Heterolytic cleavage of ammonia N–H bond by bifunctional activation in silica-grafted single site Ta(V) imido amido surface complex. Importance of the outer sphere NH3 assistance

Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst

(2010) Brian L. Conley et al.   CHEMICAL REVIEWS

Advances in selective activation and application of ammonia in homogeneous catalysis

(2010) Jarl Ivar van der Vlugt   CHEMICAL SOCIETY REVIEWS

Heterolytic splitting of H–X bonds at a cationic (PNP)Pd center

(2010) Lauren C. Gregor et al.   DALTON TRANSACTIONS

The Pt-Catalyzed Ethylene Hydroamination by Aniline: A Computational Investigation of the Catalytic Cycle

(2010) Pavel A. Dub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N−H Activation of Amines and Ammonia by Ru via Metal−Ligand Cooperation

(2010) Eugene Khaskin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction Mechanism of the Gold(I)-Catalyzed Addition of Phenols to Olefins: A Concerted Process Accelerated by Phenol and Water

(2010) Gábor Kovács et al.   ORGANOMETALLICS

Reaction of M(II) Diaryls (M = Mn or Fe) with Ammonia to Afford Parent Amido Complexes

(2010) Chengbao Ni et al.   ORGANOMETALLICS

Anion-Exchange-Triggered 1,3-Shift of an NH Proton to Iridium in Protic N-Heterocyclic Carbenes: Hydrogen-Bonding and Ion-Pairing Effects

(2009) Guoyong Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non-Innocent Scaffolds for Homogeneous Catalysis

(2009) Jarl Ivar van der Vlugt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Addition of Hydrogen or Ammonia to a Low-Valent Group 13 Metal Species at 25 °C and 1 Atmosphere

(2009) Zhongliang Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS

The mechanism of N-vinylindole formation via tandem imine formation and cycloisomerisation of o-ethynylanilines

(2009) Danielle F. Kennedy et al.   DALTON TRANSACTIONS

Cleavage of a N−H Bond of Ammonia at Room Temperature by a Germylene

(2009) Anukul Jana et al.   INORGANIC CHEMISTRY

Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium and Iridium Amido Complexes Supported by Silyl Pincer Ligation: Ammonia N−H Bond Activation by a [PSiP]Ir Complex

(2009) Erin Morgan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Allylic Amination Using Aqueous Ammonia for the Synthesis of Primary Amines

(2009) Takashi Nagano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

H/D Exchange on Silica-Grafted Tantalum(V) Imido Amido [(≡SiO)2Ta(V)(NH)(NH2)] Synthesized from Either Ammonia or Dinitrogen: IR and DFT Evidence for Heterolytic Splitting of D2

(2009) Priscilla Avenier et al.   TOPICS IN CATALYSIS

Homogeneous Catalytic Hydroamination of Alkynes and Allenes with Ammonia

(2008) Vincent Lavallo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Synthesis of Primary Amines Directly from Alcohols and Ammonia

(2008) Chidambaram Gunanathan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spectroscopic Determination of Hydrogenation Rates and Intermediates during Carbonyl Hydrogenation Catalyzed by Shvo's Hydroxycyclopentadienyl Diruthenium Hydride Agrees with Kinetic Modeling Based on Independently Measured Rates of Elementary Reactions

(2008) Charles P. Casey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Catalytic Dehydrogenation of Ammonia-Borane Involving an Unexpected Hydrogen Transfer to Ligated Carbene and Subsequent Carbon−Hydrogen Activation

(2008) Xinzheng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY