Reaction of N-Heterocyclic Silylenes with Thioketone: Formation of Silicon-Sulfur Three (Si-C-S)- and Five (Si-C-C-C-S)-Membered Ring Systems

A début for base stabilized monoalkylsilylenes

(2012) Ramachandran Azhakar et al.   CHEMICAL COMMUNICATIONS

Donor–acceptor stabilized silaformyl chloride

(2012) Rajendra S. Ghadwal et al.   CHEMICAL COMMUNICATIONS

Facile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene Ligand

(2012) Ramachandran Azhakar et al.   Chemistry-An Asian Journal

The group 7 metal carbonyl complexes from a stable heteroleptic silylene PhC(NtBu)2SiNPh2

(2012) Ramachandran Azhakar et al.   DALTON TRANSACTIONS

An access to base-stabilized three-membered silicon heterocycles

(2012) Ramachandran Azhakar et al.   DALTON TRANSACTIONS

Stable Silaimines with Three- and Four-Coordinate Silicon Atoms

(2012) Prinson P. Samuel et al.   INORGANIC CHEMISTRY

Facile Access to the Functionalized N-Donor Stabilized Silylenes PhC(NtBu)2SiX (X = PPh2, NPh2, NCy2, NiPr2, NMe2, N(SiMe3)2, OtBu)

(2012) Ramachandran Azhakar et al.   ORGANOMETALLICS

Reactivity Studies of Heteroleptic Silylenes with N2O

(2012) Ramachandran Azhakar et al.   ORGANOMETALLICS

Reactivity Studies of a Stable N-Heterocyclic Silylene with Triphenylsilanol and Pentafluorophenol

(2012) Ramachandran Azhakar et al.   ORGANOMETALLICS

Synthetic Routes to N-Heterocyclic Carbene Precursors

(2011) Laure Benhamou et al.   CHEMICAL REVIEWS

Free Radical Reactivity of Mono- and Dichlorosilylene with Muonium

(2011) Paul W. Percival et al.   CHEMISTRY-A EUROPEAN JOURNAL

Naked metal nanoparticles from metal carbonyls in ionic liquids: Easy synthesis and stabilization

(2011) Christian Vollmer et al.   COORDINATION CHEMISTRY REVIEWS

Double N–H bond activation of N,N′-bis-substituted hydrazines with stable N-heterocyclic silylene

(2011) Ramachandran Azhakar et al.   DALTON TRANSACTIONS

Reactions of Stable Amidinate Chlorosilylene and [1+4]-Oxidative Addition of N-Heterocyclic Silylene with N-Benzylideneaniline

(2011) Anukul Jana et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene

(2011) Ramachandran Azhakar et al.   INORGANIC CHEMISTRY

Formation of Silicon Centered Spirocyclic Compounds: Reaction of N-Heterocyclic Stable Silylene with Benzoylpyridine, Diisopropyl Azodicarboxylate, and 1,2-Diphenylhydrazine

(2011) Ramachandran Azhakar et al.   INORGANIC CHEMISTRY

N-Heterocyclic Carbene Stabilized Dichlorosilylene Transition-Metal Complexes of V(I), Co(I), and Fe(0)

(2011) Rajendra S. Ghadwal et al.   INORGANIC CHEMISTRY

Donor–Acceptor-Stabilized Silicon Analogue of an Acid Anhydride

(2011) Rajendra S. Ghadwal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stabilization of Low Valent Silicon Fluorides in the Coordination Sphere of Transition Metals

(2011) Ramachandran Azhakar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regiospecific C–H Bond Activation: Reactivity Study of N-Heterocyclic Silylene toward Ambidentate Phosphorus Ylide

(2011) Ramachandran Azhakar et al.   ORGANOMETALLICS

Reactions of StableN-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone

(2011) Ramachandran Azhakar et al.   ORGANOMETALLICS

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

Chemistry of functionalized silylenes

(2011) Sakya S. Sen et al.   Chemical Science

An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds

(2010) Mitsuo Kira   CHEMICAL COMMUNICATIONS

Facile Synthesis of a Rare Chlorosilylene-BH3 Adduct

(2010) Ramachandran Azhakar et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Unsymmetric Ru(II) Complexes withN-Heterocyclic Carbene and/or Terpyridine Ligands: Synthesis, Characterization, Ground- and Excited-State Electronic Structures and Their Application for DSSC Sensitizers

(2010) Hee-Jun Park et al.   INORGANIC CHEMISTRY

Synthesis of a Zinc(II) Imidazolium Dicarboxylate Ligand Metal−Organic Framework (MOF): a Potential Precursor to MOF-Tethered N-Heterocyclic Carbene Compounds

(2010) Rachel S. Crees et al.   INORGANIC CHEMISTRY

Biscarbene Palladium(II) Complexes. Reactivity of Saturated Versus UnsaturatedN-Heterocyclic Carbenes

(2010) Ching-Feng Fu et al.   INORGANIC CHEMISTRY

Facile Syntheses of Silylene Nickel Carbonyl Complexes from Lewis Base Stabilized Chlorosilylenes†

(2010) Gašper Tavčar et al.   INORGANIC CHEMISTRY

Highly Convenient Regioselective Intermolecular Hydroamination of Alkynes Yielding Ketimines Catalyzed by Gold(I) Complexes of 1,2,4-triazole Based N-heterocyclic Carbenes

(2010) Chandrakanta Dash et al.   INORGANIC CHEMISTRY

Iridium Metal Complexes Containing N-Heterocyclic Carbene Ligands for Blue-Light-Emitting Electrochemical Cells

(2010) Cheng-Han Yang et al.   INORGANIC CHEMISTRY

Regioselective C−H Activation and Sequential C−C and C−O Bond Formation Reactions of Aryl Ketones Promoted by an Yttrium Carbene

(2010) David P. Mills et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene

(2010) Sakya S. Sen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Aromatic C−F and C−H Bond Activation with Silylenes of Different Coordinate Silicon

(2010) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions of an Isolable Dialkylsilylene with Ketones†

(2010) Shintaro Ishida et al.   ORGANOMETALLICS

Unusual [3+1] Cycloaddition of a Stable Silylene with a 2,3-Diazabuta-1,3-diene versus [4+1] Cycloaddition toward a Buta-1,3-diene

(2010) Yun Xiong et al.   ORGANOMETALLICS

Versatile Reactivity of a Zwitterionic Isolable Silylene toward Ketones: Silicon-Mediated, Regio- and Stereoselective CH Activation

(2009) Yun Xiong et al.   CHEMISTRY-A EUROPEAN JOURNAL

N-Aryl substituted heterocyclic silylenes

(2009) Lingbing Kong et al.   DALTON TRANSACTIONS

A comparison of a microfocus X-ray source and a conventional sealed tube for crystal structure determination

(2009) Thomas Schulz et al.   JOURNAL OF APPLIED CRYSTALLOGRAPHY

Diketiminate Silicon(II) and Related NHSi Ligands Generated in the Coordination Sphere of Nickel(0)

(2009) Antje Meltzer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of a Zwitterionic Stable Silylene toward Halosilanes and Haloalkanes

(2009) Yun Xiong et al.   ORGANOMETALLICS

Insertion Reaction of a Silylene into a N−H Bond of Hydrazine and a [1+4] Cycloaddition with Diphenyl Hydrazone§

(2009) Anukul Jana et al.   ORGANOMETALLICS

Synthesis, structure, magnetism and nuclease activity of tetranuclear copper(ii) phosphonates containing ancillary 2,2′-bipyridine or 1,10-phenanthroline ligands

(2008) Vadapalli Chandrasekhar et al.   DALTON TRANSACTIONS