The Redox-Neutral Approach to CH Functionalization

Enantioselective Intramolecular 1,5-Hydride Transfer/Cyclization through the Direct Functionalization of C(sp3)-H Bonds Adjacent to a Heteroatom: From Nitrogen to Oxygen

(2013) Min Wang   ChemCatChem

Intramolecular CH Bond Activation through a Flexible Ester Linkage

(2012) Christopher J. Shaffer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Oxidation/C(sp3)H Functionalization of Unactivated Alkynes Using Pyridine-N-Oxide as the External Oxidant

(2012) Dian-Feng Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Activation in S-Alkenyl Sulfoximines: An Endo 1,5-Hydrogen Migration

(2012) Xuefeng Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular Redox-Triggered CH Functionalization

(2012) Igor D. Jurberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Direct C sp 3H Functionalization of Ethers: A Highly Efficient Approach to Chiral Spiroethers

(2012) Zhi-Wei Jiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic C–H activation reactions

(2012) Subhas Chandra Pan   Beilstein Journal of Organic Chemistry

Catalytic Enantioselective tert-Aminocyclization by Asymmetric Binary Acid Catalysis (ABC): Stereospecific 1,5-Hydrogen Transfer

(2012) Liujuan Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Theoretical Studies of the Asymmetric Binary-Acid-Catalyzedtert-Aminocyclization Reaction: Origins of the C sp 3H Activation and Stereoselectivity

(2012) Long Zhang et al.   Chemistry-An Asian Journal

Intermolecular Ritter-Type C–H Amination of Unactivated sp3 Carbons

(2012) Quentin Michaudel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zinc(II)-Catalyzed Redox Cross-Dehydrogenative Coupling of Propargylic Amines and Terminal Alkynes for Synthesis of N-Tethered 1,6-Enynes

(2012) Tsuyuka Sugiishi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Functionalization of Unactivated sp3 C–H Bonds via exo-Directing Groups: Synthesis of Chemically Differentiated 1,2-Diols

(2012) Zhi Ren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol

(2012) Eric M. Simmons et al.   NATURE

Guided desaturation of unactivated aliphatics

(2012) Ana-Florina Voica et al.   Nature Chemistry

FeCl3-Catalyzed Stereoselective Construction of Spirooxindole Tetrahydroquinolines via Tandem 1,5-Hydride Transfer/Ring Closure

(2012) Yan-Yan Han et al.   ORGANIC LETTERS

Concise Route to 3-Arylisoquinoline Skeleton by Lewis Acid Catalyzed C(sp3)–H Bond Functionalization and Its Application to Formal Synthesis of (±)-Tetrahydropalmatine

(2012) Keiji Mori et al.   ORGANIC LETTERS

Innate and Guided C–H Functionalization Logic

(2011) Tobias Brückl et al.   ACCOUNTS OF CHEMICAL RESEARCH

Functionalization of Acetalic C(sp3)-H Bonds by Scandium(III) Triflate-Catalyzed Intramolecular Redox Reactions: Tandem 1,4-Hydride Transfer/1,5-Cyclization Processes Leading to Protected 1-Indanones

(2011) Mateo Alajarin et al.   ADVANCED SYNTHESIS & CATALYSIS

A Practical Strategy for the Structural Diversification of Aliphatic Scaffolds through the Palladium-Catalyzed Picolinamide-Directed Remote Functionalization of Unactivated C(sp3)H Bonds

(2011) Gang He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Sp3α-C–H activation and functionalization of alcohol and ether

(2011) Shu-Yu Zhang et al.   CHEMICAL SOCIETY REVIEWS

Rapid Access to 3-Aryltetralin Skeleton via C(sp3)–H Bond Functionalization: Investigation on the Substituent Effect of Aromatic Ring Adjacent to C–H Bond in Hydride Shift/Cyclization Sequence

(2011) Keiji Mori et al.   CHEMISTRY LETTERS

Enantioselective Gold-Catalyzed Functionalization of Unreactive sp3 CH Bonds through a Redox-Neutral Domino Reaction

(2011) Guanghua Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expeditious Construction of a Carbobicyclic Skeleton via sp3-C−H Functionalization: Hydride Shift from an Aliphatic Tertiary Position in an Internal Redox Process

(2011) Keiji Mori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold and Brønsted Acid Catalyzed Hydride Shift onto Allenes: Divergence in Product Selectivity

(2011) Benoit Bolte et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Neutral Indole Annulation Cascades

(2011) Michael C. Haibach et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Activation of Enantiotopic C(sp3)−Hydrogen by Means of Chiral Phosphoric Acid: Asymmetric Synthesis of Tetrahydroquinoline Derivatives

(2011) Keiji Mori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric additions to dienes catalysed by a dithiophosphoric acid

(2011) Nathan D. Shapiro et al.   NATURE

Diverting non-haem iron catalysed aliphatic C–H hydroxylations towards desaturations

(2011) Marinus A. Bigi et al.   Nature Chemistry

Highly Enantioselective Synthesis of Tetrahydroquinolines via Cobalt(II)-Catalyzed Tandem 1,5-Hydride Transfer/Cyclization

(2011) Weidi Cao et al.   ORGANIC LETTERS

Asymmetric sp3 C–H functionalization via a chiral Brønsted acid-catalyzed redox reaction for the synthesis of cyclic aminals

(2011) Yu-Ping He et al.   TETRAHEDRON LETTERS

Hydroalkylation of Alkynyl Ethers via a Gold(I)-Catalyzed 1,5-Hydride Shift/Cyclization Sequence

(2010) Igor Dias Jurberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

One-Pot Synthesis of 1,3-Disubstituted Allenes from 1-Alkynes, Aldehydes, and Morpholine

(2010) Jinqiang Kuang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold(I)-Catalyzed Rearrangement of Propargyl Benzyl Ethers: A Practical Method for the Generation and in Situ Transformation of Substituted Allenes

(2010) Benoit Bolte et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Organocatalytic C−H Bond Functionalization via Tandem 1,5-Hydride Transfer/Ring Closure: Asymmetric Synthesis of Tetrahydroquinolines

(2010) Young Ku Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expeditious Synthesis of Benzopyrans via Lewis Acid-Catalyzed C−H Functionalization: Remarkable Enhancement of Reactivity by anOrthoSubstituent

(2010) Keiji Mori et al.   ORGANIC LETTERS

Expeditious Construction of Quinazolines via Brønsted Acid-induced C–H Activation: Further Extension of “tert-Amino Effect”

(2009) Keiji Mori et al.   CHEMISTRY LETTERS

Platinum and Ruthenium Chloride-Catalyzed Cycloisomerization of 1-Alkyl-2-ethynylbenzenes: Interception of π-Activated Alkynes with a Benzylic C−H Bond

(2009) Mamoru Tobisu et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of (−)-PNU-286607 by Asymmetric Cyclization of Alkylidene Barbiturates

(2009) J. Craig Ruble et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Intramolecular Redox Reactions: Ring-Fused Tetrahydroquinolines

(2009) Sandip Murarka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Functionalization via Hydride Transfer: Direct Coupling of Unactivated Alkynes and sp3C−H Bonds Catalyzed by Platinum Tetraiodide

(2009) Paul A. Vadola et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Isomerization and Intramolecular Redox Reaction of Alkynyl Ethers Affording Dihydropyrans and Ketoolefins

(2009) Daisuke Shikanai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Functionalization via Hydride Transfer: Synthesis of Dihydrobenzopyrans fromortho-Vinylaryl Akyl Ethers

(2009) Kevin M. McQuaid et al.   ORGANIC LETTERS

Functionalization of Csp3–H bond—Sc(OTf)3-catalyzed domino 1,5-hydride shift/cyclization/Friedel–Crafts acylation reaction of benzylidene Meldrum’s acids

(2009) Stuart J. Mahoney et al.   TETRAHEDRON LETTERS

Facile Formation of Cyclic Aminals through a Brønsted Acid-Promoted Redox Process

(2008) Chen Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

1,3-Diol Synthesis via Controlled, Radical-Mediated C−H Functionalization

(2008) Ke Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Functionalization via Hydride Transfer: Lewis Acid Catalyzed Alkylation Reactions by Direct Intramolecular Coupling of sp3C−H Bonds and Reactive Alkenyl Oxocarbenium Intermediates

(2008) Kevin M. McQuaid et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Highly Enantioselective Synthesis of Axially Chiral Allenes

(2008) Vanessa Kar-Yan Lo et al.   ORGANIC LETTERS

Lewis Acid Catalyzed Formation of Tetrahydroquinolines via an Intramolecular Redox Process

(2008) Sandip Murarka et al.   ORGANIC LETTERS

Dehydrogenation of Inert Alkyl Groups via Remote C−H Activation: Converting a Propyl Group into a π-Allylic Complex

(2008) Ramesh Giri et al.   ORGANOMETALLICS