Evaluatingcis-2,6-Dimethylpiperidide (cis-DMP) as a Base Component in Lithium-Mediated Zincation Chemistry

Opening the black box of mixed-metal TMP metallating reagents: direct cadmation or lithium–cadmium transmetallation?

(2012) David R. Armstrong et al.   Chemical Science

“LiZn(TMP)3”, a Zincate or a Turbo-Lithium Amide Reagent? DOSY NMR Spectroscopic Evidence

(2011) Pablo García-Álvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Chemoselective Metalation of Arenes and Heteroarenes Using Hindered Metal Amide Bases

(2011) Benjamin Haag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular Structures of THF-Solvated Alkali-Metal 2,2,6,6-Tetramethylpiperidides Finally Revealed: X-ray Crystallographic, DFT, and NMR (including DOSY) Spectroscopic Studies

(2011) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structurally Powered Synergic 2,2,6,6-Tetramethylpiperidine Bimetallics: New Reflections through Lithium-MediatedOrthoAluminations

(2011) Robert E. Mulvey et al.   INORGANIC CHEMISTRY

Ion Pair pKs of Some Amines: Extension of the Computed Lithium pK Scale

(2011) Andrew Streitwieser et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of N,N-dialkylaminobenzonitriles and halo-(N,N-dialkyl)benzamidines by reaction of halobenzonitriles with lithium amides

(2011) Paola Vitale et al.   TETRAHEDRON

Structurally Engineered Deprotonation/Alumination of THF and THTP with Retention of Their Cycloanionic Structures

(2010) Elaine Crosbie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lithium Cadmate-Mediated Deprotonative Metalation of Anisole: Experimental and Computational Study

(2010) Katia Snégaroff et al.   JOURNAL OF ORGANIC CHEMISTRY

Structural insights into mono-amido tris-alkyl potassium aluminates

(2010) Ben Conway et al.   NEW JOURNAL OF CHEMISTRY

Nickel, Manganese, Cobalt, and Iron-Catalyzed Deprotonative Arene Dimerization

(2010) Thanh Truong et al.   ORGANIC LETTERS

Avant-Garde Metalating Agents: Structural Basis of Alkali-Metal-Mediated Metalation

(2009) Robert E. Mulvey   ACCOUNTS OF CHEMICAL RESEARCH

Solvent-Separated and Contact Ion Pairs of Parent Lithium Trimethyl Zincate

(2009) S. Merkel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?

(2009) Ross Campbell et al.   DALTON TRANSACTIONS

Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates

(2009) William Clegg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

New strategy to the synthesis of (N→B) phenyl[N-alkyliminodiacetate-O,O′,N]boranes: The crystal structure of (N→B) phenyl[N-benzyliminodiacetate-O,O′,N]borane, (N→B)phenyl[N-(4-methyl)benzyliminodiacetate-O,O′,N]borane and (N→B) phenyl[N-phenacyliminodiacetate-O,O′,N]borane

(2009) Teresa Mancilla Percino et al.   POLYHEDRON

Synergic Sedation of Sensitive Anions: Alkali-Mediated Zincation of Cyclic Ethers and Ethene

(2009) A. R. Kennedy et al.   SCIENCE

Characterization of Reactive Intermediates by Multinuclear Diffusion-Ordered NMR Spectroscopy (DOSY)

(2008) Deyu Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

Convenient Preparation of Polyfunctional Aryl Magnesium Reagents by a Direct Magnesium Insertion in the Presence of LiCl

(2008) Fabian M. Piller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deprotonative cadmation of functionalized aromatics

(2008) Jean-Martial L’Helgoual’ch et al.   CHEMICAL COMMUNICATIONS

Mixed Alkylamido Aluminate as a Kinetically Controlled Base

(2008) Hiroshi Naka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Suppressing the Anionic Fries Rearrangement of Aryl Dialkylcarbamates; the Isolation of a Crystallineortho-Deprotonated Carbamate

(2007) Felipe García et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY