Recent Advances in the Field of Main-Group Mono- and Diatomic “Allotropes” Stabilised by Neutral Ligands

One Molecule, Two Atoms, Three Views, Four Bonds?

(2013) Sason Shaik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Carbone-Stabilized Two-Coordinate Phosphorus(III)-Centered Dication

(2013) Madelyn Qin Yi Tay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dinitrogen as Double Lewis Acid: Structure and Bonding of Triphenylphosphinazine N2(PPh3)2

(2013) Nicole Holzmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron-Boron Multiple Bond in [B(NHC)]2: Towards Stable and Aromatic [B(NHC)]nRings

(2013) Truong Ba Tai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cyclic Silylone (“Siladicarbene”) with an Electron-Rich Silicon(0) Atom

(2013) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Singlet Biradicaloid Siladicarbene: (L:)2Si

(2013) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes

(2013) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters

(2013) Caleb D. Martin et al.   CHEMICAL COMMUNICATIONS

Comparative Study of Phosphine and N-Heterocyclic Carbene Stabilized Group 13 Adducts [L(EH3)] and [L2(E2Hn)]

(2013) Nicole Holzmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Neutral tricoordinated beryllium(0) compounds – isostructural to BH3 but isoelectronic to NH3

(2013) Susmita De et al.   DALTON TRANSACTIONS

Beryllium chemistry the safe way: a theoretical evaluation of low oxidation state beryllium compounds

(2013) Shannon A. Couchman et al.   DALTON TRANSACTIONS

Easy Access to Silicon(0) and Silicon(II) Compounds

(2013) Kartik Chandra Mondal et al.   INORGANIC CHEMISTRY

Oxidation of Carbene-Stabilized Diarsenic: Diarsene Dications and Diarsenic Radical Cations

(2013) Mariham Y. Abraham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cyclic Germadicarbene (“Germylone”) from Germyliumylidene

(2013) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic Modification of Acyclic Bent Allenes (Carbodicarbenes) and Further Studies on Their Structural Implications and Reactivities

(2013) Wen-Ching Chen et al.   ORGANOMETALLICS

Carbene-stabilized main group radicals and radical ions

(2013) Caleb D. Martin et al.   Chemical Science

Coordination Chemistry at Carbon: The Patchwork Family Comprising (Ph3P)2C, (Ph3P)C(C2H4), and (C2H4)2C

(2012) Hubert Schmidbaur et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conversion of a Singlet Silylene to a stable Biradical

(2012) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An N-heterocyclic carbene adduct of diatomic tin, :SnSn:

(2012) Cameron Jones et al.   CHEMICAL COMMUNICATIONS

Carbodiphosphorane Analogues E(PPh3)2 with E=C-Pb: A Theoretical Study with Implications for Ligand Design

(2012) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Are N-Heterocyclic Carbenes “Better” Ligands than Phosphines in Main Group Chemistry? A Theoretical Case Study of Ligand-Stabilized E2 Molecules, L-E-E-L (L = NHC, phosphine; E = C, Si, Ge, Sn, Pb, N, P, As, Sb, Bi)

(2012) David J. D. Wilson et al.   INORGANIC CHEMISTRY

Three-Coordinate Beryllium β-Diketiminates: Synthesis and Reduction Chemistry

(2012) Merle Arrowsmith et al.   INORGANIC CHEMISTRY

Facile synthesis of benzimidazolin-2-chalcogenones: Nature of the carbon–chalcogen bond

(2012) Sudesh T. Manjare et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Carbene-Stabilized Beryllium Borohydride

(2012) Robert J. Gilliard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quadruple bonding in C2 and analogous eight-valence electron species

(2012) Sason Shaik et al.   Nature Chemistry

Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond

(2012) H. Braunschweig et al.   SCIENCE

Reaction of pentaarylboroles with carbon monoxide: an isolable organoboron carbonyl complex

(2012) Aiko Fukazawa et al.   Chemical Science

Synthesis, Structure, and Reactivity of a Dihydrido Borenium Cation

(2011) Blanca Inés et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structures and Stabilities of Group 13 Adducts [(NHC)(EX3)] and [(NHC)2(E2Xn)] (E=B to In; X=H, Cl; n=4, 2, 0; NHC=N-Heterocyclic Carbene) and the Search for Hydrogen Storage Systems: A Theoretical Study

(2011) Nicole Holzmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactivity of white phosphorus with compounds of the p-block

(2011) Nick A. Giffin et al.   COORDINATION CHEMISTRY REVIEWS

Carbene-stabilized main group diatomic allotropes

(2011) Yuzhong Wang et al.   DALTON TRANSACTIONS

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Cleavage of Carbene-Stabilized Disilicon

(2011) Mariham Y. Abraham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines

(2011) R. Kinjo et al.   SCIENCE

Divalent Pb(0) compounds

(2011) Nozomi Takagi et al.   THEORETICAL CHEMISTRY ACCOUNTS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbodiylides C(ECp*)2 (E=B-Tl): Another Class of Theoretically Predicted Divalent Carbon(0) Compounds

(2010) Susanne Klein et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

The Flexible Coordination Modes of Guanidine Ligands in Zn Alkyl and Halide Complexes: Chances for Catalysis

(2010) Matthias Reinmuth et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Isolation of crystalline carbene-stabilized P2-radical cations and P2-dications

(2010) Olivier Back et al.   Nature Chemistry

SiBr2(Idipp): A Stable N-Heterocyclic Carbene Adduct of Dibromosilylene

(2009) Alexander C. Filippou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonmetal-Mediated Fragmentation of P4: Isolation of P1and P2Bis(carbene) Adducts

(2009) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Stabilized Digermanium(0)

(2009) Anastas Sidiropoulos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divalent Silicon(0) Compounds

(2009) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent E(0) Compounds (E=Si-Sn)

(2009) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbene Stabilization of Diarsenic: From Hypervalency to Allotropy

(2009) Mariham Y. Abraham et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molecules with All Triple Bonds: OCBBCO, N2BBN2, and [OBBBBO]2−†

(2009) Lucas C. Ducati et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Coordination chemistry at carbon

(2009) Manuel Alcarazo et al.   Nature Chemistry

Beryllium Dimer--Caught in the Act of Bonding

(2009) J. M. Merritt et al.   SCIENCE

Synthesis of an Extremely Bent Acyclic Allene (A “Carbodicarbene”): A Strong Donor Ligand

(2008) C. Adam Dyker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbene-Stabilized Diphosphorus

(2008) Yuzhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CHEMISTRY: Soluble Allotropes of Main-Group Elements

(2008) C. A. Dyker et al.   SCIENCE

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE