dong et al.   TETRAHEDRON LETTERS

Copper-Catalyzed Highly Efficient Multicomponent Reactions of Terminal Alkynes, Acid Chlorides, and Carbodiimides: Synthesis of Functionalized Propiolamidine Derivatives

(2007) Xiaoliang Xu et al.   ADVANCED SYNTHESIS & CATALYSIS